ES8608465A1 - Un procedimiento para preparar alquilen-glicoles a partir deoxido de alquileno y agua - Google Patents
Un procedimiento para preparar alquilen-glicoles a partir deoxido de alquileno y aguaInfo
- Publication number
- ES8608465A1 ES8608465A1 ES541612A ES541612A ES8608465A1 ES 8608465 A1 ES8608465 A1 ES 8608465A1 ES 541612 A ES541612 A ES 541612A ES 541612 A ES541612 A ES 541612A ES 8608465 A1 ES8608465 A1 ES 8608465A1
- Authority
- ES
- Spain
- Prior art keywords
- hydrolysis
- processes
- organometalates
- alkylene oxides
- organometalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000002947 alkylene group Chemical group 0.000 title abstract 2
- 230000007062 hydrolysis Effects 0.000 title abstract 2
- 238000006460 hydrolysis reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000000087 stabilizing effect Effects 0.000 abstract 2
- -1 alkylene glycols Chemical class 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
- C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
- C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE ALQUILENGLICOLES A PARTIR DE OXIDO DE ALQUILENO Y AGUA. CONSISTE EN LA REACCION DE OXIDO DE ALQUILENO Y AGUA, EN UNA ZONA DE HIDROLISIS, EN PRESENCIA DE UNA FASE INSOLUBLE EN AGUA QUE CONTIENE COMO MEJORADOR DE LA SELECTIVIDAD UN ORGANOMETALATO DISOCIABLE CON UN CATION QUE CONTIENE COMPONENTE ORGANICO, DE FORMULA (RO)M YNXB, EN LA QUE Y ES UN ELEMENTO POLIVALENTE, CENTRO PORTADOR DE CARGA IONICA, RO REPRESENTA HIDROGENO O UN SUSTITUYENTE CON HIDROCARBILO, M ES EL NUMERO DE PARES DE ELECTRONES COMPARTIDOS POR Y, N ES EL NUMERO DE CENTROS PORTADORES DE CARGA, Y X F N(VCM), DONDE V ES EL ESTADO DE OXIDACION DE Y; Y UN ANION METALATO DE FORMULA (A)MM(O)QC, EN LA QUE M ES UN METAL POLIVALENTE, Q ES LA CARGA NEGATIVA DEL ANION Y A ES UN SUSTITUYENTE PARA SATURAR LAS RESTANTES VALENCIAS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/594,267 US4579983A (en) | 1984-03-28 | 1984-03-28 | Process for the hydrolysis of alkylene oxides using organometalates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8608465A1 true ES8608465A1 (es) | 1986-06-16 |
| ES541612A0 ES541612A0 (es) | 1986-06-16 |
Family
ID=24378211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES541612A Expired ES8608465A1 (es) | 1984-03-28 | 1985-03-27 | Un procedimiento para preparar alquilen-glicoles a partir deoxido de alquileno y agua |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4579983A (es) |
| EP (1) | EP0160329B1 (es) |
| JP (1) | JPS61501707A (es) |
| KR (1) | KR910007548B1 (es) |
| AT (1) | ATE58717T1 (es) |
| AU (1) | AU587185B2 (es) |
| BR (1) | BR8506208A (es) |
| CA (1) | CA1263874A (es) |
| DD (1) | DD238787A5 (es) |
| DE (1) | DE3580691D1 (es) |
| ES (1) | ES8608465A1 (es) |
| PL (1) | PL252604A1 (es) |
| WO (1) | WO1985004392A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU580300B2 (en) * | 1984-03-28 | 1989-01-12 | Union Carbide Corporation | Alcoholates of metalate anions and glycols produced from them |
| US4701571A (en) * | 1986-06-30 | 1987-10-20 | Union Carbide Corporation | Process for the production of alkylene glycols with metalate-containing solids |
| US5798412A (en) * | 1997-07-16 | 1998-08-25 | Huntsman Petrochemical Corporation | Alkylene glycol production using carbon catalysts |
| US6156942A (en) * | 1998-12-14 | 2000-12-05 | Shell Oil Company | Catalyst stabilizing additive in the hydrolysis of alkylene oxides |
| PE20001570A1 (es) * | 1998-12-14 | 2001-01-24 | Shell Int Research | Aditivo para la estabilizacion de catalizador en la hidrolisis de oxidos de alquileno |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4160116A (en) * | 1978-08-28 | 1979-07-03 | Showa Denko K.K. | Process for the production of alkylene glycols |
| CA1120955A (en) * | 1979-07-09 | 1982-03-30 | Toshihiko Kumazawa | Process for the production of alkylene glycols |
| JPS5673035A (en) * | 1979-11-19 | 1981-06-17 | Nippon Shokubai Kagaku Kogyo Co Ltd | Preparation of alkylene glycol |
| US4393254A (en) * | 1981-01-12 | 1983-07-12 | Texaco Inc. | Process for the production of alkylene glycols |
| JPS6056141B2 (ja) * | 1981-02-24 | 1985-12-09 | 株式会社日本触媒 | アルキレングリコールの製造方法 |
| US4551566A (en) * | 1982-09-30 | 1985-11-05 | Union Carbide Corporation | Process for the production of alkylene glycols |
-
1984
- 1984-03-28 US US06/594,267 patent/US4579983A/en not_active Expired - Lifetime
-
1985
- 1985-03-15 CA CA000476710A patent/CA1263874A/en not_active Expired
- 1985-03-26 DD DD85274450A patent/DD238787A5/de unknown
- 1985-03-27 DE DE8585200485T patent/DE3580691D1/de not_active Expired - Lifetime
- 1985-03-27 AT AT85200485T patent/ATE58717T1/de not_active IP Right Cessation
- 1985-03-27 ES ES541612A patent/ES8608465A1/es not_active Expired
- 1985-03-27 EP EP85200485A patent/EP0160329B1/en not_active Expired - Lifetime
- 1985-03-27 PL PL25260485A patent/PL252604A1/xx unknown
- 1985-03-28 AU AU42174/85A patent/AU587185B2/en not_active Ceased
- 1985-03-28 JP JP60501557A patent/JPS61501707A/ja active Granted
- 1985-03-28 BR BR8506208A patent/BR8506208A/pt unknown
- 1985-03-28 KR KR1019850700347A patent/KR910007548B1/ko not_active Expired
- 1985-03-28 WO PCT/US1985/000509 patent/WO1985004392A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DD238787A5 (de) | 1986-09-03 |
| JPH0333141B2 (es) | 1991-05-16 |
| EP0160329A1 (en) | 1985-11-06 |
| WO1985004392A1 (en) | 1985-10-10 |
| KR910007548B1 (ko) | 1991-09-27 |
| BR8506208A (pt) | 1986-04-15 |
| PL252604A1 (en) | 1985-12-03 |
| JPS61501707A (ja) | 1986-08-14 |
| AU4217485A (en) | 1985-11-01 |
| DE3580691D1 (de) | 1991-01-10 |
| EP0160329B1 (en) | 1990-11-28 |
| AU587185B2 (en) | 1989-08-10 |
| KR860700029A (ko) | 1986-01-31 |
| ATE58717T1 (de) | 1990-12-15 |
| CA1263874A (en) | 1989-12-12 |
| ES541612A0 (es) | 1986-06-16 |
| US4579983A (en) | 1986-04-01 |
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