ES8801324A1 - Un procedimiento para eliminar residuos de catalizador metalico a partir de soluciones de polimeros insolubles en agua contaminadas con uno o mas de dichos residuos. - Google Patents
Un procedimiento para eliminar residuos de catalizador metalico a partir de soluciones de polimeros insolubles en agua contaminadas con uno o mas de dichos residuos.Info
- Publication number
- ES8801324A1 ES8801324A1 ES557336A ES557336A ES8801324A1 ES 8801324 A1 ES8801324 A1 ES 8801324A1 ES 557336 A ES557336 A ES 557336A ES 557336 A ES557336 A ES 557336A ES 8801324 A1 ES8801324 A1 ES 8801324A1
- Authority
- ES
- Spain
- Prior art keywords
- acid
- metal
- mol
- soln
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 7
- 229910001385 heavy metal Inorganic materials 0.000 title 1
- 239000002184 metal Substances 0.000 abstract 8
- 229910052751 metal Inorganic materials 0.000 abstract 8
- 239000002253 acid Substances 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 150000007524 organic acids Chemical class 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- -1 alkyl hydroperoxide Chemical compound 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Substances OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000002244 precipitate Substances 0.000 abstract 2
- 229920003176 water-insoluble polymer Polymers 0.000 abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001279 adipic acids Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001536 azelaic acids Chemical class 0.000 abstract 1
- 238000005119 centrifugation Methods 0.000 abstract 1
- 239000000356 contaminant Substances 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C2/00—Treatment of rubber solutions
- C08C2/02—Purification
- C08C2/04—Removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
METODO PARA ELIMINAR RESIDUOS DE CATALIZADORES METALICOS DE DISOLUCIONES DE POLIMEROS CON UNO O MAS ACIDOS DICARBOXILICOS EN EXCESO, PARA PRECIPITAR LOS METALES, SEGUIDO DE LA SEPARACION DELOS PRECIPITADOS FORMADOS MEDIANTE FILTRACION O CENTRIFUGACION. TIENE APLICACIONES PARA LA PURIFICACION DE DISOLUCIONES DE POLIMEROS RESULTANTES DE PROCESOS DE HIDROGENACION CATALITICA.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US67397984A | 1984-11-23 | 1984-11-23 | |
| US06/673,978 US4595749A (en) | 1984-11-23 | 1984-11-23 | Direct removal of NI catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES557336A0 ES557336A0 (es) | 1987-12-16 |
| ES8801324A1 true ES8801324A1 (es) | 1987-12-16 |
Family
ID=27101063
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES549127A Expired ES8704981A1 (es) | 1984-11-23 | 1985-11-21 | Un procedimiento para eliminar residuos de catalizador meta-lico a partir de soluciones de polimeros insolubles en agua,contaminadas con uno o mas de dichos residuos |
| ES557336A Expired ES8801324A1 (es) | 1984-11-23 | 1987-01-15 | Un procedimiento para eliminar residuos de catalizador metalico a partir de soluciones de polimeros insolubles en agua contaminadas con uno o mas de dichos residuos. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES549127A Expired ES8704981A1 (es) | 1984-11-23 | 1985-11-21 | Un procedimiento para eliminar residuos de catalizador meta-lico a partir de soluciones de polimeros insolubles en agua,contaminadas con uno o mas de dichos residuos |
Country Status (5)
| Country | Link |
|---|---|
| EP (2) | EP0358283B1 (es) |
| JP (1) | JPH0651739B2 (es) |
| CA (1) | CA1263988A (es) |
| DE (2) | DE3587932T2 (es) |
| ES (2) | ES8704981A1 (es) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USH1303H (en) | 1990-05-24 | 1994-04-05 | Shell Oil Company | Removal of nickel catalyst from polymer solutions by water addition and centrifugation |
| US5212285A (en) * | 1990-06-14 | 1993-05-18 | Shell Oil Company | Removal of hydrogenation catalyst from polymer solutions by catalyzed precipitation |
| US5242961A (en) * | 1992-05-28 | 1993-09-07 | Shell Oil Company | Color prevention in titanium catalyzed hydrogenated diene polymers |
| USH1703H (en) * | 1995-12-28 | 1998-01-06 | Shell Oil Company | Removal of lithium from polymer cements |
| GB2308596A (en) * | 1995-12-28 | 1997-07-02 | Shell Int Research | Removal of alkali metal from polymer cements |
| US5767207A (en) * | 1995-12-28 | 1998-06-16 | Shell Oil Company | Removal of lithium from polymer cements |
| BR9803201A (pt) * | 1997-08-22 | 1999-12-21 | Shell Int Research | Extração de resíduos metálicos a partir de cimentos poliméricos. |
| US6153727A (en) * | 1998-08-18 | 2000-11-28 | Shell Oil Company | Extraction of metal residues from polymer cements |
| US6433102B1 (en) | 1998-12-04 | 2002-08-13 | Nippon Zeon Co., Ltd. | Hydrogenated polymers, resin composition, and process for producing substrate for information-recording medium |
| EP1059306A1 (en) * | 1999-06-10 | 2000-12-13 | Fina Research S.A. | Production of haze-free block copolymers |
| EP1059307A1 (en) * | 1999-06-10 | 2000-12-13 | Fina Research S.A. | Production of haze-free block copolymers |
| JP4482994B2 (ja) * | 1999-12-27 | 2010-06-16 | 住友化学株式会社 | 高分子蛍光体の製造方法および高分子発光素子 |
| JP2002308905A (ja) * | 2001-04-18 | 2002-10-23 | Kuraray Co Ltd | 水添ジエン系重合体の製造方法 |
| FR2878250B1 (fr) * | 2004-11-22 | 2007-01-12 | Solvay Sa Sa Belge | Procede pour l'epuration en metaux lourds de polymeres du chlorure de vinyle (pvc) |
| JP4984243B2 (ja) * | 2007-07-13 | 2012-07-25 | 大塚化学株式会社 | ビニル系重合体の製造方法 |
| KR100910255B1 (ko) * | 2007-10-08 | 2009-07-31 | 금호석유화학 주식회사 | 수소화된 공역디엔계 중합체의 제조방법 |
| EP2918610A1 (en) * | 2014-03-10 | 2015-09-16 | LANXESS Deutschland GmbH | Process for the preparation of polymers containing amino groups employing a heterogeneous iron catalyst |
| JP2016145268A (ja) * | 2015-02-06 | 2016-08-12 | 株式会社カネカ | 重合体の製造方法 |
| CN114392724B (zh) * | 2022-01-19 | 2024-06-25 | 万华化学集团股份有限公司 | 一种聚烯烃专用脱灰吸附剂、制备方法与应用 |
| CN114471471B (zh) * | 2022-01-28 | 2024-06-25 | 万华化学集团股份有限公司 | 用于去除聚烯烃中残留金属的吸附剂、其制备方法与应用 |
| CN116655853B (zh) * | 2023-06-06 | 2025-07-15 | 中国石油天然气股份有限公司 | 一种聚合物脱金属的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB788967A (en) * | 1954-12-27 | 1958-01-08 | Phillips Petroleum Co | Method for decolorizing hydrogenated polymers |
| US3176000A (en) * | 1961-09-25 | 1965-03-30 | Phillips Petroleum Co | Process for treatment of solid olefin polymers for removal of initiator residues |
| BE788698A (fr) * | 1971-09-14 | 1973-03-12 | Shell Int Research | Procede d'elimination de contaminants metalliques dans un polymere |
| US4028485A (en) * | 1976-01-29 | 1977-06-07 | Mobil Oil Corporation | Non-aqueous removal of soluble hydrogenation catalyst |
| JPS5830885B2 (ja) * | 1978-02-27 | 1983-07-02 | 住友化学工業株式会社 | ポリオレフィンの精製法 |
| US4403074A (en) * | 1982-01-13 | 1983-09-06 | Phillips Petroleum Company | Clear haze-free impact-resistant resinous polymers |
-
1985
- 1985-10-30 DE DE19853587932 patent/DE3587932T2/de not_active Expired - Fee Related
- 1985-10-30 EP EP89202914A patent/EP0358283B1/en not_active Expired - Lifetime
- 1985-10-30 DE DE8585201765T patent/DE3582788D1/de not_active Expired - Lifetime
- 1985-10-30 EP EP19850201765 patent/EP0186918B1/en not_active Expired
- 1985-11-12 CA CA000495126A patent/CA1263988A/en not_active Expired
- 1985-11-21 ES ES549127A patent/ES8704981A1/es not_active Expired
- 1985-11-21 JP JP60259943A patent/JPH0651739B2/ja not_active Expired - Fee Related
-
1987
- 1987-01-15 ES ES557336A patent/ES8801324A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0186918B1 (en) | 1991-05-08 |
| ES557336A0 (es) | 1987-12-16 |
| EP0186918A3 (en) | 1988-03-30 |
| EP0358283A3 (en) | 1990-05-16 |
| EP0358283B1 (en) | 1994-09-28 |
| CA1263988A (en) | 1989-12-19 |
| DE3582788D1 (de) | 1991-06-13 |
| JPS61130304A (ja) | 1986-06-18 |
| JPH0651739B2 (ja) | 1994-07-06 |
| EP0186918A2 (en) | 1986-07-09 |
| DE3587932T2 (de) | 1995-03-02 |
| ES549127A0 (es) | 1987-04-16 |
| ES8704981A1 (es) | 1987-04-16 |
| EP0358283A2 (en) | 1990-03-14 |
| DE3587932D1 (de) | 1994-11-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20041102 |