ES8602880A1 - Procedimiento para preparar composiciones predispersadas no sangrantes de peroxidos vulcanizantes - Google Patents
Procedimiento para preparar composiciones predispersadas no sangrantes de peroxidos vulcanizantesInfo
- Publication number
- ES8602880A1 ES8602880A1 ES540465A ES540465A ES8602880A1 ES 8602880 A1 ES8602880 A1 ES 8602880A1 ES 540465 A ES540465 A ES 540465A ES 540465 A ES540465 A ES 540465A ES 8602880 A1 ES8602880 A1 ES 8602880A1
- Authority
- ES
- Spain
- Prior art keywords
- butadiene
- coagent
- peroxide
- monomer
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002978 peroxides Chemical class 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000007788 liquid Substances 0.000 title 1
- 230000008018 melting Effects 0.000 title 1
- 238000002844 melting Methods 0.000 title 1
- 239000007787 solid Substances 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 12
- 239000000178 monomer Substances 0.000 abstract 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- 239000003795 chemical substances by application Substances 0.000 abstract 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 2
- -1 alkyl methacrylates Chemical class 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 2
- 229920000578 graft copolymer Polymers 0.000 abstract 2
- 239000004033 plastic Substances 0.000 abstract 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 abstract 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 abstract 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 abstract 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 abstract 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 abstract 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 abstract 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 abstract 1
- 230000000740 bleeding effect Effects 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000010410 dusting Methods 0.000 abstract 1
- 239000000383 hazardous chemical Substances 0.000 abstract 1
- 231100000206 health hazard Toxicity 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR COMPOSICIONES PREDISPERSADAS NO SANGRANTES DE PEROXIDOS VULCANIZANTES. COMPRENDE: A) MEZCLAR DE UN 20 A UN 70% EN PESO DE (A) CON (B); B) CALENTAR LA MEZCLA DE A) POR ENCIMA DEL PUNTO DE FUSION DE (A) PARA FUNDIR A (A); C) MANTENER LA MEZCLA DE (A) POR ENCIMA DEL PUNTO DE FUSION DE (A) UN TIEMPO SUFICIENTE, PARA PERMITIR QUE (A) SEA ABSORBIDO POR (B); Y D) MEZCLAR LA MEZCLA CALIENTE DE (A) CON (B), DURANTE UN TIEMPO SUFICIENTE PARA PREPARAR UNA COMPOSICION HOMOGENEA PREDISPERSADA. SIENDO (A) AGENTE VULCANIZANTE DE PEROXIDO QUE SE SELECCIONA ENTRE PEROXIDO DE DICUMILO Y A,A-BIS-(T-BUTILPEROXI)-DIISOPROPILBENCENO Y (B) UN COPOLIMERO DE INJERTO DE ETAPAS MULTIPLES COMPUESTO POR UN 70 A 90% EN PESO DE UNA PORCION DURA DERIVADA DE MONOMEROS SELECCIONADO ENTRE METACRILATOS DE ALQUILO INFERIOR Y DE UNA CANTIDAD DE AGENTE RETICULANTE SELECCIONADO ENTRE ESTERES DE ACIDOS DIMETACRILICO, TRIMETACRILICO Y OTROS Y POR UN 10 A 30% EN PESO DE UNA PORCION CAUCHUTOSA FORMADA PORMONOMEROS SELECCIONADOS ENTRE ACRILATOS DE ALQUILO INFERIOR, ACRILONITRILO Y BUTADIENO.-
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/370,499 US4397992A (en) | 1982-04-21 | 1982-04-21 | Predispersed liquid or low melting solid peroxide vulcanizing agent or coagent compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES540465A0 ES540465A0 (es) | 1985-12-01 |
| ES8602880A1 true ES8602880A1 (es) | 1985-12-01 |
Family
ID=23459934
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES521710A Expired ES8505391A1 (es) | 1982-04-21 | 1983-04-21 | Procedimiento para preparar composiciones predispersadas no sangrantes de peroxidos vulcanizantes. |
| ES540466A Granted ES540466A0 (es) | 1982-04-21 | 1985-02-15 | Procedimiento para preparar composiciones predispersadas no sangrantes de peroxidos vulcanizantes |
| ES540465A Expired ES8602880A1 (es) | 1982-04-21 | 1985-02-15 | Procedimiento para preparar composiciones predispersadas no sangrantes de peroxidos vulcanizantes |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES521710A Expired ES8505391A1 (es) | 1982-04-21 | 1983-04-21 | Procedimiento para preparar composiciones predispersadas no sangrantes de peroxidos vulcanizantes. |
| ES540466A Granted ES540466A0 (es) | 1982-04-21 | 1985-02-15 | Procedimiento para preparar composiciones predispersadas no sangrantes de peroxidos vulcanizantes |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4397992A (es) |
| EP (1) | EP0092244B1 (es) |
| JP (1) | JPS58194944A (es) |
| KR (1) | KR860000875B1 (es) |
| AT (1) | ATE24533T1 (es) |
| AU (1) | AU541656B2 (es) |
| BR (1) | BR8302072A (es) |
| CA (1) | CA1186832A (es) |
| DE (2) | DE92244T1 (es) |
| ES (3) | ES8505391A1 (es) |
| MX (1) | MX163142B (es) |
| PH (1) | PH17626A (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4518472A (en) * | 1982-09-10 | 1985-05-21 | Mitsubishi Rayon Company Ltd. | Delustering coating composition excellent in abrasion resistance |
| DE3300526A1 (de) * | 1983-01-10 | 1984-07-12 | Röhm GmbH, 6100 Darmstadt | Schlagzaehmodifizierungsmittel |
| IL75719A (en) * | 1984-07-18 | 1988-11-30 | Du Pont Canada | Polyolefin blends containing reactive agents |
| JPS62288645A (ja) * | 1986-06-06 | 1987-12-15 | Japan Synthetic Rubber Co Ltd | 熱可塑性樹脂組成物 |
| US4911961A (en) * | 1986-11-06 | 1990-03-27 | Siemens Aktiengesellschaft | Plastic covering for anti-corrosion protection of articles and the like |
| JPH0247118A (ja) * | 1988-08-10 | 1990-02-16 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂用耐候性耐衝撃性改質剤 |
| US5238978A (en) * | 1989-10-13 | 1993-08-24 | Elf Atochem North America Inc. | Peroxide masterbatches using polycaprolactone as the carrier |
| DE4106909A1 (de) * | 1991-03-05 | 1992-09-10 | Basf Ag | Mehrstufiges pfropfcopolymerisat und seine verwendung zur herstellung transparenter pvc-formmassen |
| EP0537006A3 (en) * | 1991-10-10 | 1993-06-16 | Elastochem, Inc. | Fluxed composites |
| US5614592A (en) * | 1993-06-15 | 1997-03-25 | Akzo Nobel N.V. | Filler-free peroxide masterbatch and process for making it |
| DE4440674A1 (de) * | 1994-11-14 | 1996-05-15 | Basf Ag | Verfahren zur Herstellung von kautschukmodifizierten Formmassen unter Verwendung von Peroxygruppen aufweisenden Verbindungen |
| DE19623661A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Verfahren zur Herstellung von mit Acrylkautschuk modifizierten Formmassen mittels in den Acrylkautschuk eingebauten Gruppen, die mit einer Redoxkomponente zu Radikalen zersetzt werden |
| US6194504B1 (en) * | 1997-04-28 | 2001-02-27 | Sartomer Technologies, Inc. | Process for compounding metal salts in elastomers |
| CN1073577C (zh) * | 1998-09-30 | 2001-10-24 | 复旦大学 | 一种丙烯腈、苯乙烯与聚丙烯酸酯接枝共聚物的制备方法 |
| US7468412B2 (en) * | 2005-10-05 | 2008-12-23 | Geo Specialty Chemicals, Inc. | Method and composition for the suppression of bloom in peroxide crosslinked polymeric articles |
| WO2007056154A2 (en) * | 2005-11-04 | 2007-05-18 | Dow Global Technologies Inc. | Coagent-mediated, grafted copolymers |
| CN104140634A (zh) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | 用于制造旅行箱壳的再生abs塑料及其制备方法 |
| CN104140635A (zh) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | 用微交联法增强增韧回收abs塑料及其制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA647433A (en) * | 1955-05-18 | 1962-08-28 | General Electric Company | Peroxide cured polyethylene |
| US2928801A (en) * | 1955-12-22 | 1960-03-15 | Gen Electric | Polyethylene composition containing di-alpha-cumyl peroxide, silica, and a stabilizer, and process of making same |
| US2985632A (en) * | 1956-12-04 | 1961-05-23 | Hercules Powder Co Ltd | Gr-s cured with dicamyl peroxide and sulfur |
| US3396152A (en) * | 1964-03-23 | 1968-08-06 | Firestone Tire & Rubber Co | Process of curing an acrylic elastomer |
| US3655825A (en) * | 1969-03-24 | 1972-04-11 | Rohm & Haas | Acrylic impact resistant modifiers for polyvinyl chloride |
| US3867481A (en) * | 1970-06-02 | 1975-02-18 | Rohm & Haas | Low molecular weight acrylic modifiers for rigid vinyl halide polymers |
| US3894979A (en) * | 1972-05-08 | 1975-07-15 | Akron Rubber Dev Lab Inc | Composition and method for making uniformly dispersed friable compounding ingredients |
| US3880791A (en) * | 1973-05-31 | 1975-04-29 | United States Steel Corp | Cross linkable thermoplastic adhesives |
| US3945966A (en) * | 1974-05-29 | 1976-03-23 | Horizons Incorporated A Division Of Horizons Research Incorporated | Vulcanization of fluoroalkoxyphosphazene polymers |
| US4048036A (en) * | 1974-10-24 | 1977-09-13 | Ppg Industries, Inc. | Process for producing films of low gloss by exposure to ultraviolet light |
| US4015058A (en) * | 1974-11-27 | 1977-03-29 | Union Carbide Corporation | Composition with dicumyl peroxide and process for avoiding scorching of ethylene polymer composition |
| US4025706A (en) * | 1974-11-27 | 1977-05-24 | Union Carbide Corporation | Composition with peroxides and process for avoiding scorching of ethylene polymer composition |
| US4006283A (en) * | 1974-12-23 | 1977-02-01 | General Electric Company | Preparation of di-tertiary butyl peroxide crosslink polyolefin materials |
| FR2297713A1 (fr) * | 1975-01-17 | 1976-08-13 | Telecommunications Sa | Procede d'introduction |
| US3985704A (en) * | 1975-06-19 | 1976-10-12 | Rohm And Haas Company | Methacrylate-butadiene-styrene graft polymers and process for their production |
| US4092285A (en) * | 1976-07-30 | 1978-05-30 | Wyrough And Loser, Inc. | Encapsulation of critical chemicals |
| US4110240A (en) * | 1977-07-29 | 1978-08-29 | Wyrough And Loser, Inc. | Coprecipitation process |
| JPS6019745B2 (ja) * | 1978-03-27 | 1985-05-17 | 三井化学株式会社 | ペルオキシド組成物、その製法、その用途 |
| US4202790A (en) * | 1978-06-26 | 1980-05-13 | Hercules Incorporated | Peroxide blends |
| US4268637A (en) * | 1979-06-07 | 1981-05-19 | Hercules Incorporated | Elimination of bloom in [vul-cup] peroxide crosslinked elastomer compounds |
-
1982
- 1982-04-21 US US06/370,499 patent/US4397992A/en not_active Expired - Lifetime
-
1983
- 1983-04-13 AU AU13470/83A patent/AU541656B2/en not_active Ceased
- 1983-04-15 CA CA000425924A patent/CA1186832A/en not_active Expired
- 1983-04-18 PH PH28789A patent/PH17626A/en unknown
- 1983-04-20 DE DE198383103832T patent/DE92244T1/de active Pending
- 1983-04-20 BR BR8302072A patent/BR8302072A/pt not_active IP Right Cessation
- 1983-04-20 EP EP83103832A patent/EP0092244B1/en not_active Expired
- 1983-04-20 AT AT83103832T patent/ATE24533T1/de not_active IP Right Cessation
- 1983-04-20 DE DE8383103832T patent/DE3368665D1/de not_active Expired
- 1983-04-21 KR KR1019830001680A patent/KR860000875B1/ko not_active Expired
- 1983-04-21 ES ES521710A patent/ES8505391A1/es not_active Expired
- 1983-04-21 JP JP58070877A patent/JPS58194944A/ja active Granted
- 1983-04-21 MX MX197004A patent/MX163142B/es unknown
-
1985
- 1985-02-15 ES ES540466A patent/ES540466A0/es active Granted
- 1985-02-15 ES ES540465A patent/ES8602880A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58194944A (ja) | 1983-11-14 |
| CA1186832A (en) | 1985-05-07 |
| EP0092244A2 (en) | 1983-10-26 |
| KR850001244A (ko) | 1985-03-16 |
| AU1347083A (en) | 1983-10-27 |
| DE92244T1 (de) | 1984-08-30 |
| MX163142B (es) | 1991-08-30 |
| PH17626A (en) | 1984-10-11 |
| DE3368665D1 (en) | 1987-02-05 |
| ES8602881A1 (es) | 1985-12-01 |
| KR860000875B1 (ko) | 1986-07-11 |
| BR8302072A (pt) | 1983-12-27 |
| EP0092244A3 (en) | 1984-07-04 |
| ES540465A0 (es) | 1985-12-01 |
| EP0092244B1 (en) | 1986-12-30 |
| ES521710A0 (es) | 1985-05-16 |
| JPS6137302B2 (es) | 1986-08-22 |
| ATE24533T1 (de) | 1987-01-15 |
| AU541656B2 (en) | 1985-01-17 |
| ES8505391A1 (es) | 1985-05-16 |
| US4397992A (en) | 1983-08-09 |
| ES540466A0 (es) | 1985-12-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20050712 |