FR2409255A1 - Procede pour la cyclisation d'esters de l'acide g-chlorocarboxylique - Google Patents

Procede pour la cyclisation d'esters de l'acide g-chlorocarboxylique

Info

Publication number
FR2409255A1
FR2409255A1 FR7831874A FR7831874A FR2409255A1 FR 2409255 A1 FR2409255 A1 FR 2409255A1 FR 7831874 A FR7831874 A FR 7831874A FR 7831874 A FR7831874 A FR 7831874A FR 2409255 A1 FR2409255 A1 FR 2409255A1
Authority
FR
France
Prior art keywords
cyclization
represent
ester
general formula
condensing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7831874A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Deutsche Gold und Silber Scheideanstalt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH, Deutsche Gold und Silber Scheideanstalt filed Critical Degussa GmbH
Publication of FR2409255A1 publication Critical patent/FR2409255A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/757—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

CE PROCEDE CONCERNE LA CYCLISATION D'ESTER DE L'ACIDE CHLOROCARBOXYLIQUE DE FORMULE GENERALE: (CF DESSIN DANS BOPI) DANS LAQUELLE R, R, R, R, R ET R SONT IDENTIQUES OU DIFFERENTS ET REPRESENTENT UN RADICAL ALKYLE LINEAIRE OU RAMIFIE EN C A C, OU DANS LAQUELLE ILS PEUVENT EGALEMENT, A L'EXCEPTION DE R, REPRESENTER UN ATOME D'HYDROGENE, CETTE CYCLISATION DEVANT FOURNIR DES ACIDES CYCLOPROPANECARBOXYLIQUES, EVENTUELLEMENT SUBSTITUES, ET LEURS ESTERS, DE FORMULE GENERALE: (CF DESSIN DANS BOPI) DANS LAQUELLE LES SYMBOLES R A R ONT LA SIGNIFICATION DONNEE CI-DESSUS ET DANS LAQUELLE R PEUT EN OUTRE REPRESENTER UN ATOME D'HYDROGENE, LA CYCLISATION S'EFFECTUANT AU MOYEN D'UN AGENT DE CONDENSATION BASIQUE ET ETANT EVENTUELLEMENT SUIVIE D'UNE SAPONIFICATION DE L'ESTER. IL EST CARACTERISE EN CE QU'ON UTILISE, COMME AGENT DE CONDENSATION, UN ALCOOLATE ALCALIN ANHYDRE, EN CE QUE LA CYCLISATION S'EFFECTUE DANS UN SOLVANT ORGANIQUE INERTE ET EN CE QU'ON ELIMINE PAR DISTILLATION EN CONTINU L'ALCOOL QUI SE FORME LORS DE LA REACTION.
FR7831874A 1977-11-16 1978-11-10 Procede pour la cyclisation d'esters de l'acide g-chlorocarboxylique Withdrawn FR2409255A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19772751133 DE2751133A1 (de) 1977-11-16 1977-11-16 Verfahren zum cyclisieren von gamma-chlorcarbonsaeureestern

Publications (1)

Publication Number Publication Date
FR2409255A1 true FR2409255A1 (fr) 1979-06-15

Family

ID=6023826

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7831874A Withdrawn FR2409255A1 (fr) 1977-11-16 1978-11-10 Procede pour la cyclisation d'esters de l'acide g-chlorocarboxylique

Country Status (8)

Country Link
JP (1) JPS5479254A (fr)
BE (1) BE872029A (fr)
DE (1) DE2751133A1 (fr)
FR (1) FR2409255A1 (fr)
GB (1) GB2008110A (fr)
IL (1) IL55932A0 (fr)
IT (1) IT1109289B (fr)
NL (1) NL7808602A (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2941211C2 (de) * 1979-10-11 1982-11-25 Degussa Ag, 6000 Frankfurt Verfahren zum gegebenenfalls kontinuierlichen Cyclisieren von γ-Chlorcarbonsäureestern
EP0031932B1 (fr) * 1979-12-22 1987-07-01 Hüls Troisdorf Aktiengesellschaft Lactones substituées, dérivés d'acide pentanoique et procédé pour leur préparation
DE3537813C1 (de) * 1985-10-24 1987-02-05 Degussa Verfahren zur Herstellung von 1-Methylcyclopropancarboxaldehyd
DE3538133A1 (de) * 1985-10-26 1987-04-30 Huels Chemische Werke Ag Verfahren zur herstellung von reinen, chlorfreien cyclopropancarbonsaeureestern
GB8615313D0 (en) * 1986-06-23 1986-07-30 Ici Plc Chemical process
CA2056840A1 (fr) * 1990-12-17 1992-06-18 Thomas Meul Methode de preparation d'acide dimethylcyclopropanecarboxylique
DE4222497A1 (de) * 1992-07-09 1994-01-13 Huels Chemische Werke Ag Verfahren zur Herstellung von chlorfreiem Cyclopropancarbonsäuremethylester
JP3140698B2 (ja) * 1996-11-26 2001-03-05 ダイセル化学工業株式会社 ４−ヒドロキシ−２−ピロリジノンの製造方法ならびに精製方法
US6252089B1 (en) 1997-11-25 2001-06-26 Daicel Chemical Industries, Ltd. Method of producing 4-hydroxy-2-pyrrolidinone and method of purifying the same
US6552217B2 (en) * 2000-08-01 2003-04-22 Eastman Chemical Company Process for the preparation of alkyl 1-methylcyclopropanecarboxylate

Also Published As

Publication number Publication date
IT7851913A0 (it) 1978-11-15
NL7808602A (nl) 1979-05-18
JPS5479254A (en) 1979-06-25
BE872029A (fr) 1979-05-14
DE2751133A1 (de) 1979-05-17
GB2008110A (en) 1979-05-31
IL55932A0 (en) 1979-01-31
IT1109289B (it) 1985-12-16

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Legal Events

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ST Notification of lapse