FI108444B - Menetelmõ kiinteõn katalyyttikomponentin valmistamiseksi eteenin ja alfa-olefiinien (ko)polymerointia varten - Google Patents

Menetelmõ kiinteõn katalyyttikomponentin valmistamiseksi eteenin ja alfa-olefiinien (ko)polymerointia varten Download PDF

Info

Publication number: FI108444B
Authority: FI; Finland
Prior art keywords: group; titanium; aluminum; ethylene; mmol
Prior art date: 1991-07-12

Application number

FI923152A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI923152L (fi

FI923152A0 (fi

Inventor

Renzo Invernizzi

Francesco Masi

Angelo Moalli

Francesco Menconi

Cesare Ferrero

Lia Barazzoni

Sergio Masini

Original Assignee

Polimeri Europa Srl

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-07-12

Filing date

1992-07-08

Publication date

2002-01-31

1992-07-08 Application filed by Polimeri Europa Srl filed Critical Polimeri Europa Srl

1992-07-08 Publication of FI923152A0 publication Critical patent/FI923152A0/fi

1993-01-13 Publication of FI923152L publication Critical patent/FI923152L/fi

2002-01-31 Application granted granted Critical

2002-01-31 Publication of FI108444B publication Critical patent/FI108444B/fi

Links

VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 65
239000005977 Ethylene Substances 0.000 title claims abstract description 65
238000006116 polymerization reaction Methods 0.000 title claims abstract description 47
239000004711 α-olefin Substances 0.000 title claims abstract description 23
239000011949 solid catalyst Substances 0.000 title claims description 78
238000004519 manufacturing process Methods 0.000 title claims description 4
239000010936 titanium Substances 0.000 claims abstract description 142
238000000034 method Methods 0.000 claims abstract description 102
229910052719 titanium Inorganic materials 0.000 claims abstract description 101
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 84
239000003054 catalyst Substances 0.000 claims abstract description 61
239000007787 solid Substances 0.000 claims abstract description 43
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 35
229910052735 hafnium Inorganic materials 0.000 claims abstract description 23
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract description 19
229910052726 zirconium Inorganic materials 0.000 claims abstract description 16
229910052751 metal Inorganic materials 0.000 claims abstract description 14
239000002184 metal Substances 0.000 claims abstract description 14
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 13
229910052736 halogen Inorganic materials 0.000 claims abstract description 12
150000002367 halogens Chemical group 0.000 claims abstract description 9
229910052720 vanadium Inorganic materials 0.000 claims abstract description 7
125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 103
239000000460 chlorine Substances 0.000 claims description 75
239000011777 magnesium Substances 0.000 claims description 72
-1 transition metal carboxylate Chemical class 0.000 claims description 66
229910052782 aluminium Inorganic materials 0.000 claims description 60
229910052749 magnesium Inorganic materials 0.000 claims description 46
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 42
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 35
229910052801 chlorine Inorganic materials 0.000 claims description 33
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 claims description 30
239000004698 Polyethylene Substances 0.000 claims description 30
229920000573 polyethylene Polymers 0.000 claims description 30
239000000725 suspension Substances 0.000 claims description 29
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 28
150000001875 compounds Chemical class 0.000 claims description 26
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
229920001577 copolymer Polymers 0.000 claims description 23
125000001309 chloro group Chemical group Cl* 0.000 claims description 19
125000000217 alkyl group Chemical group 0.000 claims description 18
GJWSUKYXUMVMGX-UHFFFAOYSA-N citronellic acid Chemical group OC(=O)CC(C)CCC=C(C)C GJWSUKYXUMVMGX-UHFFFAOYSA-N 0.000 claims description 16
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 15
229910052799 carbon Inorganic materials 0.000 claims description 14
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 14
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 13
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 13
239000002904 solvent Substances 0.000 claims description 12
229910052723 transition metal Inorganic materials 0.000 claims description 12
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 9
125000003118 aryl group Chemical group 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 9
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
229920000642 polymer Polymers 0.000 claims description 9
OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical group CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
229910052794 bromium Inorganic materials 0.000 claims description 6
125000000753 cycloalkyl group Chemical group 0.000 claims description 6
238000009826 distribution Methods 0.000 claims description 6
150000003624 transition metals Chemical class 0.000 claims description 6
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 5
125000005843 halogen group Chemical group 0.000 claims description 5
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 5
RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 5
OFJWFSNDPCAWDK-UHFFFAOYSA-N 2-phenylbutyric acid Chemical group CCC(C(O)=O)C1=CC=CC=C1 OFJWFSNDPCAWDK-UHFFFAOYSA-N 0.000 claims description 4
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 4
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 4
BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 4
125000005234 alkyl aluminium group Chemical group 0.000 claims description 3
229920013639 polyalphaolefin Polymers 0.000 claims description 3
WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical group CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 claims description 2
NMVXHZSPDTXJSJ-UHFFFAOYSA-L 2-methylpropylaluminum(2+);dichloride Chemical compound CC(C)C[Al](Cl)Cl NMVXHZSPDTXJSJ-UHFFFAOYSA-L 0.000 claims description 2
ATUUSOSLBXVJKL-UHFFFAOYSA-N 3-ethylpentanoic acid Chemical group CCC(CC)CC(O)=O ATUUSOSLBXVJKL-UHFFFAOYSA-N 0.000 claims description 2
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
239000002879 Lewis base Substances 0.000 claims description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminum chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 2
125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
239000007795 chemical reaction product Substances 0.000 claims description 2
JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 claims description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical group CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 2
JFICPAADTOQAMU-UHFFFAOYSA-L ethylaluminum(2+);dibromide Chemical compound CC[Al](Br)Br JFICPAADTOQAMU-UHFFFAOYSA-L 0.000 claims description 2
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical group CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims description 2
150000004820 halides Chemical class 0.000 claims description 2
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims description 2
239000012442 inert solvent Substances 0.000 claims description 2
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical group CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims description 2
150000007527 lewis bases Chemical class 0.000 claims description 2
125000005609 naphthenate group Chemical group 0.000 claims description 2
150000002902 organometallic compounds Chemical class 0.000 claims description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
239000008096 xylene Substances 0.000 claims description 2
239000000306 component Substances 0.000 claims 13
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims 6
HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 claims 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
238000006555 catalytic reaction Methods 0.000 claims 1
GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical group CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims 1
238000001035 drying Methods 0.000 claims 1
229920000092 linear low density polyethylene Polymers 0.000 claims 1
239000004707 linear low-density polyethylene Substances 0.000 claims 1
AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 claims 1
125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical group CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 claims 1
125000001424 substituent group Chemical group 0.000 claims 1
229920001862 ultra low molecular weight polyethylene Polymers 0.000 claims 1
ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical group CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 claims 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
150000003738 xylenes Chemical class 0.000 claims 1
238000002360 preparation method Methods 0.000 abstract description 44
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract description 4
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
230000007704 transition Effects 0.000 abstract 1
239000000243 solution Substances 0.000 description 87
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 78
229910001629 magnesium chloride Inorganic materials 0.000 description 42
239000004215 Carbon black (E152) Substances 0.000 description 24
229930195733 hydrocarbon Natural products 0.000 description 24
150000002430 hydrocarbons Chemical class 0.000 description 24
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 23
238000004458 analytical method Methods 0.000 description 23
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 22
238000006243 chemical reaction Methods 0.000 description 19
239000007858 starting material Substances 0.000 description 19
239000000047 product Substances 0.000 description 18
239000000155 melt Substances 0.000 description 17
239000002253 acid Substances 0.000 description 16
230000035945 sensitivity Effects 0.000 description 16
150000004703 alkoxides Chemical class 0.000 description 15
239000000178 monomer Substances 0.000 description 13
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
239000001257 hydrogen Substances 0.000 description 12
229910052739 hydrogen Inorganic materials 0.000 description 12
239000000706 filtrate Substances 0.000 description 11
239000000126 substance Substances 0.000 description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
229930008398 Citronellate Natural products 0.000 description 10
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 8
230000000052 comparative effect Effects 0.000 description 8
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 8
PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 8
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 6
125000004429 atom Chemical group 0.000 description 6
238000007334 copolymerization reaction Methods 0.000 description 6
OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 5
OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 5
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
238000003756 stirring Methods 0.000 description 5
150000003623 transition metal compounds Chemical class 0.000 description 5
LQIIEHBULBHJKX-UHFFFAOYSA-N 2-methylpropylalumane Chemical compound CC(C)C[AlH2] LQIIEHBULBHJKX-UHFFFAOYSA-N 0.000 description 4
239000011521 glass Substances 0.000 description 4
ZLQAEOMJXALFGU-UHFFFAOYSA-L magnesium;2-ethylhexanoate;chloride Chemical compound [Mg+2].[Cl-].CCCCC(CC)C([O-])=O ZLQAEOMJXALFGU-UHFFFAOYSA-L 0.000 description 4
239000003960 organic solvent Substances 0.000 description 4
238000001694 spray drying Methods 0.000 description 4
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 4
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
229910021550 Vanadium Chloride Inorganic materials 0.000 description 3
239000003426 co-catalyst Substances 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
NBDIBWSICNRDCX-UHFFFAOYSA-L magnesium dicarbonochloridate Chemical compound C([O-])(=O)Cl.[Mg+2].C([O-])(=O)Cl NBDIBWSICNRDCX-UHFFFAOYSA-L 0.000 description 3
RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 3
AVNXWYMQDJHNJS-UHFFFAOYSA-L 2-ethylhexanoate;titanium(2+);chloride Chemical compound [Cl-].[Ti+2].CCCCC(CC)C([O-])=O AVNXWYMQDJHNJS-UHFFFAOYSA-L 0.000 description 2
LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
OBKXEAXTFZPCHS-UHFFFAOYSA-N 4-phenylbutyric acid Chemical compound OC(=O)CCCC1=CC=CC=C1 OBKXEAXTFZPCHS-UHFFFAOYSA-N 0.000 description 2
NEJQCLQIHDVAIP-UHFFFAOYSA-L C1(=CC=CC=C1)C(C(=O)[O-])CC.[Cl-].[Hf+2] Chemical compound C1(=CC=CC=C1)C(C(=O)[O-])CC.[Cl-].[Hf+2] NEJQCLQIHDVAIP-UHFFFAOYSA-L 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
238000003556 assay Methods 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
238000010908 decantation Methods 0.000 description 2
MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 2
229910001507 metal halide Inorganic materials 0.000 description 2
150000005309 metal halides Chemical class 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
239000002002 slurry Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
ZBONBGOYILUGCL-UHFFFAOYSA-N 2,2-dimethylpropanoate Chemical compound CC(C)([CH2+])C([O-])=O ZBONBGOYILUGCL-UHFFFAOYSA-N 0.000 description 1
101100494773 Caenorhabditis elegans ctl-2 gene Proteins 0.000 description 1
101100112369 Fasciola hepatica Cat-1 gene Proteins 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
101000919504 Gallus gallus Beta-crystallin B1 Proteins 0.000 description 1
VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
101100005271 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) cat-1 gene Proteins 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000005662 Paraffin oil Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
206010042674 Swelling Diseases 0.000 description 1
241001122767 Theaceae Species 0.000 description 1
229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
150000001649 bromium compounds Chemical class 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 description 1
239000000539 dimer Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
238000009472 formulation Methods 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
230000002101 lytic effect Effects 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
HNVQVZHLQTUYIG-UHFFFAOYSA-L magnesium;2-phenylbutanoate;chloride Chemical compound [Mg+2].[Cl-].CCC(C([O-])=O)C1=CC=CC=C1 HNVQVZHLQTUYIG-UHFFFAOYSA-L 0.000 description 1
OLSMQDUPRYIMTC-UHFFFAOYSA-L magnesium;ethanol;dichloride Chemical compound [Mg+2].[Cl-].[Cl-].CCO OLSMQDUPRYIMTC-UHFFFAOYSA-L 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
229940094933 n-dodecane Drugs 0.000 description 1
239000008188 pellet Substances 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
ZDPHROOEEOARMN-UHFFFAOYSA-M undecanoate Chemical compound CCCCCCCCCCC([O-])=O ZDPHROOEEOARMN-UHFFFAOYSA-M 0.000 description 1
JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

FI923152A 1991-07-12 1992-07-08 Menetelmõ kiinteõn katalyyttikomponentin valmistamiseksi eteenin ja alfa-olefiinien (ko)polymerointia varten FI108444B (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
ITMI911935A IT1251462B (it)	1991-07-12	1991-07-12	Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine.
ITMI911935		1991-07-12

Publications (3)

Publication Number	Publication Date
FI923152A0 FI923152A0 (fi)	1992-07-08
FI923152L FI923152L (fi)	1993-01-13
FI108444B true FI108444B (fi)	2002-01-31

Family

ID=11360338

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI923152A FI108444B (fi)	1991-07-12	1992-07-08	Menetelmõ kiinteõn katalyyttikomponentin valmistamiseksi eteenin ja alfa-olefiinien (ko)polymerointia varten

Country Status (22)

Country	Link
EP (1)	EP0523785B1 (fr)
JP (1)	JP3333554B2 (fr)
KR (1)	KR950007986B1 (fr)
CN (1)	CN1048500C (fr)
AT (1)	ATE146486T1 (fr)
AU (1)	AU651898B2 (fr)
BR (1)	BR9202663A (fr)
CA (1)	CA2073590C (fr)
DE (1)	DE69215989T2 (fr)
DK (1)	DK0523785T3 (fr)
DZ (1)	DZ1595A1 (fr)
EG (1)	EG20415A (fr)
ES (1)	ES2095390T3 (fr)
FI (1)	FI108444B (fr)
GR (1)	GR3022276T3 (fr)
IT (1)	IT1251462B (fr)
MX (1)	MX9204069A (fr)
NO (1)	NO300272B1 (fr)
RU (1)	RU2098429C1 (fr)
SA (1)	SA92130191B1 (fr)
TN (1)	TNSN92059A1 (fr)
ZA (1)	ZA925106B (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1275867B1 (it) *	1995-03-07	1997-10-24	Enichem Elastomers	Procedimento per l'ottenimento di copolimeri elastomerici etilene- propilene ad alta purezza e distribuzione dei pesi molecolari
IT1311978B1 (it) *	1999-03-25	2002-03-22	Polimeri Europa Srl	Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine.
JP2001163912A (ja) *	1999-09-28	2001-06-19	Sumitomo Chem Co Ltd	オレフィン重合用固体触媒成分、オレフィン重合用触媒、オレフィン重合体の製造方法、並びにオレフィン重合用固体触媒成分の製造方法
US6933258B2 (en) *	2000-12-19	2005-08-23	Univation Technologies, L.L.C.	Catalyst composition and methods for its preparation and use in a polymerization process
US6703338B2 (en) *	2002-06-28	2004-03-09	Univation Technologies, Llc	Polymerization catalyst activators, method of preparing, and their use in polymerization processes
CN101970508B (zh)	2008-03-14	2013-03-27	沙特基础工业公司	催化剂体系及在该催化剂体系的存在下制备聚乙烯的方法
EP2284199A1 (fr)	2009-08-14	2011-02-16	Saudi Basic Industries Corporation	Système de catalyseur et procédé de production de polyéthylène
IT1397080B1 (it)	2009-11-23	2012-12-28	Polimeri Europa Spa	Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita'
WO2012041944A1 (fr) *	2010-09-30	2012-04-05	Basell Poliolefine Italia S.R.L.	Adduits de dichlorure de magnésium-alcool et composants catalytiques obtenus à partir de ceux-ci
IT1403278B1 (it) *	2010-12-20	2013-10-17	Polimeri Europa Spa	Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura
US8957235B2 (en) *	2011-12-12	2015-02-17	Chevron Phillips Chemical Company Lp	Preparation of transition metal carboxylates
CN104558273B (zh) *	2013-10-09	2016-09-21	中国石油化工股份有限公司	用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂以及烯烃聚合方法
CN104558271B (zh) *	2013-10-09	2016-09-21	中国石油化工股份有限公司	一种烯烃聚合催化剂载体及其制备方法
WO2016016355A1 (fr)	2014-07-31	2016-02-04	Versalis S.P.A.	Catalyseur solide pour la polymérisation ou copolymérisation d'α-oléfines et son procédé de préparation
CN107522808B (zh) *	2016-06-21	2020-09-15	中国石油化工股份有限公司	一种乙烯-辛烯共聚物的制备方法
CN108102014B (zh) *	2018-01-09	2020-10-27	为信（深圳）材料科技有限公司	一种球形烷氧基镁颗粒的组份及制备方法
CN113831436B (zh) *	2020-06-23	2022-10-04	中国科学院上海有机化学研究所	一类特高至超高分子量聚乙烯制造用催化剂
CN114249851B (zh) *	2020-09-24	2023-03-14	中国科学院上海有机化学研究所	一类低堆密度超高分子量聚乙烯微粉

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
LU77489A1 (fr) *	1977-06-06	1979-01-19
US4540756A (en) *	1983-11-01	1985-09-10	Hercules Incorporated	Process for making low crystallinity polyolefins
FR2624122B1 (fr) *	1987-12-03	1991-11-08	Solvay	Procede pour la polymerisation des alpha-olefines, complexes catalytiques solides utilisables pour cette polymerisation et procede pour leur preparation

1991
- 1991-07-12 IT ITMI911935A patent/IT1251462B/it active IP Right Grant
1992
- 1992-07-07 AT AT92202058T patent/ATE146486T1/de active
- 1992-07-07 AU AU19484/92A patent/AU651898B2/en not_active Ceased
- 1992-07-07 DE DE69215989T patent/DE69215989T2/de not_active Expired - Lifetime
- 1992-07-07 ES ES92202058T patent/ES2095390T3/es not_active Expired - Lifetime
- 1992-07-07 EP EP92202058A patent/EP0523785B1/fr not_active Expired - Lifetime
- 1992-07-07 DK DK92202058.1T patent/DK0523785T3/da active
- 1992-07-08 DZ DZ920085A patent/DZ1595A1/fr active
- 1992-07-08 ZA ZA925106A patent/ZA925106B/xx unknown
- 1992-07-08 FI FI923152A patent/FI108444B/fi not_active IP Right Cessation
- 1992-07-09 NO NO922710A patent/NO300272B1/no not_active IP Right Cessation
- 1992-07-10 MX MX9204069A patent/MX9204069A/es unknown
- 1992-07-10 TN TNTNSN92059A patent/TNSN92059A1/fr unknown
- 1992-07-10 RU SU925052283A patent/RU2098429C1/ru active
- 1992-07-10 CA CA002073590A patent/CA2073590C/fr not_active Expired - Lifetime
- 1992-07-11 CN CN92105697A patent/CN1048500C/zh not_active Expired - Lifetime
- 1992-07-11 EG EG38192A patent/EG20415A/xx active
- 1992-07-11 KR KR1019920012392A patent/KR950007986B1/ko not_active Expired - Lifetime
- 1992-07-13 BR BR929202663A patent/BR9202663A/pt not_active IP Right Cessation
- 1992-07-13 JP JP18540592A patent/JP3333554B2/ja not_active Expired - Lifetime
- 1992-10-24 SA SA92130191A patent/SA92130191B1/ar unknown
1997
- 1997-01-15 GR GR970400050T patent/GR3022276T3/el unknown

Also Published As

Publication number	Publication date
ITMI911935A1 (it)	1993-01-12
CA2073590A1 (fr)	1993-01-13
KR950007986B1 (ko)	1995-07-24
NO300272B1 (no)	1997-05-05
IT1251462B (it)	1995-05-15
EG20415A (en)	1999-02-28
JPH05194662A (ja)	1993-08-03
FI923152L (fi)	1993-01-13
JP3333554B2 (ja)	2002-10-15
NO922710L (no)	1993-01-13
KR930002386A (ko)	1993-02-23
AU651898B2 (en)	1994-08-04
FI923152A0 (fi)	1992-07-08
CA2073590C (fr)	2003-07-08
NO922710D0 (no)	1992-07-09
EP0523785B1 (fr)	1996-12-18
CN1048500C (zh)	2000-01-19
DZ1595A1 (fr)	2002-02-17
MX9204069A (es)	1993-07-01
DE69215989D1 (de)	1997-01-30
DK0523785T3 (da)	1997-03-24
EP0523785A2 (fr)	1993-01-20
CN1068578A (zh)	1993-02-03
EP0523785A3 (en)	1993-03-03
AU1948492A (en)	1993-01-14
ES2095390T3 (es)	1997-02-16
BR9202663A (pt)	1993-03-23
DE69215989T2 (de)	1997-06-12
SA92130191B1 (ar)	2004-06-01
RU2098429C1 (ru)	1997-12-10
ZA925106B (en)	1993-04-28
ATE146486T1 (de)	1997-01-15
ITMI911935A0 (it)	1991-07-12
TNSN92059A1 (fr)	1993-06-08
GR3022276T3 (en)	1997-04-30

Legal Events

Date	Code	Title	Description
1998-12-29	GB	Transfer or assigment of application	Owner name: POLIMERI EUROPA S.R.L.
2012-08-10	MA	Patent expired

Publication	Publication Date	Title
FI108444B (fi)	2002-01-31	Menetelmõ kiinteõn katalyyttikomponentin valmistamiseksi eteenin ja alfa-olefiinien (ko)polymerointia varten
US4530913A (en)	1985-07-23	Polymerization catalyst and method
US8143184B2 (en)	2012-03-27	Method for the preparation of olefin polymerisation catalyst
KR100853366B1 (ko)	2008-08-22	올레핀 중합체의 제조방법 및 이를 위해 선택된 촉매
US4530912A (en)	1985-07-23	Polymerization catalyst and method
SU424360A3 (ru)	1974-04-15	Способ получения полиолефинов
US4250286A (en)	1981-02-10	Ultra high efficiency catalyst for polymerizing olefins
AU661043B2 (en)	1995-07-13	Catalysts for the polymerization of olefins
US4283515A (en)	1981-08-11	Support, catalyst and process for polymerizing olefins
US4578440A (en)	1986-03-25	Polymerization catalyst and method
RU2089559C1 (ru)	1997-09-10	Твердый компонент катализатора, катализатор (со)полимеризации этилена и способ получения (со)полимеров этилена
US4525551A (en)	1985-06-25	Highly active and efficient polyolefin catalyst
US4211671A (en)	1980-07-08	Olefin polymerization catalyst
US6730627B1 (en)	2004-05-04	Solid component of catalyst for the (co) polymerization of ethylene and α-olefins
US20070003720A1 (en)	2007-01-04	Cocatalysts useful for preparing polyethylene pipe
US20070293710A1 (en)	2007-12-20	Catalyst For Olefin Polymerization Including Phenoxy Ligand And Method Of (Co) Polymerization Of Olefin Using Same
KR0164243B1 (ko)	1999-03-20	폴리올레핀의 제조방법
US20070004876A1 (en)	2007-01-04	Cocatalysts for olefin polymerizations
WO1984004925A1 (fr)	1984-12-20	PROCEDE DE POLYMERISATION D'OLEFINES UTILISANT UN CATALYSEUR PREPARE A PARTIR D'UN COMPOSE D'ORGANO-MAGNESIUM; COMPOSE CONTENANT DE l'OXYGENE OU DE L'AZOTE; SOURCE D'HALOGENURE; COMPOSE DE METAL DE TRANSITION ET AGENT REDUCTEUR
JPS5915123B2 (ja)	1984-04-07	オレフイン重合用触媒
CA1154421A (fr)	1983-09-27	Catalyseur ultra-efficace pour la polymerisation des olefines
JPH0782312A (ja)	1995-03-28	ポリエチレンの製造方法
JP3294112B2 (ja)	2002-06-24	オレフィン重合用触媒およびこれを用いるオレフィン重合体の製造法
KR830002497B1 (ko)	1983-10-27	2종 유기 티탄-크롬 천이금속 촉매조성물
JPS6369807A (ja)	1988-03-29	エチレン共重合体の製造方法