FR2378052A1 - Procede de preparation de polystyrylpyridine - Google Patents
Procede de preparation de polystyrylpyridineInfo
- Publication number
- FR2378052A1 FR2378052A1 FR7701955A FR7701955A FR2378052A1 FR 2378052 A1 FR2378052 A1 FR 2378052A1 FR 7701955 A FR7701955 A FR 7701955A FR 7701955 A FR7701955 A FR 7701955A FR 2378052 A1 FR2378052 A1 FR 2378052A1
- Authority
- FR
- France
- Prior art keywords
- polystyrylpyridine
- excess
- preparation
- pyridine derivatives
- solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- 238000006068 polycondensation reaction Methods 0.000 abstract 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 abstract 2
- 150000003222 pyridines Chemical class 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
- C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
- C08G16/025—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds
- C08G16/0268—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S524/924—Treating or preparing a nonaqueous solution of a solid polymer or specified intermediate condensation product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La présente invention a pour objet la préparation de solutions de polystyrylpyridine. Le procédé selon l'invention consiste à effectuer la polycondensation de l'aldéhyde téréphtalique et d'au moins un dérivé pyridinique portant au moins deux substituants méthyles réactifs à une température comprise entre 150"C et 200 degrés C, en présence d'un excès de dérivés pyridiniques. La réaction de polycondensation est arrêtée lorsque le taux de condensation est égal à au moins 50 %; l'excès de dérivés pyridiniques est alors partiellement éliminé et le polycondensat est dissous dans un solvant choisi parmi la méthyléthylcétone, l'acétate d'éthyle, le chlorure de méthylène, le trichlorethylène, le chlorobenzene, le n-propanol. Les solutions de polystyrylpyridine obtenues par le procédé de l'invention sont utiles pour la fabrication de matériaux composites.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7701955A FR2378052A1 (fr) | 1977-01-25 | 1977-01-25 | Procede de preparation de polystyrylpyridine |
| US05/870,854 US4163740A (en) | 1977-01-25 | 1978-01-19 | Process for the preparation of polystyrylpyridine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7701955A FR2378052A1 (fr) | 1977-01-25 | 1977-01-25 | Procede de preparation de polystyrylpyridine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2378052A1 true FR2378052A1 (fr) | 1978-08-18 |
| FR2378052B1 FR2378052B1 (fr) | 1981-06-12 |
Family
ID=9185846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7701955A Granted FR2378052A1 (fr) | 1977-01-25 | 1977-01-25 | Procede de preparation de polystyrylpyridine |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4163740A (fr) |
| FR (1) | FR2378052A1 (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4471107A (en) * | 1984-01-30 | 1984-09-11 | American Cyanamid Company | Process for the prepartion of vinylpolystyrylpyridine compounds |
| US4515938A (en) * | 1984-03-12 | 1985-05-07 | The Dow Chemical Company | Hydroxystyrylazapolymers |
| US4500690A (en) * | 1984-05-11 | 1985-02-19 | The Dow Chemical Company | Thermosetting polymers from aromatic aldehydes, azines and isopropenyl phenols |
| US4543388A (en) * | 1984-05-17 | 1985-09-24 | The Dow Chemical Company | Thermosettable polymers or prepolymers prepared from polymethylated pyrazines and aromatic polyaldehydes and cured products therefrom |
| US4575542A (en) * | 1985-04-23 | 1986-03-11 | The Dow Chemical Company | Thermosettable polystyrylpyridine prepolymer terminated with ethylenically unsaturated groups and cured products therefrom |
| US4522960A (en) * | 1984-08-06 | 1985-06-11 | Exxon Research & Engineering Co. | Controlled gelation on nonaqueous solutions containing low charge density polyampholytes |
| US4520158A (en) * | 1984-08-06 | 1985-05-28 | Exxon Research & Engineering Co. | Nonaqueous solvent soluble polyampholytes-viscosifier and shear thickening additive |
| US4578439A (en) * | 1984-08-09 | 1986-03-25 | The Dow Chemical Company | Styryl pyridine cyanates, styryl pyrazine cyanates and polymers thereof |
| US4575530A (en) * | 1985-04-08 | 1986-03-11 | Exxon Research And Engineering Co. | Multifunctional polymeric additive |
| US4629770A (en) * | 1985-04-23 | 1986-12-16 | The Dow Chemical Company | Thermosettable polystyrylpyrazine polymers terminated with ethylenically unsaturated groups and cured products therefrom |
| US4613663A (en) * | 1985-09-19 | 1986-09-23 | The Dow Chemical Company | Thermoplastic and thermosettable products prepared by reacting nitrogen-containing heterocyclic compounds with aromatic aldehydes |
| US4640945A (en) * | 1985-11-12 | 1987-02-03 | Exxon Research And Engineering Company | Drag reduction with novel hydrocarbon soluble polyampholytes |
| JP3128653B2 (ja) | 1990-09-11 | 2001-01-29 | 東邦レーヨン株式会社 | 熱硬化性樹脂組成物 |
| US20080152924A1 (en) * | 2006-12-22 | 2008-06-26 | Booze J David | Production process for parts of a perfluoropolymer composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2261296B1 (fr) * | 1974-02-14 | 1978-09-29 | Onera (Off Nat Aerospatiale) |
-
1977
- 1977-01-25 FR FR7701955A patent/FR2378052A1/fr active Granted
-
1978
- 1978-01-19 US US05/870,854 patent/US4163740A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4163740A (en) | 1979-08-07 |
| FR2378052B1 (fr) | 1981-06-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |