FR2076726A5 - Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids - Google Patents

Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids

Info

Publication number
FR2076726A5
FR2076726A5 FR7002655A FR7002655A FR2076726A5 FR 2076726 A5 FR2076726 A5 FR 2076726A5 FR 7002655 A FR7002655 A FR 7002655A FR 7002655 A FR7002655 A FR 7002655A FR 2076726 A5 FR2076726 A5 FR 2076726A5
Authority
FR
France
Prior art keywords
fatty acids
glass fibres
elastomers
free
fibres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7002655A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE19702002895 priority Critical patent/DE2002895A1/en
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to FR7002655A priority patent/FR2076726A5/en
Application granted granted Critical
Publication of FR2076726A5 publication Critical patent/FR2076726A5/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/27—Rubber latex

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

Glass fibre-reinforced rubber is made by (1) depositing on glass fibres an organo-Si compound in which the organic group contains an NH2 group, (2) coating the treated fibres with a S-curable elastomer containing 0.05% of ZnO and 0.5% of free fatty acid, up to 5% of S and up to 5% of a vulcanisation accelerator, and (3) applying a curable rubber to the fibres and curing the resulting composite. The S-curable elastomer can be a natural, SBR, nitrile, butyl or halogenated butyl rubber, neoprene, a polydiene or a C2H4/C3H6 terpolymer. The use of elastomers containing no more than small amounts of ZnO and fatty acids improves the bonding of the elastomer to the glass fibres through the aminosilane.
FR7002655A 1970-01-23 1970-01-26 Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids Expired FR2076726A5 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19702002895 DE2002895A1 (en) 1970-01-23 1970-01-23 Glass fiber reinforced elastomers
FR7002655A FR2076726A5 (en) 1970-01-23 1970-01-26 Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19702002895 DE2002895A1 (en) 1970-01-23 1970-01-23 Glass fiber reinforced elastomers
FR7002655A FR2076726A5 (en) 1970-01-23 1970-01-26 Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids

Publications (1)

Publication Number Publication Date
FR2076726A5 true FR2076726A5 (en) 1971-10-15

Family

ID=25758527

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7002655A Expired FR2076726A5 (en) 1970-01-23 1970-01-26 Aminosilane treated glass fibres coated with elastomers - free from zinc oxide and fatty acids

Country Status (2)

Country Link
DE (1) DE2002895A1 (en)
FR (1) FR2076726A5 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2479802A1 (en) * 1980-04-03 1981-10-09 Ppg Industries Inc Reducing chemical degradation in fibre reinforced polymers - using pref. phenolic or di:arylamine antioxidants used as stable aq. emulsions in glass fibre finishing compsns.
US4483948A (en) * 1980-09-24 1984-11-20 Ppg Industries, Inc. Antioxidants and reinforced polymers and oil-in-water emulsions of antioxidants

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2479802A1 (en) * 1980-04-03 1981-10-09 Ppg Industries Inc Reducing chemical degradation in fibre reinforced polymers - using pref. phenolic or di:arylamine antioxidants used as stable aq. emulsions in glass fibre finishing compsns.
US4483948A (en) * 1980-09-24 1984-11-20 Ppg Industries, Inc. Antioxidants and reinforced polymers and oil-in-water emulsions of antioxidants

Also Published As

Publication number Publication date
DE2002895A1 (en) 1971-07-29

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Legal Events

Date Code Title Description
ST Notification of lapse