FR3078533B1 - Procede de fabrication d'un materiau ceramique pour le stockage thermique d'energie - Google Patents

Procede de fabrication d'un materiau ceramique pour le stockage thermique d'energie Download PDF

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Publication number
FR3078533B1
FR3078533B1 FR1851786A FR1851786A FR3078533B1 FR 3078533 B1 FR3078533 B1 FR 3078533B1 FR 1851786 A FR1851786 A FR 1851786A FR 1851786 A FR1851786 A FR 1851786A FR 3078533 B1 FR3078533 B1 FR 3078533B1
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FR
France
Prior art keywords
ceramic material
thermal energy
manufacturing
energy storage
transfer fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1851786A
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English (en)
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FR3078533A1 (fr
Inventor
Rachid Boulif
Driss Dhiba
Nawal Semlal
Alain Germeau
Claudia Toussaint
Ange Nzihou
Minh Doan Pham
Abdoul Razac Sane
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Prayon SA
Association pour la Recherche et le Developpement des Methodes et Processus Industriels
OCP SA
Original Assignee
Prayon SA
Association pour la Recherche et le Developpement des Methodes et Processus Industriels
OCP SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1851786A priority Critical patent/FR3078533B1/fr
Application filed by Prayon SA, Association pour la Recherche et le Developpement des Methodes et Processus Industriels, OCP SA filed Critical Prayon SA
Priority to BR112020017789-0A priority patent/BR112020017789A2/pt
Priority to PCT/FR2019/050459 priority patent/WO2019166741A1/fr
Priority to US16/976,649 priority patent/US20200407616A1/en
Priority to RU2020132263A priority patent/RU2787164C2/ru
Priority to IL277010A priority patent/IL277010B2/en
Priority to MA052425A priority patent/MA52425A/fr
Priority to CN201980016610.1A priority patent/CN112105590A/zh
Priority to EP19717516.9A priority patent/EP3759060A1/fr
Publication of FR3078533A1 publication Critical patent/FR3078533A1/fr
Priority to SA520420078A priority patent/SA520420078B1/ar
Application granted granted Critical
Publication of FR3078533B1 publication Critical patent/FR3078533B1/fr
Priority to US18/955,532 priority patent/US20250084296A1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08—Materials not undergoing a change of physical state when used
    • C09K5/14—Solid materials, e.g. powdery or granular
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/447—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on phosphates, e.g. hydroxyapatite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00—Producing shaped prefabricated articles from the material
    • B28B1/008—Producing shaped prefabricated articles from the material made from two or more materials having different characteristics or properties
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/28—Slip casting
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/30—Drying methods
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/32—Burning methods
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/20—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein the material is extruded
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C04B2235/3212—Calcium phosphates, e.g. hydroxyapatite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6021—Extrusion moulding
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/72—Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/94—Products characterised by their shape
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14—Thermal energy storage

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

L'invention concerne un procédé de fabrication d'un matériau céramique pour le stockage thermique d'énergie, caractérisé en ce qu'il comprend la réalisation d'un mélange d'au moins des particules d'argile et des particules de phosphate, et d'eau. L'invention concerne également un matériau céramique pour le stockage d'énergie thermique, caractérisé en ce qu'il comprend une matrice d'argile et, le cas échéant, de sable, et des particules de phosphate dispersées dans ladite matrice. Un autre objet de l'invention est un procédé de stockage d'énergie thermique dans ledit matériau céramique, caractérisé en ce qu'il comprend la mise en contact d'un fluide caloporteur avec ledit matériau céramique, de sorte à transférer de la chaleur du fluide caloporteur au matériau céramique dans une phase de charge, et à transférer de la chaleur du matériau céramique au fluide caloporteur dans une phase de décharge
FR1851786A 2018-03-01 2018-03-01 Procede de fabrication d'un materiau ceramique pour le stockage thermique d'energie Expired - Fee Related FR3078533B1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR1851786A FR3078533B1 (fr) 2018-03-01 2018-03-01 Procede de fabrication d'un materiau ceramique pour le stockage thermique d'energie
EP19717516.9A EP3759060A1 (fr) 2018-03-01 2019-02-28 Procédé de fabrication d'un matériau céramique pour le stockage thermique d'énergie
US16/976,649 US20200407616A1 (en) 2018-03-01 2019-02-28 Method For Producing A Ceramic Material For Thermal Energy Storage
RU2020132263A RU2787164C2 (ru) 2018-03-01 2019-02-28 Способ изготовления керамического материала для аккумулирования тепловой энергии
IL277010A IL277010B2 (en) 2018-03-01 2019-02-28 Method for manufacturing a ceramic material for thermal energy storage
MA052425A MA52425A (fr) 2018-03-01 2019-02-28 Procédé de fabrication d'un matériau céramique pour le stockage thermique d'énergie
BR112020017789-0A BR112020017789A2 (pt) 2018-03-01 2019-02-28 Método para fabricar um material cerâmico para armazenamento de energia térmica
PCT/FR2019/050459 WO2019166741A1 (fr) 2018-03-01 2019-02-28 Procédé de fabrication d'un matériau céramique pour le stockage thermique d'énergie
CN201980016610.1A CN112105590A (zh) 2018-03-01 2019-02-28 制造用于热能储存的陶瓷材料的方法
SA520420078A SA520420078B1 (ar) 2018-03-01 2020-09-01 طريقة لتصنيع مادة خزفية لتخزين الطاقة الحرارية
US18/955,532 US20250084296A1 (en) 2018-03-01 2024-11-21 Method For Storing Thermal Energy In A Ceramic Material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1851786A FR3078533B1 (fr) 2018-03-01 2018-03-01 Procede de fabrication d'un materiau ceramique pour le stockage thermique d'energie
FR1851786 2018-03-01

Publications (2)

Publication Number Publication Date
FR3078533A1 FR3078533A1 (fr) 2019-09-06
FR3078533B1 true FR3078533B1 (fr) 2023-04-21

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FR1851786A Expired - Fee Related FR3078533B1 (fr) 2018-03-01 2018-03-01 Procede de fabrication d'un materiau ceramique pour le stockage thermique d'energie

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US (2) US20200407616A1 (fr)
EP (1) EP3759060A1 (fr)
CN (1) CN112105590A (fr)
BR (1) BR112020017789A2 (fr)
FR (1) FR3078533B1 (fr)
IL (1) IL277010B2 (fr)
MA (1) MA52425A (fr)
SA (1) SA520420078B1 (fr)
WO (1) WO2019166741A1 (fr)

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Publication number Priority date Publication date Assignee Title
CN115682799B (zh) * 2021-07-21 2025-11-18 珠海采筑电子商务有限公司 节能陶瓷砖及其制作方法

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KR930010227A (ko) * 1991-11-19 1993-06-22 아더 에이. 로이젤 2세 보일러 튜브용 내화 코팅
KR100836059B1 (ko) * 2006-03-31 2008-06-09 주식회사 엘지화학 점토를 포함하는 세라믹 필터 및 그 제조 방법
KR100857510B1 (ko) * 2007-06-01 2008-09-08 한국건설기술연구원 내화성을 확보한 고강도 콘크리트용 인공 골재 및 그 제조방법
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FR3022333B1 (fr) * 2014-06-13 2020-01-03 Association Pour La Recherche Et Le Developpement De Methodes Et Processus Industriels "Armines" Materiaux a base de phosphate dans des systemes de stockage thermique d'energie
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CN106556003A (zh) * 2016-11-16 2017-04-05 广西大学 一种节能型保温锅炉
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FR3078533A1 (fr) 2019-09-06
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EP3759060A1 (fr) 2021-01-06
US20250084296A1 (en) 2025-03-13
BR112020017789A2 (pt) 2020-12-22
SA520420078B1 (ar) 2024-03-07
US20200407616A1 (en) 2020-12-31
MA52425A (fr) 2021-01-06
IL277010B1 (en) 2024-03-01
WO2019166741A1 (fr) 2019-09-06
CN112105590A (zh) 2020-12-18
IL277010A (en) 2020-10-29

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