FR3033565B1 - Precatalyseur a base de fer et son utilisation dans la polymerisation d'olefines - Google Patents

Precatalyseur a base de fer et son utilisation dans la polymerisation d'olefines

Info

Publication number
FR3033565B1
FR3033565B1 FR1551954A FR1551954A FR3033565B1 FR 3033565 B1 FR3033565 B1 FR 3033565B1 FR 1551954 A FR1551954 A FR 1551954A FR 1551954 A FR1551954 A FR 1551954A FR 3033565 B1 FR3033565 B1 FR 3033565B1
Authority
FR
France
Prior art keywords
precatalyst
olefins
polymerization
iron
feumalc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1551954A
Other languages
English (en)
Other versions
FR3033565A1 (fr
Inventor
Sebastien Norsic
Vincent Monteil
Jean Raynaud
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Universite Claude Bernard Lyon 1
Original Assignee
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Universite Claude Bernard Lyon 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Ecole Superieure de Chimie Physique Electronique de Lyon, Universite Claude Bernard Lyon 1 filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1551954A priority Critical patent/FR3033565B1/fr
Priority to PCT/EP2016/055056 priority patent/WO2016142436A1/fr
Priority to EP16709385.5A priority patent/EP3268400B1/fr
Priority to JP2017546897A priority patent/JP6824891B2/ja
Priority to US15/555,991 priority patent/US10351638B2/en
Publication of FR3033565A1 publication Critical patent/FR3033565A1/fr
Application granted granted Critical
Publication of FR3033565B1 publication Critical patent/FR3033565B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Précatalyseur pour la polymérisation d'oléfines, de formule FeuMalc vXw(LA)y(LB)z; - Malc étant un métal alcalin et/ou un métal alcalino-terreux ; - X étant un anion ; - LA étant un acide de Lewis ; - LB étant une base de Lewis ; - u étant compris entre 0.001 et 10 ; - v étant un nombre entier ≥ 1 ; - w étant compris entre 1 et 20 ; - y étant compris entre 0 et 10 ; z étant compris entre 0 et 10.
FR1551954A 2015-03-09 2015-03-09 Precatalyseur a base de fer et son utilisation dans la polymerisation d'olefines Expired - Fee Related FR3033565B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1551954A FR3033565B1 (fr) 2015-03-09 2015-03-09 Precatalyseur a base de fer et son utilisation dans la polymerisation d'olefines
PCT/EP2016/055056 WO2016142436A1 (fr) 2015-03-09 2016-03-09 Précatalyseur à base de fer et son utilisation dans la polymérisation d'alpha-oléfines
EP16709385.5A EP3268400B1 (fr) 2015-03-09 2016-03-09 Précatalyseur à base de fer et son utilisation dans la polymérisation d'alpha-oléfines
JP2017546897A JP6824891B2 (ja) 2015-03-09 2016-03-09 鉄系プレ触媒及びα−オレフィン類の重合におけるその使用
US15/555,991 US10351638B2 (en) 2015-03-09 2016-03-09 Iron-based precatalyst and its use in the polymerization of α-olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1551954A FR3033565B1 (fr) 2015-03-09 2015-03-09 Precatalyseur a base de fer et son utilisation dans la polymerisation d'olefines

Publications (2)

Publication Number Publication Date
FR3033565A1 FR3033565A1 (fr) 2016-09-16
FR3033565B1 true FR3033565B1 (fr) 2017-03-24

Family

ID=53059296

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1551954A Expired - Fee Related FR3033565B1 (fr) 2015-03-09 2015-03-09 Precatalyseur a base de fer et son utilisation dans la polymerisation d'olefines

Country Status (5)

Country Link
US (1) US10351638B2 (fr)
EP (1) EP3268400B1 (fr)
JP (1) JP6824891B2 (fr)
FR (1) FR3033565B1 (fr)
WO (1) WO2016142436A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3055628A1 (fr) * 2016-09-07 2018-03-09 Centre National De La Recherche Scientifique Pre-catalyseur a base de cobalt ou de nickel et son utilisation dans la polymerisation d'olefines

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5146387A (en) * 1974-10-18 1976-04-20 Yozo Kondo Horiorefuinno seizohoho
IL51283A (en) * 1976-01-30 1979-11-30 Snam Progetti Process for preparing a co-catalyst for use in the polymerization of a-olefins,a co-catalyst prepared by the process,a catalytic system comprising such a co-catalyst and a process for polymerizing an a-olefin using such catalytic system
FR2728181B1 (fr) * 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
US6180734B1 (en) * 1998-10-14 2001-01-30 Bridgestone Corporation Process for producing syndiotactic 1,2-polybutadiene and iron-based catalyst compositions for use therein
JP2001247609A (ja) * 1999-12-27 2001-09-11 Sumitomo Chem Co Ltd 付加重合用触媒および付加重合体の製造方法
CN1282671C (zh) * 2003-08-08 2006-11-01 中国石油化工股份有限公司 一种镁化合物负载后过渡金属催化剂组分及其制法和应用
JP4996779B2 (ja) * 2006-02-22 2012-08-08 日本ポリプロ株式会社 オレフィン重合用触媒成分、及び当触媒成分の製造法、並びに当触媒成分を用いた重合触媒によるオレフィン重合体の製造方法
CN102336850B (zh) * 2011-07-07 2013-07-17 中山大学 一种催化乙烯链穿梭聚合的催化剂及其应用
US9815918B2 (en) * 2012-03-19 2017-11-14 Formosa Plastics Corporation, U.S.A. Catalyst component for high activity and high stereoselectivity in olefin polymerization

Also Published As

Publication number Publication date
JP6824891B2 (ja) 2021-02-03
FR3033565A1 (fr) 2016-09-16
EP3268400B1 (fr) 2019-05-15
EP3268400A1 (fr) 2018-01-17
US20180037678A1 (en) 2018-02-08
JP2018507941A (ja) 2018-03-22
US10351638B2 (en) 2019-07-16
WO2016142436A1 (fr) 2016-09-15

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