FI96320C - Menetelmä alkeenien oligomeroimiseksi - Google Patents

Menetelmä alkeenien oligomeroimiseksi Download PDF

Info

Publication number: FI96320C
Authority: FI; Finland
Prior art keywords: zeolite; chromium; catalyst; oligomerization; hzsm
Prior art date: 1994-12-29

Application number

FI946167A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI946167A0 (fi

FI96320B (fi

Inventor

Pirkko Raulo

Kari M Keskinen

Marja Tiitta

Original Assignee

Neste Oy

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-12-29

Filing date

1994-12-29

Publication date

1996-06-10

1994-12-29 Application filed by Neste Oy filed Critical Neste Oy

1994-12-29 Priority to FI946167A priority Critical patent/FI96320C/fi

1994-12-29 Publication of FI946167A0 publication Critical patent/FI946167A0/fi

1995-12-20 Priority to AT95941108T priority patent/ATE204319T1/de

1995-12-20 Priority to DE69522238T priority patent/DE69522238T2/de

1995-12-20 Priority to EP95941108A priority patent/EP0800568B1/fr

1995-12-20 Priority to PT95941108T priority patent/PT800568E/pt

1995-12-20 Priority to PCT/FI1995/000694 priority patent/WO1996020988A1/fr

1995-12-20 Priority to DK95941108T priority patent/DK0800568T3/da

1996-02-29 Application granted granted Critical

1996-02-29 Publication of FI96320B publication Critical patent/FI96320B/fi

1996-06-10 Publication of FI96320C publication Critical patent/FI96320C/fi

Links

238000006384 oligomerization reaction Methods 0.000 title claims abstract description 28
238000000034 method Methods 0.000 title claims abstract description 24
150000001336 alkenes Chemical class 0.000 title claims abstract description 14
239000010457 zeolite Substances 0.000 claims abstract description 83
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 80
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 79
239000003054 catalyst Substances 0.000 claims abstract description 71
229910052804 chromium Inorganic materials 0.000 claims abstract description 36
239000011651 chromium Substances 0.000 claims abstract description 36
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 35
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 16
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims abstract description 12
239000010687 lubricating oil Substances 0.000 claims abstract description 9
238000005342 ion exchange Methods 0.000 claims abstract description 7
239000002283 diesel fuel Substances 0.000 claims abstract description 6
238000002360 preparation method Methods 0.000 claims abstract 2
238000004821 distillation Methods 0.000 claims description 26
239000000243 solution Substances 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 10
238000001354 calcination Methods 0.000 claims description 6
150000001844 chromium Chemical class 0.000 claims description 6
229930195733 hydrocarbon Natural products 0.000 claims description 5
150000002430 hydrocarbons Chemical class 0.000 claims description 5
239000011148 porous material Substances 0.000 claims description 5
238000002156 mixing Methods 0.000 claims description 3
229910004298 SiO 2 Inorganic materials 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims description 2
239000008240 homogeneous mixture Substances 0.000 claims description 2
238000005470 impregnation Methods 0.000 abstract description 5
238000006243 chemical reaction Methods 0.000 description 15
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
239000000571 coke Substances 0.000 description 7
229910052782 aluminium Inorganic materials 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
150000001768 cations Chemical class 0.000 description 4
-1 propylene Chemical class 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
239000002253 acid Substances 0.000 description 2
238000011021 bench scale process Methods 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000001294 propane Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
239000007790 solid phase Substances 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
229910021555 Chromium Chloride Inorganic materials 0.000 description 1
241001674048 Phthiraptera Species 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
MYSOGRBSLYQXQF-UHFFFAOYSA-N [Cr+3].[Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O Chemical compound [Cr+3].[Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MYSOGRBSLYQXQF-UHFFFAOYSA-N 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
235000013844 butane Nutrition 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
150000001845 chromium compounds Chemical class 0.000 description 1
229910001430 chromium ion Inorganic materials 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003921 oil Substances 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
- C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

FI946167A 1994-12-29 1994-12-29 Menetelmä alkeenien oligomeroimiseksi FI96320C (fi)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
FI946167A FI96320C (fi)	1994-12-29	1994-12-29	Menetelmä alkeenien oligomeroimiseksi
AT95941108T ATE204319T1 (de)	1994-12-29	1995-12-20	Verfahren zur oligomerisation von alkenen
DE69522238T DE69522238T2 (de)	1994-12-29	1995-12-20	Verfahren zur oligomerisation von alkenen
EP95941108A EP0800568B1 (fr)	1994-12-29	1995-12-20	Procede d'oligomerisation d'alcenes
PT95941108T PT800568E (pt)	1994-12-29	1995-12-20	Processo de oligomerizacao de alcenos
PCT/FI1995/000694 WO1996020988A1 (fr)	1994-12-29	1995-12-20	Procede d'oligomerisation d'alcenes
DK95941108T DK0800568T3 (da)	1994-12-29	1995-12-20	Fremgangsmåde til oligomerisering af alkener

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FI946167		1994-12-29
FI946167A FI96320C (fi)	1994-12-29	1994-12-29	Menetelmä alkeenien oligomeroimiseksi

Publications (3)

Publication Number	Publication Date
FI946167A0 FI946167A0 (fi)	1994-12-29
FI96320B FI96320B (fi)	1996-02-29
FI96320C true FI96320C (fi)	1996-06-10

Family

ID=8542080

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI946167A FI96320C (fi)	1994-12-29	1994-12-29	Menetelmä alkeenien oligomeroimiseksi

Country Status (7)

Country	Link
EP (1)	EP0800568B1 (fr)
AT (1)	ATE204319T1 (fr)
DE (1)	DE69522238T2 (fr)
DK (1)	DK0800568T3 (fr)
FI (1)	FI96320C (fr)
PT (1)	PT800568E (fr)
WO (1)	WO1996020988A1 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3862095B2 (ja) *	1994-11-23	2006-12-27	エクソンモービル・ケミカル・パテンツ・インク	ゼオライト結合ゼオライト触媒を用いる炭化水素転化プロセス
RU2137808C1 (ru) *	1998-02-19	1999-09-20	Общество с ограниченной ответственностью "НИЦ НХТ"	Способ получения продуктов димеризации и олигомеризации
RU2135547C1 (ru) *	1998-03-31	1999-08-27	Фалькевич Генрих Семенович	Способ олигомеризации низших олефинов
RU2167845C2 (ru) *	1998-08-25	2001-05-27	Открытое акционерное общество "Научно-исследовательский институт "Ярсинтез"	Способ получения димеров и/или олигомеров алкенов
RU2159268C1 (ru) *	1999-03-10	2000-11-20	Открытое акционерное общество "Всероссийский научно-исследовательский институт органического синтеза в г.Новокуйбышевске"	Способ переработки технической фракции углеводородов c2-c5
RU2252931C2 (ru) *	2003-03-11	2005-05-27	Павлов Олег Станиславович	Способ переработки углеводородной смеси
CN1298684C (zh) *	2004-05-28	2007-02-07	中国石油化工股份有限公司	丁烯齐聚反应制备碳八烯烃的方法
FR2871167B1 (fr) *	2004-06-04	2006-08-04	Inst Francais Du Petrole	Procede d'amelioration de coupes essences et de transformation en gazoles
FR2980195B1 (fr)	2011-09-20	2013-08-23	IFP Energies Nouvelles	Procede de separation du pentene-2 d'une coupe c5 contenant du pentene-2 et du pentene-1 par oligomerisation selective du pentene-1
US20130172650A1 (en) *	2012-01-04	2013-07-04	Phillips 66 Company	Upgrading light olefins
EP2698199A1 (fr) *	2012-08-14	2014-02-19	Saudi Basic Industries Corporation	Procédé de dimérisation d'oléfines
US9670425B2 (en)	2013-12-17	2017-06-06	Uop Llc	Process for oligomerizing and cracking to make propylene and aromatics
US9732285B2 (en)	2013-12-17	2017-08-15	Uop Llc	Process for oligomerization of gasoline to make diesel
RU2698302C1 (ru) *	2017-03-07	2019-08-26	Михайло Барильчук	Установка для переработки алифатических углеводородов c2-c12 с использованием цеолитсодержащих катализаторов

1994
- 1994-12-29 FI FI946167A patent/FI96320C/fi not_active IP Right Cessation
1995
- 1995-12-20 EP EP95941108A patent/EP0800568B1/fr not_active Expired - Lifetime
- 1995-12-20 DK DK95941108T patent/DK0800568T3/da active
- 1995-12-20 AT AT95941108T patent/ATE204319T1/de not_active IP Right Cessation
- 1995-12-20 DE DE69522238T patent/DE69522238T2/de not_active Expired - Fee Related
- 1995-12-20 WO PCT/FI1995/000694 patent/WO1996020988A1/fr not_active Ceased
- 1995-12-20 PT PT95941108T patent/PT800568E/pt unknown

Also Published As

Publication number	Publication date
WO1996020988A1 (fr)	1996-07-11
DE69522238T2 (de)	2002-05-16
ATE204319T1 (de)	2001-09-15
PT800568E (pt)	2001-12-28
EP0800568A1 (fr)	1997-10-15
FI946167A0 (fi)	1994-12-29
EP0800568B1 (fr)	2001-08-16
DE69522238D1 (de)	2001-09-20
FI96320B (fi)	1996-02-29
DK0800568T3 (da)	2001-12-17

Legal Events

Date	Code	Title	Description
1994-12-29	FG	Patent granted	Owner name: NESTE OY
1996-02-01	BB	Publication of examined application
2005-06-30	MA	Patent expired

Publication	Publication Date	Title
US4720602A (en)	1988-01-19	Process for converting C2 to C12 aliphatics to aromatics over a zinc-activated zeolite
CA1189470A (fr)	1985-06-25	Methode pour ameliorer l'activite catalytique
RU2177468C2 (ru)	2001-12-27	Способ конверсии углеводородов с использованием связанного цеолитом цеолитного катализатора
EP0037671B1 (fr)	1983-03-30	Réactions d'oléfines, sélection quant à la forme, catalysées par des acides, sur des zéolites cristallines
CA1153395A (fr)	1983-09-06	Conversion d'olefines en mtbe et en tame
US4590321A (en)	1986-05-20	Aromatization reactions with zeolites containing phosphorus oxide
US5536894A (en)	1996-07-16	MCM-56 as sorbent and catalyst component
FI96320C (fi)	1996-06-10	Menetelmä alkeenien oligomeroimiseksi
CA1262363A (fr)	1989-10-17	Reactions d'aromatisation aux zeolites
US4522929A (en)	1985-06-11	Active zeolite catalysts of improved stability
US4429176A (en)	1984-01-31	Active zeolite catalysts of improved stability
US5968343A (en)	1999-10-19	Hydrocarbon conversion catalyst composition and processes therefor and therewith
EP0057071B1 (fr)	1985-09-11	Prétraitement de charges pour le déparaffinage catalytique
US4804801A (en)	1989-02-14	Process for converting C2 to C8 aliphatics to aromatics over a metal-activated zeolite
US5237120A (en)	1993-08-17	Double bond isomerization of olefin-containing feeds with minimal oligomertization using surface acidity deactivated zeolite catalysts
US5250484A (en)	1993-10-05	Surface modified porous acidic crystalline catalyst
US4605805A (en)	1986-08-12	Acid-catalyzed organic compound conversion
US4291185A (en)	1981-09-22	Alkylation of benzene in petroleum
EP0089795B1 (fr)	1987-03-25	Procédé de conversion d'oléfines en lubrifiants à haut indice de viscosité
CA1228564A (fr)	1987-10-27	Catalyseur et methode d'hydrodeparaffinage
Asaftei et al.	2015	Conversion of ndustrial fedstock mainly with butanes and butenes over B-HZSM-5 and Zn-HZSM-5 modifed catalysts
US4377503A (en)	1983-03-22	Shape selective metallic catalysis
JPS60222428A (ja)	1985-11-07	炭化水素の接触転化法
RU2094419C1 (ru)	1997-10-27	Способ каталитической изомеризации с*008-ароматических углеводородов
US4861933A (en)	1989-08-29	Process for converting aliphatics to aromatics over a gallium-activated zeolite