FR2071424A5 - Carbonyl cmpds from olefines in presence - of n-alkyllactams - Google Patents
Carbonyl cmpds from olefines in presence - of n-alkyllactamsInfo
- Publication number
- FR2071424A5 FR2071424A5 FR6945270A FR6945270A FR2071424A5 FR 2071424 A5 FR2071424 A5 FR 2071424A5 FR 6945270 A FR6945270 A FR 6945270A FR 6945270 A FR6945270 A FR 6945270A FR 2071424 A5 FR2071424 A5 FR 2071424A5
- Authority
- FR
- France
- Prior art keywords
- alkyllactams
- cmpds
- olefines
- carbonyl
- pyroolidone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogenated Pyridines (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Olefins can be linear or cyclic. The oxidation uses molecular O2, and is carried out in aqueous soln. containing 90-99% N-alkyl lactam (these are 5 or 6-membered rings, esp. N-methyl pyroolidone) and Pd or Cu salts and Cl-ions. Reaction is at 20-100 degrees C, and pH 3-6.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6945270A FR2071424A5 (en) | 1969-12-29 | 1969-12-29 | Carbonyl cmpds from olefines in presence - of n-alkyllactams |
| NL7000856A NL7000856A (en) | 1969-12-29 | 1970-01-21 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6945270A FR2071424A5 (en) | 1969-12-29 | 1969-12-29 | Carbonyl cmpds from olefines in presence - of n-alkyllactams |
| NL7000856A NL7000856A (en) | 1969-12-29 | 1970-01-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2071424A5 true FR2071424A5 (en) | 1971-09-17 |
Family
ID=26215457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR6945270A Expired FR2071424A5 (en) | 1969-12-29 | 1969-12-29 | Carbonyl cmpds from olefines in presence - of n-alkyllactams |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR2071424A5 (en) |
| NL (1) | NL7000856A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2310989A1 (en) * | 1975-05-13 | 1976-12-10 | Khcheian Khachik | Oxidn of ethylene to acetaldehyde - in aq catalyst soln contg cupric chloro-acetate, palladium salt and acetic acid |
| EP0237108A1 (en) * | 1986-03-06 | 1987-09-16 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of carbonyl compounds |
-
1969
- 1969-12-29 FR FR6945270A patent/FR2071424A5/en not_active Expired
-
1970
- 1970-01-21 NL NL7000856A patent/NL7000856A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2310989A1 (en) * | 1975-05-13 | 1976-12-10 | Khcheian Khachik | Oxidn of ethylene to acetaldehyde - in aq catalyst soln contg cupric chloro-acetate, palladium salt and acetic acid |
| EP0237108A1 (en) * | 1986-03-06 | 1987-09-16 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of carbonyl compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7000856A (en) | 1971-07-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |