FI61299C - Regenereringsfoerfarande foer kinonfoerbindningar - Google Patents

Regenereringsfoerfarande foer kinonfoerbindningar Download PDF

Info

Publication number: FI61299C
Authority: FI; Finland
Prior art keywords: working solution; treatment; reduced; quinone; oxidized
Prior art date: 1971-12-20

Application number

FI3538/72A

Other languages

English (en)

Finnish (fi)

Other versions

FI61299B (fi

Inventor

William Reid Logan

Alan Rippon

Original Assignee

Laporte Industries Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1971-12-20

Filing date

1972-12-14

Publication date

1982-07-12

1972-12-14 Application filed by Laporte Industries Ltd filed Critical Laporte Industries Ltd

1982-03-31 Application granted granted Critical

1982-03-31 Publication of FI61299B publication Critical patent/FI61299B/fi

1982-07-12 Publication of FI61299C publication Critical patent/FI61299C/fi

Links

239000012224 working solution Substances 0.000 description 44
238000011282 treatment Methods 0.000 description 34
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 23
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 18
238000000034 method Methods 0.000 description 17
-1 alkali metal aluminosilicate Chemical class 0.000 description 14
239000003795 chemical substances by application Substances 0.000 description 13
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
230000001172 regenerating effect Effects 0.000 description 12
230000008929 regeneration Effects 0.000 description 12
238000011069 regeneration method Methods 0.000 description 12
239000002904 solvent Substances 0.000 description 12
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
239000000243 solution Substances 0.000 description 9
150000004053 quinones Chemical class 0.000 description 8
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 6
125000004122 cyclic group Chemical group 0.000 description 6
239000000126 substance Substances 0.000 description 6
SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 5
KFVBMBOOLFSJHV-UHFFFAOYSA-K aluminum;sodium;hexane-1,2,3,4,5,6-hexol;carbonate;hydroxide Chemical compound [OH-].[Na+].[Al+3].[O-]C([O-])=O.OCC(O)C(O)C(O)C(O)CO KFVBMBOOLFSJHV-UHFFFAOYSA-K 0.000 description 5
238000000354 decomposition reaction Methods 0.000 description 5
239000000203 mixture Substances 0.000 description 5
239000012492 regenerant Substances 0.000 description 5
239000007787 solid Substances 0.000 description 5
238000010923 batch production Methods 0.000 description 4
239000000047 product Substances 0.000 description 4
238000009835 boiling Methods 0.000 description 3
239000007857 degradation product Substances 0.000 description 3
150000002118 epoxides Chemical class 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
238000005984 hydrogenation reaction Methods 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000004593 Epoxy Substances 0.000 description 2
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000008044 alkali metal hydroxides Chemical class 0.000 description 2
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 2
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
IMXBRVLCKXGWSS-UHFFFAOYSA-N methyl 2-cyclohexylacetate Chemical compound COC(=O)CC1CCCCC1 IMXBRVLCKXGWSS-UHFFFAOYSA-N 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
235000012217 sodium aluminium silicate Nutrition 0.000 description 2
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
RKMPHYRYSONWOL-UHFFFAOYSA-N 1-ethyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(CC)CCC2 RKMPHYRYSONWOL-UHFFFAOYSA-N 0.000 description 1
AAHIKPPSMXWKAV-UHFFFAOYSA-N 2,3-diethylnaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(CC)=C(CC)C(=O)C2=C1 AAHIKPPSMXWKAV-UHFFFAOYSA-N 0.000 description 1
PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
BXRGMKVTCTWHRD-UHFFFAOYSA-N 2-butyl-3-methylnaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(CCCC)=C(C)C(=O)C2=C1 BXRGMKVTCTWHRD-UHFFFAOYSA-N 0.000 description 1
JORLUGVBYJSSAW-UHFFFAOYSA-N 2-ethyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CC(CC)CC2 JORLUGVBYJSSAW-UHFFFAOYSA-N 0.000 description 1
UMWZLYTVXQBTTE-UHFFFAOYSA-N 2-pentylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCCC)=CC=C3C(=O)C2=C1 UMWZLYTVXQBTTE-UHFFFAOYSA-N 0.000 description 1
YTPSFXZMJKMUJE-UHFFFAOYSA-N 2-tert-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)C)=CC=C3C(=O)C2=C1 YTPSFXZMJKMUJE-UHFFFAOYSA-N 0.000 description 1
HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
239000007789 gas Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
230000001939 inductive effect Effects 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000000429 sodium aluminium silicate Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
238000003756 stirring Methods 0.000 description 1
210000000689 upper leg Anatomy 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Epoxy Compounds (AREA)
Treatment Of Water By Oxidation Or Reduction (AREA)
Detergent Compositions (AREA)

FI3538/72A 1971-12-20 1972-12-14 Regenereringsfoerfarande foer kinonfoerbindningar FI61299C (fi)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
GB5902971		1971-12-20
GB5903071		1971-12-20
GB5903071		1971-12-20
GB5902971A GB1405251A (en)	1971-12-20	1971-12-20	Peroxygen compounds

Publications (2)

Publication Number	Publication Date
FI61299B FI61299B (fi)	1982-03-31
FI61299C true FI61299C (fi)	1982-07-12

Family

ID=26267762

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI3538/72A FI61299C (fi)	1971-12-20	1972-12-14	Regenereringsfoerfarande foer kinonfoerbindningar

Country Status (13)

Country	Link
JP (1)	JPS5730801B2 (de)
AT (1)	AT360490B (de)
BE (1)	BE792900A (de)
CA (1)	CA994989A (de)
DE (1)	DE2261894C2 (de)
ES (1)	ES409763A1 (de)
FI (1)	FI61299C (de)
FR (1)	FR2164667B1 (de)
GB (1)	GB1405251A (de)
IN (1)	IN137860B (de)
IT (1)	IT974499B (de)
NL (1)	NL175610C (de)
RO (1)	RO62354A (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4566998A (en) *	1981-09-28	1986-01-28	Foret S.A.	Production of hydrogen peroxide
JP4735500B2 (ja) *	2006-09-29	2011-07-27	三菱瓦斯化学株式会社	アントラキノン法による過酸化水素の製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1138743B (de) *	1958-06-24	1962-10-31	Laporte Chemical	Verfahren zur Regenerierung von verbrauchten organischen Arbeitsloesungen bei der Wasserstoffperoxydherstellung
NL123981C (de) *	1961-02-27	1900-01-01
DE1273499B (de) *	1964-07-28	1968-07-25	Degussa	Verfahren zum Regenerieren von Arbeitsloesungen fuer die Herstellung von Wasserstoffperoxid nach dem Anthrachinonverfahren
US3432267A (en) *	1967-05-26	1969-03-11	Fmc Corp	Regeneration of anthraquinone working solution used in the production of hydrogen peroxide

0
- BE BE792900D patent/BE792900A/xx not_active IP Right Cessation
1971
- 1971-12-20 GB GB5902971A patent/GB1405251A/en not_active Expired
1972
- 1972-12-07 CA CA158,785A patent/CA994989A/en not_active Expired
- 1972-12-08 IN IN2099/72A patent/IN137860B/en unknown
- 1972-12-13 JP JP12634372A patent/JPS5730801B2/ja not_active Expired
- 1972-12-14 IT IT7254728A patent/IT974499B/it active
- 1972-12-14 FI FI3538/72A patent/FI61299C/fi active
- 1972-12-18 ES ES409763A patent/ES409763A1/es not_active Expired
- 1972-12-18 FR FR7245144A patent/FR2164667B1/fr not_active Expired
- 1972-12-18 DE DE2261894A patent/DE2261894C2/de not_active Expired
- 1972-12-18 NL NLAANVRAGE7217248,A patent/NL175610C/xx not_active IP Right Cessation
- 1972-12-19 AT AT1081372A patent/AT360490B/de not_active IP Right Cessation
- 1972-12-20 RO RO73237A patent/RO62354A/ro unknown

Also Published As

Publication number	Publication date
DE2261894C2 (de)	1983-03-17
IT974499B (it)	1974-06-20
FR2164667B1 (de)	1976-06-04
RO62354A (de)	1977-08-15
JPS4869793A (de)	1973-09-21
IN137860B (de)	1975-10-04
ES409763A1 (es)	1976-04-16
ATA1081372A (de)	1980-06-15
GB1405251A (en)	1975-09-10
NL175610B (nl)	1984-07-02
BE792900A (fr)	1973-06-18
NL7217248A (de)	1973-06-22
DE2261894A1 (de)	1973-06-28
JPS5730801B2 (de)	1982-07-01
NL175610C (nl)	1984-12-03
FI61299B (fi)	1982-03-31
AT360490B (de)	1981-01-12
CA994989A (en)	1976-08-17
FR2164667A1 (de)	1973-08-03

Publication	Publication Date	Title
Duke et al.	1961	The homogeneous base-catalyzed decomposition of hydrogen peroxide1
DE69016678T2 (de)	1995-07-13	Peroxycarbonsäuregenerator.
JPH11157810A (ja)	1999-06-15	過酸化水素の直接製造方法
US4729855A (en)	1988-03-08	Method of decontaminating radioactive metal surfaces
NO305278B1 (no)	1999-05-03	FremgangsmÕte for konsentrasjon, fjerning og separasjon av °nskede ioner fra en multippel-ion kildeoppl°sning, samt aminoalkylfosfonsyreinneholdende ligand-fastbµrerforbindelse for anvendelse ved fremgangsmÕten
KR850000732A (ko)	1985-03-09	원자로에서의 금속 표면 오염제거 방법 및 장치
DE492064T1 (de)	1992-11-05	Verfahren zur herstellung von wasserstoffperoxid.
CN100581647C (zh)	2010-01-20	有机组分负载型炭鳌合吸附剂及其制备方法和应用
Pan et al.	1984	Studies on ozone bleaching. I. The effect of pH, temperature, buffer systems and heavy metal-ions on stability of ozone in aqueous solution
US3912766A (en)	1975-10-14	Regeneration of degraded quinones for the production of hydrogen peroxide
CZ20004281A3 (cs)	2002-02-13	Způsob výroby peroxidu vodíku antrachinonovým postupem
FI61299B (fi)	1982-03-31	Regenereringsfoerfarande foer kinonfoerbindningar
US3965251A (en)	1976-06-22	Method of regenerating a degraded working solution for the production of hydrogen peroxide
DE69608528T2 (de)	2001-01-18	Verfahren zur Aktivierung oder Regenerierung eines Katalysators der zur Herstellung von Wasserstoffperoxid eingesetzt wird
US3814701A (en)	1974-06-04	Regeneration of spent alumina
EP0647721A2 (de)	1995-04-12	Mittel zur Behandlung von Metallionen in wässriger Lösung, Verfahren zu seiner Herstellung und Verfahren zur Behandlung von Metallionen in wässriger Lösung
Gemeay et al.	1996	Activity of silica-alumina surface modified with some transition metal ions
MX169166B (es)	1993-06-23	Regeneracion de un baño de procesamiento quimico de cobre
EP0207269A2 (de)	1987-01-07	Phenylsulfonatgruppen-haltige Organopolysiloxane, Verfahren zu ihrer Herstellung und Verwendung
US3305314A (en)	1967-02-21	Purification process
JPH05115B2 (de)	1993-01-05
JPH09241009A (ja)	1997-09-16	過酸化水素の製造方法
KR20020032225A (ko)	2002-05-03	과산화수소의 직접적 제조방법
Anderson et al.	1987	Study of copper (2+)-doped zeolites Na-rho, K-rho, and Ca-rho by electron spin resonance and electron spin echo modulation spectroscopies
Bilski et al.	1988	Oxygen consumption in two aqueous systems: excited nitrite ions-oxygen and nitrite ions-singlet oxygen