FR2445310A1 - Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur - Google Patents

Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur

Info

Publication number
FR2445310A1
FR2445310A1 FR7931595A FR7931595A FR2445310A1 FR 2445310 A1 FR2445310 A1 FR 2445310A1 FR 7931595 A FR7931595 A FR 7931595A FR 7931595 A FR7931595 A FR 7931595A FR 2445310 A1 FR2445310 A1 FR 2445310A1
Authority
FR
France
Prior art keywords
oxidation
methacrylic acid
catalyst
methacroleine
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7931595A
Other languages
English (en)
Other versions
FR2445310B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon Research and Development Corp
Original Assignee
Halcon Research and Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/972,745 external-priority patent/US4252682A/en
Priority claimed from US05/973,354 external-priority patent/US4374757A/en
Priority claimed from US05/972,743 external-priority patent/US4252681A/en
Priority claimed from US05/973,495 external-priority patent/US4252683A/en
Priority claimed from US06/027,634 external-priority patent/US4261859A/en
Priority claimed from US06/027,633 external-priority patent/US4261858A/en
Priority claimed from US06/027,635 external-priority patent/US4261860A/en
Priority claimed from US06/027,632 external-priority patent/US4240930A/en
Priority claimed from US06/047,860 external-priority patent/US4377501A/en
Priority claimed from US06/081,406 external-priority patent/US4271040A/en
Application filed by Halcon Research and Development Corp filed Critical Halcon Research and Development Corp
Publication of FR2445310A1 publication Critical patent/FR2445310A1/fr
Publication of FR2445310B1 publication Critical patent/FR2445310B1/fr
Application granted granted Critical
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne une composition de catalyseur permettant d'oxyder par O2 moléculaire des aldéhydes insaturés en phase vapeur. Le catalyseur comprend une combinaison d'oxydes de Mo, Cu, P, Sb et Cs et/ou Ca, et il peut éventuellement aussi comprendre au moins l'un des éléments Ni, Zn Ru, Rh, Pd, Pt, As, K, Rb, Sr, Ba, Cr, V, Nb, W, Mn, Re et les terres rares, y compris La. Application : oxydation de la méthacroléine en acide méthacrylique pouvant servir à la fabrication de verres organiques
FR7931595A 1978-12-26 1979-12-24 Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur Granted FR2445310A1 (fr)

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
US05/972,745 US4252682A (en) 1978-12-26 1978-12-26 Catalyst for producing methacrylic acid
US05/973,495 US4252683A (en) 1978-12-26 1978-12-26 Catalyst for producing methacrylic acid
US05/972,743 US4252681A (en) 1978-12-26 1978-12-26 Catalyst for producing methacrylic acid
US05/973,354 US4374757A (en) 1978-12-26 1978-12-26 Catalyst and process for producing methacrylic acid
US06/027,633 US4261858A (en) 1979-04-06 1979-04-06 Catalyst for producing methacrylic acid
US06/027,634 US4261859A (en) 1979-04-06 1979-04-06 Catalyst for producing methacrylic acid
US06/027,635 US4261860A (en) 1979-04-06 1979-04-06 Catalyst for producing methacrylic acid
US06/027,632 US4240930A (en) 1979-04-06 1979-04-06 Catalyst and process for producing methacrylic acid
US06/047,860 US4377501A (en) 1978-12-26 1979-06-12 Catalyst and process for producing methacrylic acid
US06/081,406 US4271040A (en) 1978-12-26 1979-10-03 Catalyst and process for producing methacrylic acid

Publications (2)

Publication Number Publication Date
FR2445310A1 true FR2445310A1 (fr) 1980-07-25
FR2445310B1 FR2445310B1 (fr) 1984-05-25

Family

ID=27580733

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7931595A Granted FR2445310A1 (fr) 1978-12-26 1979-12-24 Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur

Country Status (7)

Country Link
BR (1) BR7908476A (fr)
DE (1) DE2952455C2 (fr)
FR (1) FR2445310A1 (fr)
GB (3) GB2040717B (fr)
IT (1) IT1164100B (fr)
MX (1) MX154396A (fr)
NL (1) NL7909142A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2509722A1 (fr) * 1981-07-17 1983-01-21 Halcon Sd Group Inc Procede d'oxydation catalytique, en phase vapeur, de la methacroleine en acide methacrylique par de l'oxygene moleculaire

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3030243A1 (de) * 1980-08-09 1982-03-18 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
US4511548A (en) * 1981-12-18 1985-04-16 The Standard Oil Company Ammoxidation of methanol to produce hydrogen cyanide
DE3208571A1 (de) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator, insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
DE3208572A1 (de) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen Verfahren und katalysator zur herstellung von methacrylsaeure
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
DE19630832A1 (de) * 1996-07-31 1998-02-05 Hoechst Ag Verfahren zur selektiven Herstellung von Essigsäure

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2273586A1 (fr) * 1974-06-07 1976-01-02 Nippon Kayaku Kk Catalyseur d'oxydation pour produire l'acide methacrylique
FR2275436A1 (fr) * 1974-05-31 1976-01-16 Mitsubishi Rayon Co Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique
FR2297082A1 (fr) * 1975-01-13 1976-08-06 Standard Oil Co Catalyseurs d'oxydation
FR2306188A1 (fr) * 1975-04-03 1976-10-29 Mitsubishi Rayon Co Procede de preparation d'un acide carboxylique insature
US4000088A (en) * 1974-06-03 1976-12-28 Nippon Kayaku Co., Ltd. Oxidation catalyst for the manufacture of methacrylic acid
FR2333770A1 (fr) * 1975-12-03 1977-07-01 Mitsubishi Rayon Co Procede catalytique de fabrication d'acides carboxyliques insatures et produits obtenus par ce procede

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2460541C3 (de) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure
GB1489559A (en) * 1975-03-03 1977-10-19 Mitsubishi Rayon Co Catalytic process for the preparation of acrylic acid or methacrylic acid

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2275436A1 (fr) * 1974-05-31 1976-01-16 Mitsubishi Rayon Co Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique
US4000088A (en) * 1974-06-03 1976-12-28 Nippon Kayaku Co., Ltd. Oxidation catalyst for the manufacture of methacrylic acid
FR2273586A1 (fr) * 1974-06-07 1976-01-02 Nippon Kayaku Kk Catalyseur d'oxydation pour produire l'acide methacrylique
FR2297082A1 (fr) * 1975-01-13 1976-08-06 Standard Oil Co Catalyseurs d'oxydation
FR2306188A1 (fr) * 1975-04-03 1976-10-29 Mitsubishi Rayon Co Procede de preparation d'un acide carboxylique insature
FR2333770A1 (fr) * 1975-12-03 1977-07-01 Mitsubishi Rayon Co Procede catalytique de fabrication d'acides carboxyliques insatures et produits obtenus par ce procede

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2509722A1 (fr) * 1981-07-17 1983-01-21 Halcon Sd Group Inc Procede d'oxydation catalytique, en phase vapeur, de la methacroleine en acide methacrylique par de l'oxygene moleculaire

Also Published As

Publication number Publication date
GB2040717B (en) 1983-09-14
GB2121309B (en) 1984-06-06
IT1164100B (it) 1987-04-08
GB8307119D0 (en) 1983-04-20
BR7908476A (pt) 1980-09-23
DE2952455C2 (de) 1988-07-28
GB2116063A (en) 1983-09-21
DE2952455A1 (de) 1980-07-17
GB8307118D0 (en) 1983-04-20
MX154396A (es) 1987-08-07
IT7951168A0 (it) 1979-12-21
GB2040717A (en) 1980-09-03
GB2121309A (en) 1983-12-21
NL7909142A (nl) 1980-06-30
GB2116063B (en) 1984-02-01
FR2445310B1 (fr) 1984-05-25

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