FI59417C - Foerfarande foer framstaellning av olefinpolymerer - Google Patents

Foerfarande foer framstaellning av olefinpolymerer Download PDF

Info

Publication number: FI59417C
Authority: FI; Finland
Prior art keywords: catalyst; melt index; polymers; temperature; polymer
Prior art date: 1974-05-03

Application number

FI750769A

Other languages

English (en)

Finnish (fi)

Other versions

FI59417B (fi

FI750769A7 (fr

Inventor

Donald Dwight Norwood

Karl Meixner

Original Assignee

Phillips Petroleum Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-05-03

Filing date

1975-03-17

Publication date

1981-08-10

1975-03-17 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1975-11-04 Publication of FI750769A7 publication Critical patent/FI750769A7/fi

1981-04-30 Publication of FI59417B publication Critical patent/FI59417B/fi

1981-08-10 Application granted granted Critical

1981-08-10 Publication of FI59417C publication Critical patent/FI59417C/fi

Links

239000003054 catalyst Substances 0.000 description 37
229920000642 polymer Polymers 0.000 description 36
238000000034 method Methods 0.000 description 24
229920001577 copolymer Polymers 0.000 description 19
239000000155 melt Substances 0.000 description 12
239000000243 solution Substances 0.000 description 11
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 10
150000004703 alkoxides Chemical class 0.000 description 10
229910052782 aluminium Inorganic materials 0.000 description 9
239000005977 Ethylene Substances 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 7
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 7
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
230000035945 sensitivity Effects 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
239000003085 diluting agent Substances 0.000 description 5
238000009826 distribution Methods 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
125000001183 hydrocarbyl group Chemical group 0.000 description 5
229920000098 polyolefin Polymers 0.000 description 5
150000001336 alkenes Chemical class 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
150000001845 chromium compounds Chemical class 0.000 description 4
229910000423 chromium oxide Inorganic materials 0.000 description 4
239000001282 iso-butane Substances 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
230000035882 stress Effects 0.000 description 4
239000002253 acid Substances 0.000 description 3
230000004913 activation Effects 0.000 description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
229940117975 chromium trioxide Drugs 0.000 description 3
GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000000071 blow moulding Methods 0.000 description 2
PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
230000001276 controlling effect Effects 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000000178 monomer Substances 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000002002 slurry Substances 0.000 description 2
150000003609 titanium compounds Chemical class 0.000 description 2
JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
SDTMFDGELKWGFT-UHFFFAOYSA-N 2-methylpropan-2-olate Chemical compound CC(C)(C)[O-] SDTMFDGELKWGFT-UHFFFAOYSA-N 0.000 description 1
LQIIEHBULBHJKX-UHFFFAOYSA-N 2-methylpropylalumane Chemical compound CC(C)C[AlH2] LQIIEHBULBHJKX-UHFFFAOYSA-N 0.000 description 1
BCEIUDAMUFAQMG-UHFFFAOYSA-M CC(C)(C)O[Cr](O)(=O)=O Chemical compound CC(C)(C)O[Cr](O)(=O)=O BCEIUDAMUFAQMG-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
FUWMBNHWYXZLJA-UHFFFAOYSA-N [Si+4].[O-2].[Ti+4].[O-2].[O-2].[O-2] Chemical compound [Si+4].[O-2].[Ti+4].[O-2].[O-2].[O-2] FUWMBNHWYXZLJA-UHFFFAOYSA-N 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000010533 azeotropic distillation Methods 0.000 description 1
ICEQTWAHBIDMIH-UHFFFAOYSA-N bis(2-methylpropyl)alumanylium;2-methylpropan-1-olate Chemical compound CC(C)C[O-].CC(C)C[Al+]CC(C)C ICEQTWAHBIDMIH-UHFFFAOYSA-N 0.000 description 1
UDGQVBVWZIGNSE-UHFFFAOYSA-N butan-1-olate (4-methylphenyl)aluminum(2+) Chemical compound [O-]CCCC.[O-]CCCC.C1(=CC=C(C=C1)[Al+2])C UDGQVBVWZIGNSE-UHFFFAOYSA-N 0.000 description 1
239000001273 butane Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
XEHUIDSUOAGHBW-UHFFFAOYSA-N chromium;pentane-2,4-dione Chemical compound [Cr].CC(=O)CC(C)=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O XEHUIDSUOAGHBW-UHFFFAOYSA-N 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
UWAMTZZJXXCIOH-UHFFFAOYSA-M diethyl(phenoxy)alumane Chemical compound CC[Al+]CC.[O-]C1=CC=CC=C1 UWAMTZZJXXCIOH-UHFFFAOYSA-M 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
MWNKMBHGMZHEMM-UHFFFAOYSA-N dimethylalumanylium;ethanolate Chemical compound CCO[Al](C)C MWNKMBHGMZHEMM-UHFFFAOYSA-N 0.000 description 1
ORVACBDINATSAR-UHFFFAOYSA-N dimethylaluminum Chemical compound C[Al]C ORVACBDINATSAR-UHFFFAOYSA-N 0.000 description 1
HJXLFUBYELPHMP-UHFFFAOYSA-M diphenylalumanylium;phenoxide Chemical compound [O-]C1=CC=CC=C1.C=1C=CC=CC=1[Al+]C1=CC=CC=C1 HJXLFUBYELPHMP-UHFFFAOYSA-M 0.000 description 1
XOCWTYIVWYOSGQ-UHFFFAOYSA-N dipropylalumane Chemical compound C(CC)[AlH]CCC XOCWTYIVWYOSGQ-UHFFFAOYSA-N 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000006353 environmental stress Effects 0.000 description 1
HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
DSQUOVKGANUBRC-UHFFFAOYSA-N propoxy(dipropyl)alumane Chemical compound CCCO[Al](CCC)CCC DSQUOVKGANUBRC-UHFFFAOYSA-N 0.000 description 1
239000011819 refractory material Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000008698 shear stress Effects 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

FI750769A 1974-05-03 1975-03-17 Foerfarande foer framstaellning av olefinpolymerer FI59417C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US46669274A	1974-05-03	1974-05-03
US46669274		1974-05-03

Publications (3)

Publication Number	Publication Date
FI750769A7 FI750769A7 (fr)	1975-11-04
FI59417B FI59417B (fi)	1981-04-30
FI59417C true FI59417C (fi)	1981-08-10

Family

ID=23852742

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI750769A FI59417C (fi)	1974-05-03	1975-03-17	Foerfarande foer framstaellning av olefinpolymerer

Country Status (10)

Country	Link
JP (1)	JPS5117993A (fr)
BE (1)	BE828671A (fr)
CA (1)	CA1073891A (fr)
DE (1)	DE2519320C3 (fr)
ES (1)	ES436783A1 (fr)
FI (1)	FI59417C (fr)
FR (1)	FR2269537B1 (fr)
GB (1)	GB1501728A (fr)
IT (1)	IT1037349B (fr)
NO (1)	NO145530C (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS55114556A (en) *	1979-02-22	1980-09-03	Nrm Corp	Belt folding machine and its belt folding method
JPS56120329A (en) *	1980-02-28	1981-09-21	Mitsubishi Heavy Ind Ltd	Turning-up method for ply
WO1994013708A1 (fr) *	1992-12-17	1994-06-23	Neste Oy	Procede de polymerisation d'ethylene a l'aide d'un catalyseur renfermant du chrome, et polymere d'ethylene ainsi obtenu
EP0905148B1 (fr) *	1997-09-27	2003-02-05	ATOFINA Research	Catalyseurs pour la fabrication de polyéthylène et leur utilisation
US7388059B2 (en)	2004-06-28	2008-06-17	Japan Polyethylene Corporation	Ethylene polymer, catalyst for producing thereof and method for producing thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5029944B2 (fr) *	1972-06-30	1975-09-27

1975
- 1975-02-13 CA CA220,076A patent/CA1073891A/fr not_active Expired
- 1975-03-17 FI FI750769A patent/FI59417C/fi not_active IP Right Cessation
- 1975-04-07 JP JP50042156A patent/JPS5117993A/ja active Pending
- 1975-04-17 IT IT22464/75A patent/IT1037349B/it active
- 1975-04-18 GB GB16117/75A patent/GB1501728A/en not_active Expired
- 1975-04-21 ES ES436783A patent/ES436783A1/es not_active Expired
- 1975-04-30 DE DE2519320A patent/DE2519320C3/de not_active Expired
- 1975-04-30 FR FR7513701A patent/FR2269537B1/fr not_active Expired
- 1975-05-02 NO NO751577A patent/NO145530C/no unknown
- 1975-05-02 BE BE156014A patent/BE828671A/fr not_active IP Right Cessation

Also Published As

Publication number	Publication date
JPS5117993A (fr)	1976-02-13
FR2269537A1 (fr)	1975-11-28
DE2519320B2 (de)	1979-12-20
GB1501728A (en)	1978-02-22
ES436783A1 (es)	1977-01-01
NO145530B (no)	1982-01-04
IT1037349B (it)	1979-11-10
DE2519320A1 (de)	1975-11-06
NO145530C (no)	1982-04-14
FI59417B (fi)	1981-04-30
DE2519320C3 (de)	1980-09-11
CA1073891A (fr)	1980-03-18
FR2269537B1 (fr)	1980-02-08
NO751577L (fr)	1975-11-04
BE828671A (fr)	1975-11-03
FI750769A7 (fr)	1975-11-04

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: PHILLIPS PETROLEUM CO

Publication	Publication Date	Title
US3947433A (en)	1976-03-30	Supported chromium oxide catalyst having mixed adjuvant
JP6018362B2 (ja)	2016-11-02	修飾クロム系触媒およびそれを用いる重合方法
KR0161989B1 (ko)	1999-01-15	에틸렌 중합 방법
CA1142162A (fr)	1983-03-01	Methode de polymerisation, et produits de cette polymerisation
US3970613A (en)	1976-07-20	Polymerization process
RU2255094C2 (ru)	2005-06-27	Катализатор и способ полимеризации
EP1172381A1 (fr)	2002-01-16	Polymères d'éthylène et procédé pour leur production
US4130505A (en)	1978-12-19	Two stage activation of fluorided chromium-containing catalyst
US3959178A (en)	1976-05-25	Mixed hydrocarbyloxide treated catalyst activated at different temperatures
JP2015013999A (ja)	2015-01-22	硫酸塩による処理を通して活性クロム／アルミナ触媒群を調製する方法および当該クロム／アルミナ触媒群を用いて製造する重合体類
KR101667830B1 (ko)	2016-10-19	중합촉매 제조방법
US4025707A (en)	1977-05-24	Mixed hydrocarbyloxide treated catalyst activated at different temperatures
US3351623A (en)	1967-11-07	Ethylene polymerization
FI59417B (fi)	1981-04-30	Foerfarande foer framstaellning av olefinpolymerer
US4184979A (en)	1980-01-22	Catalyst and process of preparing the catalyst
EP2970527B1 (fr)	2019-07-03	Procédés de préparation d'un catalyseur de polymérisation
EP2271681B1 (fr)	2013-10-23	Procédés de préparation d'un catalyseur de polymérisation
US4252927A (en)	1981-02-24	Process for polymerizing 1-olefins with a chromium-containing catalyst and a modifier comprising a trihydrocarbyl aluminum and an α-ω
US4252928A (en)	1981-02-24	Process for polymerizing 1-olefins with a chromium catalyst and a catalyst modifier comprising an aliphatic diene and a trihydrocarbyl boron
EP0186174A2 (fr)	1986-07-02	Procédé de polymérisation et copolymères de l'éthylène et produits ainsi préparés
US4224428A (en)	1980-09-23	Polymerization process
WO1999031146A1 (fr)	1999-06-24	Procedes servant a produire des copolymeres d'ethylene et au moins une autre olefine
US3174957A (en)	1965-03-23	Copolymerization of ethylene with higher olefins
CA2967398C (fr)	2023-01-24	Compositions catalytiques a base de chrome pour la polymerisation d'olefines
EP3223943B1 (fr)	2023-09-27	Composition comprenant des particules