FI57431C - Foerfarande foer framstaellning av ligninharts - Google Patents

Foerfarande foer framstaellning av ligninharts Download PDF

Info

Publication number: FI57431C
Authority: FI; Finland
Prior art keywords: formaldehyde; condensation; weight; phenol; water
Prior art date: 1973-02-21

Application number

FI509/74A

Other languages

English (en)

Finnish (fi)

Other versions

FI57431B (fi

Inventor

Bengt Axel Wennerblom

Alf Hugo Karlsson

Original Assignee

Casco Ab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-02-21

Filing date

1974-02-21

Publication date

1980-08-11

1974-02-21 Application filed by Casco Ab filed Critical Casco Ab

1980-04-30 Publication of FI57431B publication Critical patent/FI57431B/fi

1980-08-11 Application granted granted Critical

1980-08-11 Publication of FI57431C publication Critical patent/FI57431C/fi

Links

WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 115
238000009833 condensation Methods 0.000 claims description 35
230000005494 condensation Effects 0.000 claims description 35
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 34
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
239000002253 acid Substances 0.000 claims description 20
239000002699 waste material Substances 0.000 claims description 17
230000002378 acidificating effect Effects 0.000 claims description 13
239000011541 reaction mixture Substances 0.000 claims description 13
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 13
238000000034 method Methods 0.000 claims description 12
239000007859 condensation product Substances 0.000 claims description 10
229920001732 Lignosulfonate Polymers 0.000 claims description 9
230000008569 process Effects 0.000 claims description 9
238000010521 absorption reaction Methods 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 3
239000004117 Lignosulphonate Substances 0.000 claims 1
229920000877 Melamine resin Polymers 0.000 claims 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims 1
235000019357 lignosulphonate Nutrition 0.000 claims 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 1
229920005989 resin Polymers 0.000 description 28
239000011347 resin Substances 0.000 description 28
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 22
229920005610 lignin Polymers 0.000 description 19
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
239000007864 aqueous solution Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 9
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 8
239000011093 chipboard Substances 0.000 description 7
239000011230 binding agent Substances 0.000 description 6
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
239000000843 powder Substances 0.000 description 6
238000003825 pressing Methods 0.000 description 6
230000006835 compression Effects 0.000 description 5
238000007906 compression Methods 0.000 description 5
239000003292 glue Substances 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 4
229920003986 novolac Polymers 0.000 description 4
239000005011 phenolic resin Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
230000008961 swelling Effects 0.000 description 4
239000000853 adhesive Substances 0.000 description 3
238000004026 adhesive bonding Methods 0.000 description 3
230000001070 adhesive effect Effects 0.000 description 3
239000003513 alkali Substances 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000006482 condensation reaction Methods 0.000 description 3
238000004821 distillation Methods 0.000 description 3
229920001568 phenolic resin Polymers 0.000 description 3
239000004848 polyfunctional curative Substances 0.000 description 3
229910000027 potassium carbonate Inorganic materials 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000002023 wood Substances 0.000 description 3
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
239000010410 layer Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000002940 repellent Effects 0.000 description 2
239000005871 repellent Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
239000002344 surface layer Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
241001268128 Phenolia Species 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
230000009471 action Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000005452 bending Methods 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229920005551 calcium lignosulfonate Polymers 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
150000001728 carbonyl compounds Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000011094 fiberboard Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000002655 kraft paper Substances 0.000 description 1
238000003475 lamination Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
238000004904 shortening Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000000542 sulfonic acid group Chemical group 0.000 description 1
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
239000002966 varnish Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
General Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Biochemistry (AREA)
Materials Engineering (AREA)
Phenolic Resins Or Amino Resins (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

FI509/74A 1973-02-21 1974-02-21 Foerfarande foer framstaellning av ligninharts FI57431C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
SE7302412		1973-02-21
SE7302412A SE371645B (de)	1973-02-21	1973-02-21

Publications (2)

Publication Number	Publication Date
FI57431B FI57431B (fi)	1980-04-30
FI57431C true FI57431C (fi)	1980-08-11

Family

ID=20316700

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI509/74A FI57431C (fi)	1973-02-21	1974-02-21	Foerfarande foer framstaellning av ligninharts

Country Status (4)

Country	Link
US (1)	US3940352A (de)
FI (1)	FI57431C (de)
NO (1)	NO740573L (de)
SE (1)	SE371645B (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4168252A (en) *	1972-09-04	1979-09-18	Toshiaki Makino	Process for manufacturing organosilicon synthetic resin from alkali pulp black liquor
US4130515A (en) *	1977-06-30	1978-12-19	Georgia-Pacific Corporation	Lignin-based composition board binder comprising a copolymer of a lignosulfonate, melamine and an aldehyde
US4177313A (en) *	1978-11-28	1979-12-04	Georgia-Pacific Corporation	Amine-modified lignosulfonate-extended phenol formaldehyde resins
US4215212A (en) *	1979-04-09	1980-07-29	Akzona Incorporated	Regenerated cellulose containing cross linked sodium lignate or sodium lignosulfonate
CA1138589A (en) *	1979-04-20	1982-12-28	Krishan K. Sudan	Lignosulphonate phenolic resin binder
US4423173A (en) *	1982-09-29	1983-12-27	Masonite Corporation	Lignosulfonate-phenol-formaldehyde resin binder
US4701383A (en) *	1982-09-29	1987-10-20	Masonite Corporation	Lignosulfonate-phenol-formaldehyde resin binder in sheet material and method of making said sheet material
USRE32408E (en) *	1982-09-29	1987-04-28	Masonite Corporation	Lignosulfonate-phenol-formaldehyde resin binder
US4559097A (en) *	1982-09-29	1985-12-17	Masonite Corporation	Method of bonding using a lignosulfonate-phenol-formaldehyde resin binder
US4404334A (en) *	1982-11-18	1983-09-13	Georgia-Pacific Corporation	Thermosetting resinous polyol
CA1214293A (en) *	1983-05-31	1986-11-18	Louis R. Calve	Nh.sub.4ssl-pf thermosetting resin and method of binding lignocellulosic material employing same
CA1245784A (en) *	1985-05-09	1988-11-29	Shui-Tung Chiu	Phenolic compound-modified spent sulfite liquor and process for preparing same
US10808068B2 (en) *	2018-01-26	2020-10-20	Hexion Inc.	Manufacture of novolacs and resoles using lignin

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2282518A (en) *	1936-04-09	1942-05-12	Mead Corp	Preparation of phenol-ligninaldehyde resins
US2794790A (en) *	1953-11-02	1957-06-04	Ontario Research Foundation	Preparation of thermosetting binders from phenol derivatives of waste sulphite liquor
US3227667A (en) *	1960-09-21	1966-01-04	Borden Co	Lignin, phenol, and aldehyde condensation process and product

1973
- 1973-02-21 SE SE7302412A patent/SE371645B/xx unknown
1974
- 1974-02-20 NO NO740573A patent/NO740573L/no unknown
- 1974-02-21 US US05/444,447 patent/US3940352A/en not_active Expired - Lifetime
- 1974-02-21 FI FI509/74A patent/FI57431C/fi active

Also Published As

Publication number	Publication date
US3940352A (en)	1976-02-24
FI57431B (fi)	1980-04-30
NO135425C (de)	1977-04-05
SE371645B (de)	1974-11-25
DE2408441B2 (de)	1977-04-21
DE2408441A1 (de)	1974-08-29
NO740573L (no)	1974-08-22
NO135425B (de)	1976-12-27

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EP2758457B1 (de)	2016-03-09	Verfahren zur erhöhung der lignin-reaktivität
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EP3612586A1 (de)	2020-02-26	Phenolfreies imprägnierharz
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CA3120737A1 (en)	2020-06-04	Process for preparing a solution of lignin in an aqueous medium
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Maree et al.	2022	Lignin phenol formaldehyde resins synthesised using South African spent pulping liquor
JP2018141152A (ja)	2018-09-13	熱硬化性フェノール樹脂の製造方法及び前記方法より得られるフェノール樹脂
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US4201851A (en)	1980-05-06	Organic phenol extract compositions of pecan pith agricultural residues and method
US4200723A (en)	1980-04-29	Organic phenol extract compositions of peanut hull agricultural residues and method
FI129584B (en)	2022-05-13	Resin composition
WO2024134449A1 (en)	2024-06-27	Improved bonding resin
US4201699A (en)	1980-05-06	Phenol-aldehyde resin composition containing pecan pith extract and an aldehyde
DE4030718A1 (de)	1992-04-02	Verfahren zur herstellung eines bindemittels auf ligninbasis
WO1998050467A1 (fr)	1998-11-12	Composition de resine et panneau realise avec cette resine
US4469858A (en)	1984-09-04	Tree foliage extracts and their use in phenol-aldehyde resins
JPWO1998050467A1 (ja)	2000-06-27	樹脂組成物及びそれを使用したボード
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