FR2072336A5 - Catalytic oxidation/oxidative dehydrogena- - tion of alkanes - Google Patents

Catalytic oxidation/oxidative dehydrogena- - tion of alkanes

Info

Publication number
FR2072336A5
FR2072336A5 FR7042211A FR7042211A FR2072336A5 FR 2072336 A5 FR2072336 A5 FR 2072336A5 FR 7042211 A FR7042211 A FR 7042211A FR 7042211 A FR7042211 A FR 7042211A FR 2072336 A5 FR2072336 A5 FR 2072336A5
Authority
FR
France
Prior art keywords
alkane
propane
catalytic oxidation
dehydrogena
alkanes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7042211A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Power Gas Corp Ltd
Original Assignee
Imperial Chemical Industries Ltd
Power Gas Corp Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd, Power Gas Corp Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of FR2072336A5 publication Critical patent/FR2072336A5/en
Expired legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8435—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A feed gas containing an alkane in the vapour phase at a partial pressure of >=0.20 atm. is led over a suitable catalyst at elevated temperature. The preferred alkane pressure is pref. min. 0.70 atm. and the alkane constitutes preferably more than 70% of the feed gas which also contains air or O2 when alkane-concentration is high. The catalytic oxidation process may oxidise a propane alkane to an aldehyde such as propane or isobutane to acrolein or methacrolein and includes oxidative dehydrogenation such as from propane to propylene, n-butane to butene and/or butadiene, isopentane to isopentene and/or isoprene.
FR7042211A 1969-11-25 1970-11-24 Catalytic oxidation/oxidative dehydrogena- - tion of alkanes Expired FR2072336A5 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB5758769 1969-11-25
GB1407270 1970-03-24
GB3450870 1970-07-16
GB3550070 1970-07-22
GB5013170 1970-10-22

Publications (1)

Publication Number Publication Date
FR2072336A5 true FR2072336A5 (en) 1971-09-24

Family

ID=27516134

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7042211A Expired FR2072336A5 (en) 1969-11-25 1970-11-24 Catalytic oxidation/oxidative dehydrogena- - tion of alkanes

Country Status (6)

Country Link
JP (1) JPS516647B1 (en)
AU (1) AU2266070A (en)
BE (1) BE759434A (en)
DE (1) DE2058054C2 (en)
FR (1) FR2072336A5 (en)
NL (1) NL171258C (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2104020A5 (en) * 1970-08-08 1972-04-14 Degussa
FR2207116A1 (en) * 1972-11-16 1974-06-14 Standard Oil Co
US3928392A (en) * 1973-10-17 1975-12-23 Sun Ventures Inc Oxidation of butane to make anhydride and catalyst therefor
US3968054A (en) * 1973-10-17 1976-07-06 Sun Ventures, Inc. Catalyst for the oxidation of butane to maleic anhydride
FR2386535A1 (en) * 1977-04-04 1978-11-03 Standard Oil Co PREPARATION OF MALEIC ANHYDRIDE FROM HYDROCARBONS WITH 4 CARBON ATOMS, USING A CATALYST CONTAINING TI, P, O
FR2386536A1 (en) * 1977-04-04 1978-11-03 Standard Oil Co PROCESS FOR PREPARING MALEIC ANHYDRIDE BY CATALYTIC OXIDATION OF AN UNSATURE ORGANIC COMPOUND
EP0013741A1 (en) * 1979-01-26 1980-08-06 Chemische Werke Hüls Ag Process for the preparation of maleic anhydride

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3856824A (en) * 1971-12-27 1974-12-24 Monsanto Co Modified p-v-fe catalyst for production of maleic anhydride from saturated aliphatic hydrocarbons
BE791294A (en) * 1972-01-03 1973-05-14 Chem Systems BUTANE OXIDATION PROCESS TO FORM MALEIC ANHYDRIDE
JPS53124673U (en) * 1977-03-14 1978-10-04
JPH085820B2 (en) * 1988-04-05 1996-01-24 旭化成工業株式会社 Method for producing methacrylic acid and / or methacrolein
WO1993013042A1 (en) * 1989-05-22 1993-07-08 Setsuo Yamamatsu Process for producing methacrylic acid and methacrolein
DE19622331A1 (en) * 1996-06-04 1997-12-11 Basf Ag Process of heterogeneously catalyzed gas phase oxidation of propane to acrolein
JP4182237B2 (en) * 1997-09-30 2008-11-19 住友化学株式会社 Catalyst for gas-phase catalytic oxidation reaction of isobutane and method for producing alkene and / or oxygen-containing compound using the same
DE19837517A1 (en) 1998-08-19 2000-02-24 Basf Ag Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using modified air with less nitrogen and more oxygen than normal air as the oxygen source
DE19837519A1 (en) 1998-08-19 2000-02-24 Basf Ag Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using air as the oxygen source and removing nitrogen from residual gas before recycling
US7326802B2 (en) 2002-09-27 2008-02-05 Basf Aktiengesellschaft Preparation of at least one partial oxidation and/or ammoxidation product of propylene
CN106890647B (en) * 2015-12-17 2020-02-14 中国石油天然气股份有限公司 Catalyst for preparing isobutene by dehydrogenating isobutane and preparation method thereof
CN114733548A (en) * 2022-04-09 2022-07-12 润泰化学（泰兴）有限公司 Method for preparing methyl methacrylate by dehydrogenating and esterifying isobutyric acid

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE916167C (en) * 1952-05-14 1954-08-05 Dr E H Karl Ziegler Dr Process for the production of aluminum trialkyls
US3380931A (en) * 1960-01-12 1968-04-30 Shell Oil Co Oxidation catalysts
US3293290A (en) * 1963-03-04 1966-12-20 Union Oil Co Process for the production of unsaturated aldehydes and acids
US3334152A (en) * 1964-01-02 1967-08-01 Petro Tex Chem Corp Unsaturated hydrocarbons by oxidative dehydrogenation over ferrite catalyst

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2104020A5 (en) * 1970-08-08 1972-04-14 Degussa
FR2207116A1 (en) * 1972-11-16 1974-06-14 Standard Oil Co
US3928392A (en) * 1973-10-17 1975-12-23 Sun Ventures Inc Oxidation of butane to make anhydride and catalyst therefor
US3968054A (en) * 1973-10-17 1976-07-06 Sun Ventures, Inc. Catalyst for the oxidation of butane to maleic anhydride
FR2386535A1 (en) * 1977-04-04 1978-11-03 Standard Oil Co PREPARATION OF MALEIC ANHYDRIDE FROM HYDROCARBONS WITH 4 CARBON ATOMS, USING A CATALYST CONTAINING TI, P, O
FR2386536A1 (en) * 1977-04-04 1978-11-03 Standard Oil Co PROCESS FOR PREPARING MALEIC ANHYDRIDE BY CATALYTIC OXIDATION OF AN UNSATURE ORGANIC COMPOUND
EP0013741A1 (en) * 1979-01-26 1980-08-06 Chemische Werke Hüls Ag Process for the preparation of maleic anhydride

Also Published As

Publication number Publication date
NL7017219A (en) 1971-05-27
NL171258C (en) 1983-03-01
JPS516647B1 (en) 1976-03-01
DE2058054A1 (en) 1971-06-09
NL171258B (en) 1982-10-01
BE759434A (en) 1971-04-30
DE2058054C2 (en) 1985-01-31
AU2266070A (en) 1972-06-01

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