FR2400565A1 - Procede pour recuperer le cuivre et le zinc de sulfures complexes - Google Patents
Procede pour recuperer le cuivre et le zinc de sulfures complexesInfo
- Publication number
- FR2400565A1 FR2400565A1 FR7824217A FR7824217A FR2400565A1 FR 2400565 A1 FR2400565 A1 FR 2400565A1 FR 7824217 A FR7824217 A FR 7824217A FR 7824217 A FR7824217 A FR 7824217A FR 2400565 A1 FR2400565 A1 FR 2400565A1
- Authority
- FR
- France
- Prior art keywords
- zinc
- solution
- stage
- acid
- sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title abstract 4
- 239000011701 zinc Substances 0.000 title abstract 4
- 229910052725 zinc Inorganic materials 0.000 title abstract 4
- 150000003568 thioethers Chemical class 0.000 title 1
- 239000000243 solution Substances 0.000 abstract 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 235000003891 ferrous sulphate Nutrition 0.000 abstract 2
- 239000011790 ferrous sulphate Substances 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 abstract 2
- 238000002386 leaching Methods 0.000 abstract 2
- 239000002244 precipitate Substances 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 239000005083 Zinc sulfide Substances 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- 229910052935 jarosite Inorganic materials 0.000 abstract 1
- 229910052976 metal sulfide Inorganic materials 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 229910052984 zinc sulfide Inorganic materials 0.000 abstract 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
- C22B15/0093—Treating solutions by chemical methods by gases, e.g. hydrogen or hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
On soumet les sulfures métalliques à une lixiviation acide à contre-courant en deux stades 1,7 pour former un sulfure de cuivre simple et une solution de sulfate ferreux; on effectue le second stade de lixiviation acide en deux étapes; dans la première étape 8, on opère avec une concentration de la pulpe relativement élevée et une concentration élevée en acide pour extraire le fer et le zinc, on dilue la suspension obtenue et, dans la seconde étape 9, on opère avec une concentration relativement faible de la pulpe et une faible concentration en acide pour dissoudre le sulfate ferreux précipité, précipiter le cuivre dissous par l'acide sulfhydrique et précipiter le zinc en solution sous forme de sulfure de zinc pratiquement pur; la solution de dilution de la suspension de la première étape du second stade est de préférence une solution d'acide sulfunque produit provenant d'une précipitation de jarosite et une solution contenant du fer et du zinc d'une lixiviation d'activation ultérieure.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA285,127A CA1104837A (fr) | 1977-08-19 | 1977-08-19 | Methode d'extraction du cuivre et du zinc en presence dans les sulfures complexes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2400565A1 true FR2400565A1 (fr) | 1979-03-16 |
| FR2400565B1 FR2400565B1 (fr) | 1983-09-02 |
Family
ID=4109371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7824217A Granted FR2400565A1 (fr) | 1977-08-19 | 1978-08-18 | Procede pour recuperer le cuivre et le zinc de sulfures complexes |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4157912A (fr) |
| JP (1) | JPS5456022A (fr) |
| AU (1) | AU516361B2 (fr) |
| BE (1) | BE869857A (fr) |
| CA (1) | CA1104837A (fr) |
| DE (1) | DE2835694A1 (fr) |
| FR (1) | FR2400565A1 (fr) |
| GB (1) | GB2003125B (fr) |
| ZA (1) | ZA784376B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111549223A (zh) * | 2020-06-23 | 2020-08-18 | 中南大学 | 一种锌湿法冶炼除铜剂及其应用方法 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4511541A (en) * | 1982-12-02 | 1985-04-16 | J. R. Simplot Company | Process for the recovery of cadmium and other metals from solution |
| FI75868C (fi) * | 1986-10-03 | 1988-08-08 | Outokumpu Oy | Saett att utfaella och avskilja metaller. |
| CA2417413C (fr) * | 2000-07-25 | 2008-10-28 | Phelps Dodge Corporation | Procede de recuperation de metaux precieux a partir de materiaux metalliferes par lixiviation sous pression haute temperature |
| CA2417417C (fr) | 2000-07-25 | 2008-09-30 | Phelps Dodge Corporation | Procede pour recuperer des metaux precieux dans des materiaux contenant des metaux, par lixiviation sous pression a temperature moyenne |
| JP4171300B2 (ja) | 2000-07-25 | 2008-10-22 | フェルプス ドッジ コーポレイション | 硫酸の生成および金属の回収のために高温圧力浸出を使用する元素硫黄含有材料の処理 |
| US7476308B2 (en) * | 2001-07-25 | 2009-01-13 | Phelps Dodge Corporation | Process for multiple stage direct electrowinning of copper |
| US6451088B1 (en) * | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Method for improving metals recovery using high temperature leaching |
| US6451089B1 (en) | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Process for direct electrowinning of copper |
| US20050126923A1 (en) * | 2001-07-25 | 2005-06-16 | Phelps Dodge Corporation | Process for recovery of copper from copper-bearing material using medium temperature pressure leaching, direct electrowinning and solvent/solution extraction |
| FI116071B (fi) * | 2003-02-26 | 2005-09-15 | Outokumpu Oy | Menetelmä sinkin talteenottamiseksi vastavirtaliuotuksella |
| US7736487B2 (en) * | 2004-10-29 | 2010-06-15 | Freeport-Mcmoran Corporation | Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solution extraction |
| AP1924A (en) * | 2004-10-29 | 2008-12-05 | Phelps Dodge Corp | Process for multiple stage direct electrowinning of copper |
| BRPI0419191B1 (pt) * | 2004-10-29 | 2013-05-14 | mÉtodo de recuperaÇço de cobre a partir de um material metalÍfero. | |
| FI126764B (en) | 2011-12-22 | 2017-05-15 | Outotec Oyj | A method for enhancing reactor volume utilization in hydrometallurgical leaching |
| FI129230B (en) * | 2014-11-20 | 2021-09-30 | Smidth As F L | Systems and methods for improving the recovery of metal during atmospheric leaching of metal sulphides |
| US11898221B2 (en) | 2017-05-17 | 2024-02-13 | Flsmidth A/S | Activation system and method for enhancing metal recovery during atmospheric leaching of metal sulfides |
| KR102678432B1 (ko) * | 2023-11-21 | 2024-06-27 | 고려아연 주식회사 | 황산아연 용액으로부터 구리를 회수하는 방법 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR975786A (fr) * | 1947-12-06 | 1951-03-09 | Orkla Grube Aktiebolag | Procédé de traitement complet de pyrites de fer contenant du cuivre |
| FR2125524A1 (fr) * | 1971-02-19 | 1972-09-29 | Cominco Ltd | |
| FR2128615A1 (fr) * | 1971-03-05 | 1972-10-20 | Cominco Ltd | |
| FR2132875A1 (fr) * | 1971-04-13 | 1972-11-24 | Mac Gauley Patrick | |
| FR2245770A1 (fr) * | 1973-09-28 | 1975-04-25 | Sherritt Gordon Mines Ltd | |
| US3891522A (en) * | 1972-02-28 | 1975-06-24 | Cominco Ltd | Hydrometallurgical process for treating copper-iron sulphides |
| US3957602A (en) * | 1974-07-24 | 1976-05-18 | Cyprus Metallurgical Processes Corporation | Recovery of copper from chalcopyrite utilizing copper sulfate leach |
| US3964901A (en) * | 1973-10-19 | 1976-06-22 | Sherritt Gordon Mines Limited | Production of copper and sulfur from copper-iron sulfides |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3053651A (en) * | 1958-01-21 | 1962-09-11 | Chemetals Corp | Treatment of sulfide minerals |
| US4049770A (en) * | 1973-10-19 | 1977-09-20 | Sherritt Gordon Mines Limited | Recovery of copper and zinc as sulfides from copper-iron sulfides |
| US4093526A (en) * | 1977-09-08 | 1978-06-06 | Amax Inc. | Hydrometallurgical leaching and refining of nickel-copper concentrates, and electrowinning of copper |
-
1977
- 1977-08-19 CA CA285,127A patent/CA1104837A/fr not_active Expired
-
1978
- 1978-08-01 AU AU38509/78A patent/AU516361B2/en not_active Expired
- 1978-08-02 ZA ZA00784376A patent/ZA784376B/xx unknown
- 1978-08-14 US US05/933,372 patent/US4157912A/en not_active Expired - Lifetime
- 1978-08-14 GB GB7833189A patent/GB2003125B/en not_active Expired
- 1978-08-16 DE DE19782835694 patent/DE2835694A1/de not_active Withdrawn
- 1978-08-18 JP JP10079978A patent/JPS5456022A/ja active Pending
- 1978-08-18 BE BE189979A patent/BE869857A/fr not_active IP Right Cessation
- 1978-08-18 FR FR7824217A patent/FR2400565A1/fr active Granted
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR975786A (fr) * | 1947-12-06 | 1951-03-09 | Orkla Grube Aktiebolag | Procédé de traitement complet de pyrites de fer contenant du cuivre |
| FR2125524A1 (fr) * | 1971-02-19 | 1972-09-29 | Cominco Ltd | |
| FR2128615A1 (fr) * | 1971-03-05 | 1972-10-20 | Cominco Ltd | |
| FR2132875A1 (fr) * | 1971-04-13 | 1972-11-24 | Mac Gauley Patrick | |
| US3891522A (en) * | 1972-02-28 | 1975-06-24 | Cominco Ltd | Hydrometallurgical process for treating copper-iron sulphides |
| FR2245770A1 (fr) * | 1973-09-28 | 1975-04-25 | Sherritt Gordon Mines Ltd | |
| US3964901A (en) * | 1973-10-19 | 1976-06-22 | Sherritt Gordon Mines Limited | Production of copper and sulfur from copper-iron sulfides |
| US3957602A (en) * | 1974-07-24 | 1976-05-18 | Cyprus Metallurgical Processes Corporation | Recovery of copper from chalcopyrite utilizing copper sulfate leach |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111549223A (zh) * | 2020-06-23 | 2020-08-18 | 中南大学 | 一种锌湿法冶炼除铜剂及其应用方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1104837A (fr) | 1981-07-14 |
| DE2835694A1 (de) | 1979-03-01 |
| JPS5456022A (en) | 1979-05-04 |
| US4157912A (en) | 1979-06-12 |
| GB2003125B (en) | 1982-02-24 |
| AU516361B2 (en) | 1981-05-28 |
| BE869857A (fr) | 1978-12-18 |
| GB2003125A (en) | 1979-03-07 |
| ZA784376B (en) | 1979-06-27 |
| FR2400565B1 (fr) | 1983-09-02 |
| AU3850978A (en) | 1980-02-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FR2400565A1 (fr) | Procede pour recuperer le cuivre et le zinc de sulfures complexes | |
| US3616331A (en) | Recovery of nickel and copper from sulfides | |
| US2726934A (en) | Hydrometallurgical method of extracting metal values | |
| GB1494990A (en) | Two-stage pressure leaching process for zinc and iron bearing mineral sulphides | |
| CA2221940A1 (fr) | Extraction hydrometallurgique, assistee par des chlorures de nickel et de cobalt a partir de minerais sulphures | |
| RU98104256A (ru) | Способ гидрометаллургического извлечения никеля из никелевых штейнов двух видов | |
| CA2038165A1 (fr) | Methode de recuperation de l'or a partir de minerais difficilement fusibles | |
| SE9902008L (sv) | Förfarande för rening av sur laklösning | |
| CA2229232A1 (fr) | Procede d'extraction du nickel par hydrometallurgie a partir de deux mattes de nickel differentes | |
| GB1378053A (en) | Processes for the precipitation of copper sulhpide | |
| US5750019A (en) | Process for hydrometallurgic and electrochemical treatment of sulfur antimony ores with production of electrolytic antimony and elemental sulfur | |
| Zhang et al. | SO2/O2 as an oxidant in hydrometallurgy | |
| GB1374851A (en) | Hydrometallurgical process for extraction of copper and sulphur from copper-iron sulphides | |
| KR830010208A (ko) | 아연-함유 황화물로부터 아연회수 방법 | |
| KR20050006158A (ko) | 금의 회수 방법 | |
| FR2313452A1 (fr) | Procede de traitement des residus de lixiviation des minerais de zinc | |
| MA20364A1 (fr) | Procede pour recuperer des metaux a partir de matieres contenant de fer | |
| JP3069520B2 (ja) | ヒ素硫化物含有製錬中間物からのヒ素の分離方法 | |
| FR2391284A1 (fr) | Procede d'extraction de zinc d'un minerai contenant du sulfure de zinc | |
| GB1375055A (fr) | ||
| US2390540A (en) | Recovery of copper from copperbearing solutions | |
| JPS5952696B2 (ja) | 銅電解アノ−ドスライムから銅及びセレニウムを回収する方法 | |
| KR20030043957A (ko) | 황화광 물질로부터 아연을 회수하기 위한 가압 침출 방법 | |
| GB746633A (en) | Improved method of extracting zinc from zinc bearing material | |
| IL41674A (en) | Recovery of copper,zinc or nickel from sulfide concentrates |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |