FR3051683B1 - Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes - Google Patents

Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes Download PDF

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Publication number
FR3051683B1
FR3051683B1 FR1654932A FR1654932A FR3051683B1 FR 3051683 B1 FR3051683 B1 FR 3051683B1 FR 1654932 A FR1654932 A FR 1654932A FR 1654932 A FR1654932 A FR 1654932A FR 3051683 B1 FR3051683 B1 FR 3051683B1
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FR
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Prior art keywords
octens
chrome
phosphine
processing
catalytic composition
Prior art date
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Expired - Fee Related
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FR1654932A
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English (en)
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FR3051683A1 (fr
Inventor
Pierre-Alain Breuil
David Proriol
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1654932A priority Critical patent/FR3051683B1/fr
Priority to PCT/EP2017/061884 priority patent/WO2017207280A1/fr
Priority to EP17723148.7A priority patent/EP3463653A1/fr
Priority to US16/306,037 priority patent/US10646858B2/en
Priority to CN201780033929.6A priority patent/CN109195703B/zh
Publication of FR3051683A1 publication Critical patent/FR3051683A1/fr
Application granted granted Critical
Publication of FR3051683B1 publication Critical patent/FR3051683B1/fr
Expired - Fee Related legal-status Critical Current
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention porte sur une composition comprenant au moins un précurseur de chrome, au moins un ligand hétéroatomique et optionnellement, au moins un activateur. L'invention porte également sur le procédé de préparation de la composition selon l'invention et l'utilisation de ladite composition dans un procédé d'oligomérisation d'oléfines.
FR1654932A 2016-05-31 2016-05-31 Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes Expired - Fee Related FR3051683B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1654932A FR3051683B1 (fr) 2016-05-31 2016-05-31 Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes
PCT/EP2017/061884 WO2017207280A1 (fr) 2016-05-31 2017-05-17 Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes
EP17723148.7A EP3463653A1 (fr) 2016-05-31 2017-05-17 Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes
US16/306,037 US10646858B2 (en) 2016-05-31 2017-05-17 Catalytic composition based on chromium and a ligand based on phosphine and its use in a method for producing octenes
CN201780033929.6A CN109195703B (zh) 2016-05-31 2017-05-17 基于铬和基于膦的配体的催化组合物及其在生产辛烯的方法中的用途

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1654932A FR3051683B1 (fr) 2016-05-31 2016-05-31 Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes

Publications (2)

Publication Number Publication Date
FR3051683A1 FR3051683A1 (fr) 2017-12-01
FR3051683B1 true FR3051683B1 (fr) 2020-10-09

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FR1654932A Expired - Fee Related FR3051683B1 (fr) 2016-05-31 2016-05-31 Composition catalytique a base de chrome et d'un ligand a base de phosphine et son utilisation dans un procede de procuction d'octenes

Country Status (5)

Country Link
US (1) US10646858B2 (fr)
EP (1) EP3463653A1 (fr)
CN (1) CN109195703B (fr)
FR (1) FR3051683B1 (fr)
WO (1) WO2017207280A1 (fr)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10303931B4 (de) 2002-02-04 2013-04-18 Institut Français du Pétrole Katalytische Zusammensetzung zur Dimerisierung, Co-Dimerisierung, Oligomerisierung und Polymerisation der Olefine
JP2006516265A (ja) * 2002-12-20 2006-06-29 サソル テクノロジー （ピーティーワイ） リミテッド オレフィンの三量体化
FR2895406B1 (fr) 2005-12-22 2010-08-13 Inst Francais Du Petrole Procede pour la fabrication de 2,3-dimethylbut-1-ene
CN100443178C (zh) * 2006-03-10 2008-12-17 中国石油天然气股份有限公司 一种乙烯低聚的催化剂组合物及其应用
KR101074202B1 (ko) * 2007-01-18 2011-10-14 에스케이종합화학 주식회사 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법
CN103044181A (zh) * 2011-10-17 2013-04-17 中国石油天然气股份有限公司 一种乙烯四聚反应制备辛烯-1的方法
CN104245640B (zh) 2012-05-09 2017-10-27 沙索技术有限公司 乙烯的四聚
US9487456B2 (en) * 2012-05-09 2016-11-08 Sasol Technology (Proprietary) Limited Tetramerisation of ethylene
CN104511311B (zh) * 2013-09-30 2017-07-07 华东理工大学 一种高选择性的乙烯三聚、四聚催化剂体系及其使用方法

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Publication number Publication date
WO2017207280A1 (fr) 2017-12-07
US10646858B2 (en) 2020-05-12
US20190168202A1 (en) 2019-06-06
FR3051683A1 (fr) 2017-12-01
CN109195703A (zh) 2019-01-11
EP3463653A1 (fr) 2019-04-10
CN109195703B (zh) 2022-06-24

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