ES8600199A1 - Procedimiento de preparacion de nuevos esteres del acido vinilciclopropancarboxilico en su forma racemica u opticamente activa, con actividad pesticida. - Google Patents
Procedimiento de preparacion de nuevos esteres del acido vinilciclopropancarboxilico en su forma racemica u opticamente activa, con actividad pesticida.Info
- Publication number
- ES8600199A1 ES8600199A1 ES528023A ES528023A ES8600199A1 ES 8600199 A1 ES8600199 A1 ES 8600199A1 ES 528023 A ES528023 A ES 528023A ES 528023 A ES528023 A ES 528023A ES 8600199 A1 ES8600199 A1 ES 8600199A1
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- acid derivatives
- vinylcyclopropanecarboxylic acid
- insecticide containing
- novel esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PDOBSLHNWIVQJX-UHFFFAOYSA-N 1-ethenylcyclopropane-1-carboxylic acid Chemical class OC(=O)C1(C=C)CC1 PDOBSLHNWIVQJX-UHFFFAOYSA-N 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title abstract 2
- 239000002917 insecticide Substances 0.000 title abstract 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 abstract 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
- 239000013543 active substance Substances 0.000 abstract 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 235000000484 citronellol Nutrition 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/16—Unsaturated compounds
- C07C61/40—Unsaturated compounds containing halogen
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
PROCEDIMIENTO DE PREPARACION DE NUEVOS ESTERES DEL ACIDO VINILCICLOPROPANCARBOXILICO EN SU FORMA RACEMICA U OPTICAMENTE ACTIVA, CON ACTIVIDAD PESTICIDA.CONSISTE EN HACER REACCIONAR UN ACIDO VINILCICLOPROPANCARBOXILICO O UN DERIVADO ESTERIFICABLE DEL MISMO DE FORMUL (II) CON UN ALCOHOL DE FORMULA R-Q, PARA OBTENER ESTERES DEL ACIDO VINILCICLOPROPANCARBOXILICO EN SU FORMA RACEMICA U OPTICAMENTE ACTIVA DE FORMULA (I), DONDE X REPRESENTA UN HALOGENO COMO CL O BR Y R1 REPRESENTA UN RADICAL ALCOHILO DERIVADO DEL GERANIOL, DEL CITRONELOL O DEL 3,4,5-TRIMETOXIBENCILICO. LA REACCION DE ESTERIFICACION SE EFECTUA EN PRESENCIA DE UN DISOLVENTE INERTE COMO BENCENO.SON UTILES EN EL CAMPO DE LA AGRICULTURA POR SU ACTIVIDAD INSECTICIDA Y ACARICIDA.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES528023A ES528023A0 (es) | 1983-12-13 | 1983-12-13 | Procedimiento de preparacion de nuevos esteres del acido vinilciclopropancarboxilico en su forma racemica u opticamente activa, con actividad pesticida. |
| AR298930A AR240795A1 (es) | 1983-12-13 | 1984-12-12 | Nuevos esteres de un derivado del acido vinilciclopropancarboxilico en su forma racemica u opticamente activa y procedimiento de preparacion. |
| FR8419008A FR2556342B1 (fr) | 1983-12-13 | 1984-12-12 | Nouveaux esters d'un derive d'acide vinylcyclopropanecarboxylique sous forme racemique ou optiquement active, procede de preparation de ces nouveaux esters, utilisation de ces esters pour lutter contre les insectes ou les acariens, et composition en particulier pour lutter contre les insectes ou les acariens contenant de tels esters |
| BR8406360A BR8406360A (pt) | 1983-12-13 | 1984-12-12 | Processo de preparacao de novos esteres de derivados do acido vinilciclopropanocabo-xilico na sua forma racemica oticamente ativa |
| DE19843445504 DE3445504A1 (de) | 1983-12-13 | 1984-12-13 | Neue ester von derivaten der vinylcyclopropancarbonsaeure und verfahren zu ihrer herstellung sowie diese enthaltendes insektizides mittel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES528023A ES528023A0 (es) | 1983-12-13 | 1983-12-13 | Procedimiento de preparacion de nuevos esteres del acido vinilciclopropancarboxilico en su forma racemica u opticamente activa, con actividad pesticida. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8600199A1 true ES8600199A1 (es) | 1985-10-01 |
| ES528023A0 ES528023A0 (es) | 1985-10-01 |
Family
ID=8486588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES528023A Granted ES528023A0 (es) | 1983-12-13 | 1983-12-13 | Procedimiento de preparacion de nuevos esteres del acido vinilciclopropancarboxilico en su forma racemica u opticamente activa, con actividad pesticida. |
Country Status (5)
| Country | Link |
|---|---|
| AR (1) | AR240795A1 (es) |
| BR (1) | BR8406360A (es) |
| DE (1) | DE3445504A1 (es) |
| ES (1) | ES528023A0 (es) |
| FR (1) | FR2556342B1 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE129490T1 (de) * | 1990-07-27 | 1995-11-15 | Chinoin Gyogyszer Es Vegyeszet | Verfahren zur herstellung von optisch aktiven oder racemischen cyclopropancarbonsäurechloriden. |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3285950A (en) * | 1963-10-02 | 1966-11-15 | Hoffmann La Roche | Unsaturated esters of chrysanthemum monocarboxylic acid |
| JPS4875879A (es) * | 1972-01-17 | 1973-10-12 | ||
| JPS527427A (en) * | 1975-07-08 | 1977-01-20 | Sumitomo Chem Co Ltd | Insecticide and tickicide composition comprising a cyclopropane carbox ylic acid ester and a process for its preparation |
| JPS5473758A (en) | 1977-10-27 | 1979-06-13 | Sumitomo Chem Co Ltd | Asymmetric synthesis of chrysanthemumic acid derivative ester |
| DE2928406A1 (de) * | 1979-07-13 | 1981-01-29 | Bayer Ag | Neue menthylester, verfahren zu ihrer herstellung und ihre verwendung zur enantiomerentrennung chiraler carbonsaeuren |
| DE3127752A1 (de) * | 1981-07-14 | 1983-02-03 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von permethrinsaeurementhylester |
-
1983
- 1983-12-13 ES ES528023A patent/ES528023A0/es active Granted
-
1984
- 1984-12-12 FR FR8419008A patent/FR2556342B1/fr not_active Expired
- 1984-12-12 BR BR8406360A patent/BR8406360A/pt unknown
- 1984-12-12 AR AR298930A patent/AR240795A1/es active
- 1984-12-13 DE DE19843445504 patent/DE3445504A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| FR2556342B1 (fr) | 1988-11-25 |
| DE3445504A1 (de) | 1985-06-20 |
| FR2556342A1 (fr) | 1985-06-14 |
| BR8406360A (pt) | 1985-10-08 |
| AR240795A1 (es) | 1991-02-28 |
| ES528023A0 (es) | 1985-10-01 |
| AR240795A2 (es) | 1991-02-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Patent lapsed |
Effective date: 19960507 |