FI86896B - Foerfarande foer blekning av cellulosamassa. - Google Patents
Foerfarande foer blekning av cellulosamassa. Download PDFInfo
- Publication number
- FI86896B FI86896B FI892151A FI892151A FI86896B FI 86896 B FI86896 B FI 86896B FI 892151 A FI892151 A FI 892151A FI 892151 A FI892151 A FI 892151A FI 86896 B FI86896 B FI 86896B
- Authority
- FI
- Finland
- Prior art keywords
- bleaching
- pulp
- oxygen
- chlorine
- enzyme
- Prior art date
Links
- 238000004061 bleaching Methods 0.000 claims abstract description 73
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000001301 oxygen Substances 0.000 claims abstract description 46
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 46
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 44
- 108090000790 Enzymes Proteins 0.000 claims abstract description 43
- 102000004190 Enzymes Human genes 0.000 claims abstract description 43
- 239000000126 substance Substances 0.000 claims abstract description 34
- 230000003647 oxidation Effects 0.000 claims abstract description 26
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000004155 Chlorine dioxide Substances 0.000 claims abstract description 22
- 235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 22
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000460 chlorine Substances 0.000 claims abstract description 17
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 16
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940088598 enzyme Drugs 0.000 claims description 40
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 12
- 229920002678 cellulose Polymers 0.000 claims description 11
- 239000001913 cellulose Substances 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 8
- 238000009896 oxidative bleaching Methods 0.000 claims description 5
- 229940059442 hemicellulase Drugs 0.000 claims description 4
- 108010002430 hemicellulase Proteins 0.000 claims description 4
- 108010059892 Cellulase Proteins 0.000 claims description 3
- 108090000371 Esterases Proteins 0.000 claims description 3
- 108010059820 Polygalacturonase Proteins 0.000 claims description 3
- 229940106157 cellulase Drugs 0.000 claims description 3
- 108010093305 exopolygalacturonase Proteins 0.000 claims description 3
- 239000011122 softwood Substances 0.000 claims description 2
- 230000003301 hydrolyzing effect Effects 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 11
- 231100000167 toxic agent Toxicity 0.000 abstract description 2
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 150000004045 organic chlorine compounds Chemical class 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 229920005610 lignin Polymers 0.000 description 6
- 239000002351 wastewater Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 2
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 235000014347 soups Nutrition 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- RSPISYXLHRIGJD-UHFFFAOYSA-N OOOO Chemical compound OOOO RSPISYXLHRIGJD-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 244000155172 Podocarpus elatus Species 0.000 description 1
- 235000003209 Podocarpus elatus Nutrition 0.000 description 1
- 241000223259 Trichoderma Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 101150113965 carH gene Proteins 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
- D21C9/144—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites with ClO2/Cl2 and other bleaching agents in a multistage process
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Paper (AREA)
- Noodles (AREA)
- Cereal-Derived Products (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Table Devices Or Equipment (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Hard Magnetic Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI892151A FI86896B (fi) | 1989-05-04 | 1989-05-04 | Foerfarande foer blekning av cellulosamassa. |
| NO893716A NO172355C (no) | 1989-05-04 | 1989-09-18 | Fremgangsmaate for bleking av masse |
| EP89117233A EP0395792B1 (de) | 1989-05-04 | 1989-09-18 | Verfahren zum Bleichen von Zellstoff |
| JP1241666A JPH02293486A (ja) | 1989-05-04 | 1989-09-18 | パルプ漂白法 |
| CA000611771A CA1339593C (en) | 1989-05-04 | 1989-09-18 | Procedure for the bleaching of pulp in which oxygen is used as the oxidating bleaching chemical |
| DE8989117233T DE68907593D1 (de) | 1989-05-04 | 1989-09-18 | Verfahren zum bleichen von zellstoff. |
| AT89117233T ATE91518T1 (de) | 1989-05-04 | 1989-09-18 | Verfahren zum bleichen von zellstoff. |
| ES89117233T ES2045320T3 (es) | 1989-05-04 | 1989-09-18 | Procedimiento para el blanqueo de pasta papelera. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI892151A FI86896B (fi) | 1989-05-04 | 1989-05-04 | Foerfarande foer blekning av cellulosamassa. |
| FI892151 | 1989-05-04 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI892151A0 FI892151A0 (fi) | 1989-05-04 |
| FI892151L FI892151L (fi) | 1990-11-05 |
| FI86896B true FI86896B (fi) | 1992-07-15 |
Family
ID=8528357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI892151A FI86896B (fi) | 1989-05-04 | 1989-05-04 | Foerfarande foer blekning av cellulosamassa. |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0395792B1 (de) |
| JP (1) | JPH02293486A (de) |
| AT (1) | ATE91518T1 (de) |
| CA (1) | CA1339593C (de) |
| DE (1) | DE68907593D1 (de) |
| ES (1) | ES2045320T3 (de) |
| FI (1) | FI86896B (de) |
| NO (1) | NO172355C (de) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE134231T1 (de) * | 1989-08-14 | 1996-02-15 | Genencor Int Europ | Verbesserung beim bleichen von pulpe |
| SE465320B (sv) * | 1990-01-10 | 1991-08-26 | Korsnaes Ab | Preparat som uppvisar enzymatisk delignifieringsaktivitet, saett att framstaella detsamma och tillaempningar daerav |
| US5837515A (en) * | 1990-05-16 | 1998-11-17 | Alko-Yhtiot Oy | Enzyme preparations and methods for their production |
| JP2859393B2 (ja) * | 1990-07-24 | 1999-02-17 | ノボ ノルディスク アクティーゼルスカブ | セルラーゼ及びその製造法 |
| DE4129739A1 (de) * | 1990-09-11 | 1992-03-12 | Sandoz Ag | Chlorfreies bleichen von papierpulpe |
| JPH04240287A (ja) * | 1991-01-21 | 1992-08-27 | Kobe Steel Ltd | パルプの漂白方法 |
| FI90670C (sv) * | 1991-05-02 | 1994-03-10 | Metsae Serla Oy | Behandling av alkalibehandlad massa för användning i pappersframställning |
| FI108800B (fi) * | 1991-05-07 | 2002-03-28 | Iogen Corp | Menetelmä ja laitteisto entsyymin käyttämiseksi paperimassan valmistuksessa ja valkaisussa |
| US5785811A (en) * | 1992-11-09 | 1998-07-28 | The Mead Corporation | Process for treating lignocellulosic material with soybean peroxidase in the presence of peroxide |
| US5871730A (en) * | 1994-07-29 | 1999-02-16 | Universite De Sherbrooke | Thermostable xylanase DNA, protein and methods of use |
| US7816129B2 (en) | 1994-07-29 | 2010-10-19 | Ab Enzymes Gmbh | Production and secretion of proteins of bacterial origin in filamentous fungi |
| US5935836A (en) * | 1994-07-29 | 1999-08-10 | Rohm Enzyme Finland Oy | Actinomadura xylanase sequences and methods of use |
| US6300114B1 (en) | 1994-07-29 | 2001-10-09 | Rohm Enzyme Finland Oy | Sequences of xylanase and xylanase expression vectors |
| CA2301371C (en) * | 1999-03-23 | 2009-09-01 | Oji Paper Co., Ltd. | Process for bleaching lignocellulose pulp |
| US6942754B2 (en) | 1999-03-23 | 2005-09-13 | Oji Paper Co., Ltd. | Process for producing xylooligosaccharide from lignocellulose pulp |
| US6824646B2 (en) | 1999-03-23 | 2004-11-30 | Oji Paper Co., Ltd. | Process for oxygen bleaching and enzyme treating lignocellulosic pulp with liquid treatment and recovery |
| CA2432788C (en) | 2000-12-22 | 2008-10-07 | Iogen Bio-Products Corporation | Alkaline extraction stages comprising xylanase |
| US9096519B2 (en) | 2013-01-10 | 2015-08-04 | California Institute Of Technology | Process for the synthesis of ketones from internal alkenes |
| US9586883B2 (en) | 2013-04-19 | 2017-03-07 | California Institute Of Technology | Aldehyde-selective wacker-type oxidation of unbiased alkenes |
| CN111979823A (zh) * | 2020-08-07 | 2020-11-24 | 齐鲁工业大学 | 一种硫酸盐木浆短程序ecf漂白工艺x/d-z-p(x/z-d-p) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5468402A (en) * | 1977-11-09 | 1979-06-01 | Kogyo Gijutsuin | Property modification of biochemical pulp |
| FI81395B (fi) * | 1988-03-14 | 1990-06-29 | Cultor Oy | Foerfarande foer blekning av cellulosamassa. |
| FI90888B (fi) * | 1989-02-14 | 1993-12-31 | Enso Gutzeit Oy | Menetelmä selluloosamassan valkaisemiseksi |
-
1989
- 1989-05-04 FI FI892151A patent/FI86896B/fi not_active Application Discontinuation
- 1989-09-18 DE DE8989117233T patent/DE68907593D1/de not_active Expired - Lifetime
- 1989-09-18 CA CA000611771A patent/CA1339593C/en not_active Expired - Fee Related
- 1989-09-18 NO NO893716A patent/NO172355C/no not_active IP Right Cessation
- 1989-09-18 ES ES89117233T patent/ES2045320T3/es not_active Expired - Lifetime
- 1989-09-18 EP EP89117233A patent/EP0395792B1/de not_active Revoked
- 1989-09-18 JP JP1241666A patent/JPH02293486A/ja active Pending
- 1989-09-18 AT AT89117233T patent/ATE91518T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO172355B (no) | 1993-03-29 |
| EP0395792A2 (de) | 1990-11-07 |
| ATE91518T1 (de) | 1993-07-15 |
| DE68907593D1 (de) | 1993-08-19 |
| FI892151L (fi) | 1990-11-05 |
| EP0395792A3 (de) | 1991-01-16 |
| EP0395792B1 (de) | 1993-07-14 |
| NO172355C (no) | 1993-07-07 |
| ES2045320T3 (es) | 1994-01-16 |
| JPH02293486A (ja) | 1990-12-04 |
| CA1339593C (en) | 1997-12-23 |
| NO893716D0 (no) | 1989-09-18 |
| NO893716L (no) | 1990-11-05 |
| FI892151A0 (fi) | 1989-05-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD | Application lapsed |
Owner name: ENSO GUTZEIT OY |