FI64172C - Foerfarande och katalysator foer polymerisering av en etylenhaltig sats med en reducerad kromatesterkatalysator pao en kiseldioxidbaerare - Google Patents

Foerfarande och katalysator foer polymerisering av en etylenhaltig sats med en reducerad kromatesterkatalysator pao en kiseldioxidbaerare Download PDF

Info

Publication number: FI64172C
Authority: FI; Finland
Prior art keywords: catalyst; chromate; chromate ester; ester; polymerization
Prior art date: 1976-03-30

Application number

FI770977A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI770977A7 (fr

FI64172B (fi

Inventor

Anthony David Hamer

Frederick John Karol

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-03-30

Filing date

1977-03-29

Publication date

1983-10-10

1977-03-29 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1977-10-01 Publication of FI770977A7 publication Critical patent/FI770977A7/fi

1983-06-30 Application granted granted Critical

1983-06-30 Publication of FI64172B publication Critical patent/FI64172B/fi

1983-10-10 Publication of FI64172C publication Critical patent/FI64172C/fi

Links

239000003054 catalyst Substances 0.000 title claims description 136
238000006116 polymerization reaction Methods 0.000 title description 40
239000011248 coating agent Substances 0.000 title 1
238000000576 coating method Methods 0.000 title 1
-1 chromate ester Chemical class 0.000 claims description 122
239000003638 chemical reducing agent Substances 0.000 claims description 38
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 26
239000005977 Ethylene Substances 0.000 claims description 25
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 22
150000002989 phenols Chemical class 0.000 claims description 22
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
229910052739 hydrogen Inorganic materials 0.000 claims description 17
239000001257 hydrogen Substances 0.000 claims description 17
150000002430 hydrocarbons Chemical group 0.000 claims description 15
238000000034 method Methods 0.000 claims description 15
239000000178 monomer Substances 0.000 claims description 10
239000000377 silicon dioxide Substances 0.000 claims description 10
AHXGRMIPHCAXFP-UHFFFAOYSA-L chromyl dichloride Chemical group Cl[Cr](Cl)(=O)=O AHXGRMIPHCAXFP-UHFFFAOYSA-L 0.000 claims description 7
229910052736 halogen Inorganic materials 0.000 claims description 7
150000002367 halogens Chemical class 0.000 claims description 7
229910052718 tin Inorganic materials 0.000 claims description 7
238000011282 treatment Methods 0.000 claims description 7
IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims description 6
150000002431 hydrogen Chemical class 0.000 claims description 5
GZFGOTFRPZRKDS-UHFFFAOYSA-N 4-bromophenol Chemical compound OC1=CC=C(Br)C=C1 GZFGOTFRPZRKDS-UHFFFAOYSA-N 0.000 claims description 3
QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 claims description 3
230000000379 polymerizing effect Effects 0.000 claims description 2
KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims 1
239000002685 polymerization catalyst Substances 0.000 claims 1
229920000642 polymer Polymers 0.000 description 32
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 25
238000006243 chemical reaction Methods 0.000 description 21
150000001875 compounds Chemical class 0.000 description 21
238000002360 preparation method Methods 0.000 description 20
239000002904 solvent Substances 0.000 description 20
239000002002 slurry Substances 0.000 description 18
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 17
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
239000012632 extractable Substances 0.000 description 10
239000000155 melt Substances 0.000 description 10
230000035484 reaction time Effects 0.000 description 10
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 9
CQBWEBXPMRPCSI-UHFFFAOYSA-M O[Cr](O[SiH3])(=O)=O Chemical class O[Cr](O[SiH3])(=O)=O CQBWEBXPMRPCSI-UHFFFAOYSA-M 0.000 description 9
238000002844 melting Methods 0.000 description 8
230000008018 melting Effects 0.000 description 8
229920000573 polyethylene Polymers 0.000 description 8
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 7
125000004432 carbon atom Chemical group C* 0.000 description 7
150000002148 esters Chemical class 0.000 description 7
229930195733 hydrocarbon Natural products 0.000 description 7
239000000463 material Substances 0.000 description 7
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
239000011651 chromium Substances 0.000 description 6
230000008878 coupling Effects 0.000 description 6
238000010168 coupling process Methods 0.000 description 6
238000005859 coupling reaction Methods 0.000 description 6
229910052698 phosphorus Inorganic materials 0.000 description 6
239000011574 phosphorus Substances 0.000 description 6
239000011135 tin Substances 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
229910052804 chromium Inorganic materials 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
239000011261 inert gas Substances 0.000 description 5
239000003960 organic solvent Substances 0.000 description 5
239000002245 particle Substances 0.000 description 5
238000006722 reduction reaction Methods 0.000 description 5
239000011347 resin Substances 0.000 description 5
229920005989 resin Polymers 0.000 description 5
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
238000001035 drying Methods 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000000203 mixture Substances 0.000 description 4
239000011148 porous material Substances 0.000 description 4
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
229910052719 titanium Inorganic materials 0.000 description 4
239000010936 titanium Substances 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
239000012986 chain transfer agent Substances 0.000 description 3
150000001993 dienes Chemical class 0.000 description 3
GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
150000005673 monoalkenes Chemical class 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
231100000614 poison Toxicity 0.000 description 3
239000002574 poison Substances 0.000 description 3
150000003254 radicals Chemical class 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
125000003944 tolyl group Chemical group 0.000 description 3
RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
125000005916 2-methylpentyl group Chemical group 0.000 description 2
JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
150000004703 alkoxides Chemical class 0.000 description 2
125000002877 alkyl aryl group Chemical group 0.000 description 2
125000003710 aryl alkyl group Chemical group 0.000 description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000000969 carrier Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
238000005243 fluidization Methods 0.000 description 2
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
238000005259 measurement Methods 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
125000001624 naphthyl group Chemical group 0.000 description 2
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000000047 product Substances 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
238000012360 testing method Methods 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
125000005023 xylyl group Chemical group 0.000 description 2
PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
AMWKIEQSDUQJOV-UHFFFAOYSA-N CCCCCCCCCCCCC[SiH2]O[Cr](=O)(=O)O[SiH2]CCCCCCCCCCCCC Chemical compound CCCCCCCCCCCCC[SiH2]O[Cr](=O)(=O)O[SiH2]CCCCCCCCCCCCC AMWKIEQSDUQJOV-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
241001446459 Heia Species 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
101100379123 Mus musculus Npr1 gene Proteins 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
240000007817 Olea europaea Species 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
TVDSCXSDCGJORM-UHFFFAOYSA-N [Cr](=O)(=O)(O[SiH2]C1=C(C(=C(C2=CC=CC=C12)C)C)C)O[SiH2]C1=C(C(=C(C2=CC=CC=C12)C)C)C.[Cr](=O)(=O)(O[SiH2]C1=C(C(=C(C=C1)CC)CC)CC)O[SiH2]C1=C(C(=C(C=C1)CC)CC)CC.[Cr](=O)(=O)(O[Si](C1=CC=CC2=CC=CC=C12)(C1=CC=CC2=CC=CC=C12)C1=CC=CC2=CC=CC=C12)O[Si](C1=CC=CC2=CC=CC=C12)(C1=CC=CC2=CC=CC=C12)C1=CC=CC2=CC=CC=C12 Chemical compound [Cr](=O)(=O)(O[SiH2]C1=C(C(=C(C2=CC=CC=C12)C)C)C)O[SiH2]C1=C(C(=C(C2=CC=CC=C12)C)C)C.[Cr](=O)(=O)(O[SiH2]C1=C(C(=C(C=C1)CC)CC)CC)O[SiH2]C1=C(C(=C(C=C1)CC)CC)CC.[Cr](=O)(=O)(O[Si](C1=CC=CC2=CC=CC=C12)(C1=CC=CC2=CC=CC=C12)C1=CC=CC2=CC=CC=C12)O[Si](C1=CC=CC2=CC=CC=C12)(C1=CC=CC2=CC=CC=C12)C1=CC=CC2=CC=CC=C12 TVDSCXSDCGJORM-UHFFFAOYSA-N 0.000 description 1
BCFRWAJVFIQTTM-UHFFFAOYSA-N [Cr](=O)(=O)(O[Si](C1=C(C=CC=C1)C)(C1=C(C=CC=C1)C)C1=C(C=CC=C1)C)O[Si](C1=C(C=CC=C1)C)(C1=C(C=CC=C1)C)C1=C(C=CC=C1)C.[Cr](=O)(=O)(O[Si](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)O[Si](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound [Cr](=O)(=O)(O[Si](C1=C(C=CC=C1)C)(C1=C(C=CC=C1)C)C1=C(C=CC=C1)C)O[Si](C1=C(C=CC=C1)C)(C1=C(C=CC=C1)C)C1=C(C=CC=C1)C.[Cr](=O)(=O)(O[Si](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)O[Si](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 BCFRWAJVFIQTTM-UHFFFAOYSA-N 0.000 description 1
SZEBMVXBAMRJCK-UHFFFAOYSA-M [Cr](=O)(=O)(O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1)O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1.[Cr](=O)(=O)(O[SiH3])O Chemical compound [Cr](=O)(=O)(O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1)O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1.[Cr](=O)(=O)(O[SiH3])O SZEBMVXBAMRJCK-UHFFFAOYSA-M 0.000 description 1
DLWQRNGCVOAWFU-UHFFFAOYSA-N [Cr](=O)(=O)(O[Si](CCC(C)C)(CCC(C)C)CCC(C)C)O[Si](CCC(C)C)(CCC(C)C)CCC(C)C.[Cr](=O)(=O)(O[Si](CCCC)(CCCC)CCCC)O[Si](CCCC)(CCCC)CCCC Chemical compound [Cr](=O)(=O)(O[Si](CCC(C)C)(CCC(C)C)CCC(C)C)O[Si](CCC(C)C)(CCC(C)C)CCC(C)C.[Cr](=O)(=O)(O[Si](CCCC)(CCCC)CCCC)O[Si](CCCC)(CCCC)CCCC DLWQRNGCVOAWFU-UHFFFAOYSA-N 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000004913 activation Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000002168 alkylating agent Substances 0.000 description 1
229940100198 alkylating agent Drugs 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
125000002619 bicyclic group Chemical group 0.000 description 1
238000007664 blowing Methods 0.000 description 1
238000009835 boiling Methods 0.000 description 1
210000000481 breast Anatomy 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
229910000423 chromium oxide Inorganic materials 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
230000007423 decrease Effects 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
UWAMTZZJXXCIOH-UHFFFAOYSA-M diethyl(phenoxy)alumane Chemical compound CC[Al+]CC.[O-]C1=CC=CC=C1 UWAMTZZJXXCIOH-UHFFFAOYSA-M 0.000 description 1
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
239000003759 ester based solvent Substances 0.000 description 1
125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
239000008187 granular material Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
238000005286 illumination Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
229910021514 lead(II) hydroxide Inorganic materials 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
108010086652 phytohemagglutinin-P Proteins 0.000 description 1
230000003389 potentiating effect Effects 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
238000005245 sintering Methods 0.000 description 1
238000007613 slurry method Methods 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000010998 test method Methods 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
238000003878 thermal aging Methods 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
231100000765 toxin Toxicity 0.000 description 1
239000003053 toxin Substances 0.000 description 1
108700012359 toxins Proteins 0.000 description 1
238000012546 transfer Methods 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000008096 xylene Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Polymerization Catalysts (AREA)

FI770977A 1976-03-30 1977-03-29 Foerfarande och katalysator foer polymerisering av en etylenhaltig sats med en reducerad kromatesterkatalysator pao en kiseldioxidbaerare FI64172C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US67197576		1976-03-30
US05/671,975 US4065612A (en)	1976-03-30	1976-03-30	Phenol modified polymerization catalyst and polymerization process

Publications (3)

Publication Number	Publication Date
FI770977A7 FI770977A7 (fr)	1977-10-01
FI64172B FI64172B (fi)	1983-06-30
FI64172C true FI64172C (fi)	1983-10-10

Family

ID=24696641

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI770977A FI64172C (fi)	1976-03-30	1977-03-29	Foerfarande och katalysator foer polymerisering av en etylenhaltig sats med en reducerad kromatesterkatalysator pao en kiseldioxidbaerare

Country Status (21)

Country	Link
US (1)	US4065612A (fr)
JP (1)	JPS52117986A (fr)
AU (1)	AU517299B2 (fr)
BE (1)	BE852977A (fr)
BR (1)	BR7701941A (fr)
CA (1)	CA1083560A (fr)
DE (1)	DE2713877C2 (fr)
DK (1)	DK150149C (fr)
ES (2)	ES457310A1 (fr)
FI (1)	FI64172C (fr)
FR (1)	FR2346373A1 (fr)
GB (1)	GB1549096A (fr)
HK (1)	HK67580A (fr)
IN (1)	IN144829B (fr)
IT (1)	IT1075367B (fr)
MX (1)	MX4828E (fr)
MY (1)	MY8100242A (fr)
NL (1)	NL178880C (fr)
NO (1)	NO148815C (fr)
PH (1)	PH13407A (fr)
SE (1)	SE435519B (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4100105A (en) *	1977-01-21	1978-07-11	Union Carbide Corporation	Titanium-modified silyl chromate catalysts for ethylene polymerization
US4170589A (en) *	1978-02-22	1979-10-09	Union Carbide Corporation	Catalytic polymerization of ethylene with supported chromium [II] catalyst in the presence of a phenolic antioxidant
JPS58128715U (ja) *	1982-02-25	1983-08-31	マツダ株式会社	プレス切断用型具
US4735931A (en) *	1986-06-16	1988-04-05	Phillips Petroleum Company	In situ comonomer generation in olefin polymerization
US4820785A (en) *	1986-06-16	1989-04-11	Phillips Petroleum Company	In situ comonomer generation in olefin polymerization
US5096868A (en) *	1987-10-21	1992-03-17	Mobil Oil Corporation	Catalyst composition for polymerizing alpha-olefins and alpha-olefins polymerization therewith
AU2377900A (en) *	1998-12-29	2000-07-31	Chevron Phillips Chemical Company Lp	Improved chromate ester catalyst and method of using same to produce high performance polyethylene products
JP4666426B2 (ja) *	2000-09-29	2011-04-06	東邦チタニウム株式会社	オレフィン類重合用固体触媒成分および触媒
US7414099B2 (en) *	2004-12-15	2008-08-19	Univation Technologies, Llc	Hindered polyalicyclic alkyl catalysts and their use in a gas-phase polymerization reactor

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE557561A (fr) *	1956-08-02
US3150122A (en) *	1957-11-07	1964-09-22	Monsanto Co	Production of high-density ziegler polymers
NL135065C (fr) *	1965-05-14
US3493554A (en) *	1966-06-27	1970-02-03	Nat Distillers Chem Corp	Olefin polymerization process employing a chromate catalyst
US3535297A (en) *	1968-02-14	1970-10-20	Union Carbide Corp	Polymerization of ethylene using supported activated chromyl chloride catalysts
US3642749A (en) *	1969-03-27	1972-02-15	Union Carbide Corp	Olefin polymerization using di-tertiary polyalicyclic chromate ester catalyst systems

1976
- 1976-03-30 US US05/671,975 patent/US4065612A/en not_active Expired - Lifetime
1977
- 1977-03-02 CA CA273,021A patent/CA1083560A/fr not_active Expired
- 1977-03-28 AU AU23690/77A patent/AU517299B2/en not_active Expired
- 1977-03-29 NO NO771115A patent/NO148815C/no unknown
- 1977-03-29 FI FI770977A patent/FI64172C/fi not_active IP Right Cessation
- 1977-03-29 NL NLAANVRAGE7703396,A patent/NL178880C/xx not_active IP Right Cessation
- 1977-03-29 IN IN473/CAL/77A patent/IN144829B/en unknown
- 1977-03-29 JP JP3405477A patent/JPS52117986A/ja active Granted
- 1977-03-29 DK DK138977A patent/DK150149C/da not_active IP Right Cessation
- 1977-03-29 BE BE176195A patent/BE852977A/fr not_active IP Right Cessation
- 1977-03-29 GB GB13184/77A patent/GB1549096A/en not_active Expired
- 1977-03-29 ES ES457310A patent/ES457310A1/es not_active Expired
- 1977-03-29 ES ES457309A patent/ES457309A1/es not_active Expired
- 1977-03-29 BR BR7701941A patent/BR7701941A/pt unknown
- 1977-03-29 DE DE2713877A patent/DE2713877C2/de not_active Expired
- 1977-03-29 MX MX77100751U patent/MX4828E/es unknown
- 1977-03-29 IT IT21846/77A patent/IT1075367B/it active
- 1977-03-29 FR FR7709407A patent/FR2346373A1/fr active Granted
- 1977-03-29 PH PH19598A patent/PH13407A/en unknown
- 1977-03-29 SE SE7703627A patent/SE435519B/xx not_active IP Right Cessation
1980
- 1980-11-27 HK HK675/80A patent/HK67580A/xx unknown
1981
- 1981-12-30 MY MY242/81A patent/MY8100242A/xx unknown

Also Published As

Publication number	Publication date
NO771115L (no)	1977-10-03
ES457310A1 (es)	1978-07-01
AU2369077A (en)	1978-10-05
US4065612A (en)	1977-12-27
MX4828E (es)	1982-10-21
MY8100242A (en)	1981-12-31
FI770977A7 (fr)	1977-10-01
DK138977A (da)	1977-10-01
GB1549096A (en)	1979-08-01
CA1083560A (fr)	1980-08-12
BR7701941A (pt)	1977-11-08
HK67580A (en)	1980-12-05
DK150149B (da)	1986-12-15
ES457309A1 (es)	1978-07-01
IT1075367B (it)	1985-04-22
NL178880C (nl)	1986-06-02
NL178880B (nl)	1986-01-02
IN144829B (fr)	1978-07-15
NO148815B (no)	1983-09-12
FR2346373B1 (fr)	1983-12-16
JPS5618126B2 (fr)	1981-04-27
FI64172B (fi)	1983-06-30
JPS52117986A (en)	1977-10-03
PH13407A (en)	1980-03-28
NL7703396A (nl)	1977-10-04
DE2713877C2 (de)	1987-03-19
DE2713877A1 (de)	1977-10-06
BE852977A (fr)	1977-09-29
FR2346373A1 (fr)	1977-10-28
SE7703627L (sv)	1977-10-01
AU517299B2 (en)	1981-07-23
DK150149C (da)	1987-06-29
SE435519B (sv)	1984-10-01
NO148815C (no)	1983-12-21

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: UNION CARBIDE CORP

Publication	Publication Date	Title
KR101412118B1 (ko)	2014-07-02	혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매
EP0804490B1 (fr)	1998-06-17	Catalyseurs a base de borabenzene pour la polymerisation d'olefines
KR100389180B1 (ko)	2004-03-30	비상용성 중합 촉매들간의 전이방법
US5686542A (en)	1997-11-11	Process for the preparation of branched low-pressure polyethylene, new low-pressure polyethylenes, and preformed bifunctional catalysts
FI64172C (fi)	1983-10-10	Foerfarande och katalysator foer polymerisering av en etylenhaltig sats med en reducerad kromatesterkatalysator pao en kiseldioxidbaerare
US4833111A (en)	1989-05-23	Catalyst composition for polymerizing alpha-olefin polymers of narrow molecular weight distribution
EP1123321B1 (fr)	2006-12-20	Compositions catalytiques bidentees et tridentees sur support et polymerisation d'olefines utilisant ces compositions
US5661095A (en)	1997-08-26	Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane
JP3670010B2 (ja)	2005-07-13	触媒組成物の製造方法
KR100296196B1 (ko)	2001-10-24	선형저밀도폴리에틸렌(lldpe)수지생성물의제조에사용하기위한촉매조성물
FI85868B (fi)	1992-02-28	Foerfarande foer framstaellning av polyolefin.
CA3128864A1 (fr)	2020-08-27	Polyethylene ayant un niveau eleve de reticulation et tuyau en polyethylene reticule comprenant ce dernier
FI67711B (fi)	1985-01-31	Katalytisk polymerisering av etylen med en krom(ii)-katalysator pao en baerare i naervaro av ett fenolskt antioxidationsmedel
CA2280740A1 (fr)	1998-08-13	Catalyseur de ziegler-natta destine a la polymerisation ou a la copolymerisation d'ethylene
AU5363794A (en)	1994-05-09	High activity polyethylene catalysts
US6476165B1 (en)	2002-11-05	Olefin polymerization process using fatty amine additives and boron-modified supported catalyst
KR100437987B1 (ko)	2004-08-16	높은응력균열저항을갖는에틸렌중합체,및그의제조를위한촉매계
US20020013218A1 (en)	2002-01-31	Process for producing improved premixed supported boraaryl catalysts
JPS55102608A (en)	1980-08-06	Preparation of olefin polymer
EP0113936A1 (fr)	1984-07-25	Catalyseur sur support pour la polymérisation des oléfines
JPS5915124B2 (ja)	1984-04-07	シリカ担体及びその製造法
AU715831B2 (en)	2000-02-10	High activity catalysts for the preparation of polyethylene with an intermediate molecular weight distribution
CN108690150B (zh)	2020-11-10	一种用于烯烃聚合的催化剂体系及烯烃聚合方法
US6444765B1 (en)	2002-09-03	Olefin polymerization process for producing broad MWD polymers
JP3272371B2 (ja)	2002-04-08	エチレン・高級α−オレフィン共重合体およびその製造方法