FR3044006B1 - Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique - Google Patents

Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique Download PDF

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Publication number
FR3044006B1
FR3044006B1 FR1561142A FR1561142A FR3044006B1 FR 3044006 B1 FR3044006 B1 FR 3044006B1 FR 1561142 A FR1561142 A FR 1561142A FR 1561142 A FR1561142 A FR 1561142A FR 3044006 B1 FR3044006 B1 FR 3044006B1
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organic material
unsaturated
saturated
hydrocarbon group
group
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FR3044006A1 (fr
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Hamid Mokhtari
Pascal Nardoux
Philippe Morel
Yvon PREVOST
Christophe ROYE
Laure Dehuyser
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Orano Mining SA
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Areva Mines SA
Orano Mining SA
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Priority to FR1561142A priority Critical patent/FR3044006B1/fr
Priority to US15/776,889 priority patent/US20180333697A1/en
Priority to PCT/EP2016/078293 priority patent/WO2017085312A1/fr
Priority to MA42558A priority patent/MA42558B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3251—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3259—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulfur with at least one silicon atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0265—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries extraction by solid resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Nanotechnology (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Biochemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

L'invention se rapporte à un matériau organique qui comprend un support solide polymérique sur lequel sont greffées des molécules répondant à la formule générale (I) ci-après : dans laquelle : - m = 0, 1 ou 2 ; - R1 et R2 = un groupe hydrocarboné, saturé ou insaturé, linéaire ou ramifié, en C6 à C12 ; - R3 = H ; un groupe hydrocarboné, saturé ou insaturé, linéaire ou ramifié, en C1 à C12 ; un groupe hydrocarboné, saturé ou insaturé, comprenant un ou plusieurs cycles en C3 à C8 ; ou un groupe aryle comprenant un ou plusieurs cycles ; - ou bien R2 et R3 forment ensemble un groupe -(CH2)n- avec n = de 1 à 4 ; - R4 = un groupe hydrocarboné, saturé ou insaturé, linéaire ou ramifié, en C2 à C8 ; un groupe hydrocarboné, saturé ou insaturé, comprenant un ou plusieurs cycles ; ou un groupe aromatique comprenant un ou plusieurs cycles ; et - R5 = un groupe hydrocarboné, saturé ou insaturé, linéaire ou ramifié, en C3 à C12 ; un groupe hydrocarboné, saturé ou insaturé, comprenant un ou plusieurs cycles ; ou un groupe hydrocarboné comprenant un groupe aryle formé d'un ou de plusieurs cycles, R5 étant relié à au moins un groupe G, lui-même relié au support solide polymérique par au moins une liaison covalente (matérialisée par le trait en pointillé) et choisi parmi un groupe amide, alcényle, alcynyle, amine, thioéther, éther-oxyde et 1,2,3- triazole. L'invention se rapporte aussi à l'utilisation du matériau organique pour extraire l'uranium(VI) d'une solution aqueuse d'acide, à des procédés d'extraction et de récupération de l'uranium(VI) associés ainsi qu'à une molécule, précurseur du matériau organique.
FR1561142A 2015-11-19 2015-11-19 Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique Active FR3044006B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR1561142A FR3044006B1 (fr) 2015-11-19 2015-11-19 Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique
US15/776,889 US20180333697A1 (en) 2015-11-19 2016-11-21 Novel organic material for extracting the uranium from an aqueous solution of phosphoric acid, associated methods for extracting and retrieving the uranium and a precursor of such an organic material
PCT/EP2016/078293 WO2017085312A1 (fr) 2015-11-19 2016-11-21 Nouveau matériau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procédés d'extraction et de récupération de l'uranium associés et précurseur d'un tel matériau organique
MA42558A MA42558B1 (fr) 2015-11-19 2016-11-21 Nouveau matériau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procédés d'extraction et de récupération de l'uranium associés et précurseur d'un tel matériau organique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1561142A FR3044006B1 (fr) 2015-11-19 2015-11-19 Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique
FR1561142 2015-11-19

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FR3044006A1 FR3044006A1 (fr) 2017-05-26
FR3044006B1 true FR3044006B1 (fr) 2020-03-06

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FR1561142A Active FR3044006B1 (fr) 2015-11-19 2015-11-19 Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique

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US (1) US20180333697A1 (fr)
FR (1) FR3044006B1 (fr)
MA (1) MA42558B1 (fr)
WO (1) WO2017085312A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3060006B1 (fr) * 2016-12-13 2020-02-28 Orano Mining Materiau organique mesoporeux, utile notamment pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, et ses utilisations
WO2019068962A1 (fr) * 2017-10-02 2019-04-11 Universite Paris-Sud Nouveaux polymères greffes, leurs procédés de préparation, et leurs utilisations notamment pour le captage de métaux
DE102018102919C5 (de) 2018-02-09 2026-04-09 Provisur Technologies, Inc. Fördereinrichtung zur Förderung von Lebensmittelprodukten und zugehöriges Betriebsverfahren
CN114478851B (zh) * 2022-01-26 2022-09-09 核工业北京化工冶金研究院 交联聚苯乙烯树脂及其制备方法和用途

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4402917A (en) 1980-09-05 1983-09-06 Allied Chemical Corporation Extraction of uranium from phosphoric acid using supported extractants
IL69384A0 (en) 1983-08-01 1983-11-30 Israel Atomic Energy Comm Recovery of uranium from wet process phosphoric acid by liquid-solid ion exchange
FR2990206B1 (fr) * 2012-05-07 2014-06-06 Commissariat Energie Atomique Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations
FR3002463B1 (fr) * 2013-02-25 2016-08-19 Commissariat Energie Atomique Materiau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux contenant de l'acide phosphorique, ses procedes de preparation et ses utilisations

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US20180333697A1 (en) 2018-11-22
WO2017085312A1 (fr) 2017-05-26
FR3044006A1 (fr) 2017-05-26
MA42558B1 (fr) 2019-10-31

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