FR2071188A5 - Antioxidant composition for polyethylene - Google Patents
Antioxidant composition for polyethyleneInfo
- Publication number
- FR2071188A5 FR2071188A5 FR6944209A FR6944209A FR2071188A5 FR 2071188 A5 FR2071188 A5 FR 2071188A5 FR 6944209 A FR6944209 A FR 6944209A FR 6944209 A FR6944209 A FR 6944209A FR 2071188 A5 FR2071188 A5 FR 2071188A5
- Authority
- FR
- France
- Prior art keywords
- polyethylene
- substd
- antioxidant composition
- antioxidant
- mercaptobenzthiol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003963 antioxidant agent Substances 0.000 title abstract 3
- 230000003078 antioxidant effect Effects 0.000 title abstract 2
- 239000004698 Polyethylene Substances 0.000 title 1
- -1 polyethylene Polymers 0.000 title 1
- 229920000573 polyethylene Polymers 0.000 title 1
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 abstract 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 238000010525 oxidative degradation reaction Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920001021 polysulfide Polymers 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 abstract 1
- 229960002447 thiram Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
- C08K5/3725—Sulfides, e.g. R-(S)x-R' containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3437—Six-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
- C08K5/47—Thiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Combination of antioxidants which improve resistance of ethylene (co)polymers against thermo-oxidative degradation comprise a blocked 8-300C phenol, a 1,2-dihydro-2,2,4-trimethylquinoline (which may be polymer), and a Zn-salt of an org. cpd. e.g. mercaptobenzimidazole, mercaptobenzthiol, an N-substd. dithiocarbamic acid or an N-substd. sulphide or polysulphide of thiuram. This antioxidant compsn has synergistic effect.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6944209A FR2071188A5 (en) | 1969-12-19 | 1969-12-19 | Antioxidant composition for polyethylene |
| LU62264D LU62264A1 (en) | 1969-12-19 | 1970-12-17 | |
| BE760576A BE760576A (en) | 1969-12-19 | 1970-12-18 | IMPROVEMENT OF THE RESISTANCE TO THERMOOXIDIZING DEGRADATION OF ETHYLENE POLYMERS AND COPOLYMERS |
| NL7018475A NL7018475A (en) | 1969-12-19 | 1970-12-18 | |
| DE19702062603 DE2062603A1 (en) | 1969-12-19 | 1970-12-18 | Improvement of the resistance to thermo-oxidizing decomposition of polymers and copolymers of ethylene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6944209A FR2071188A5 (en) | 1969-12-19 | 1969-12-19 | Antioxidant composition for polyethylene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2071188A5 true FR2071188A5 (en) | 1971-09-17 |
Family
ID=9044893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR6944209A Expired FR2071188A5 (en) | 1969-12-19 | 1969-12-19 | Antioxidant composition for polyethylene |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE760576A (en) |
| DE (1) | DE2062603A1 (en) |
| FR (1) | FR2071188A5 (en) |
| LU (1) | LU62264A1 (en) |
| NL (1) | NL7018475A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5196462A (en) * | 1991-05-16 | 1993-03-23 | Himont Incorporated | Zinc-salts of certain mercapto compounds as antioxidants for high temperature aging of thermoplastic elastomers |
-
1969
- 1969-12-19 FR FR6944209A patent/FR2071188A5/en not_active Expired
-
1970
- 1970-12-17 LU LU62264D patent/LU62264A1/xx unknown
- 1970-12-18 NL NL7018475A patent/NL7018475A/xx unknown
- 1970-12-18 DE DE19702062603 patent/DE2062603A1/en active Pending
- 1970-12-18 BE BE760576A patent/BE760576A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE760576A (en) | 1971-05-27 |
| LU62264A1 (en) | 1971-05-14 |
| DE2062603A1 (en) | 1971-06-24 |
| NL7018475A (en) | 1971-06-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |