FR3078700B1 - Procede de production du 2,3,3,3-tetrafluoropropene - Google Patents

Procede de production du 2,3,3,3-tetrafluoropropene Download PDF

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Publication number
FR3078700B1
FR3078700B1 FR1851954A FR1851954A FR3078700B1 FR 3078700 B1 FR3078700 B1 FR 3078700B1 FR 1851954 A FR1851954 A FR 1851954A FR 1851954 A FR1851954 A FR 1851954A FR 3078700 B1 FR3078700 B1 FR 3078700B1
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FR
France
Prior art keywords
stream
tetrafluoropropene
trifluoropropene
chloro
reactor
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Expired - Fee Related
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FR1851954A
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English (en)
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FR3078700A1 (fr
Inventor
Laurent Wendlinger
Dominique Deur-Bert
Anne Pigamo
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Arkema France SA
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Arkema France SA
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Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR1851954A priority Critical patent/FR3078700B1/fr
Priority to PCT/FR2019/050479 priority patent/WO2019170991A1/fr
Priority to EP19715971.8A priority patent/EP3762355A1/fr
Priority to CN201980015511.1A priority patent/CN111770908A/zh
Priority to US16/976,599 priority patent/US11084768B2/en
Publication of FR3078700A1 publication Critical patent/FR3078700A1/fr
Application granted granted Critical
Publication of FR3078700B1 publication Critical patent/FR3078700B1/fr
Expired - Fee Related legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/204—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being a halogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne un procédé pour la production de 2,3,3,3-tétrafluoropropène comprenant les étapes : i) dans un premier réacteur, mise en contact d'un courant A comprenant 2-chloro-3,3,3-trifluoropropène avec de l'acide fluorhydrique en phase gazeuse en présence d'un catalyseur pour produire un courant B comprenant 2,3,3,3-tétrafluoropropène, HF et 2-chloro-3,3,3-trifluoropropène n'ayant pas réagi ; et ii) dans un second réacteur, mise en contact en phase gazeuse en présence ou non d'un catalyseur d'acide fluorhydrique avec un courant comprenant au moins un composé chloré sélectionné parmi le groupe consistant en 1,1,1,2,3-pentachloropropane, 2,3-dichloro-1,1,1-trifluoropropane , 2,3,3,3-tétrachloropropène et 1,1,2,3-tétrachloropropène pour produire un courant C comprenant 2-chloro-3,3,3-trifluoropropène, caractérisé en ce que le courant B obtenu à l'étape i) alimente ledit second réacteur utilisé pour l'étape ii) ; et en ce que la conductivité électrique dudit courant A fourni à l'étape i) est inférieure à 15 mS/cm.
FR1851954A 2018-03-07 2018-03-07 Procede de production du 2,3,3,3-tetrafluoropropene Expired - Fee Related FR3078700B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1851954A FR3078700B1 (fr) 2018-03-07 2018-03-07 Procede de production du 2,3,3,3-tetrafluoropropene
PCT/FR2019/050479 WO2019170991A1 (fr) 2018-03-07 2019-03-04 Procédé de production du 2,3,3,3-tétrafluoropropène
EP19715971.8A EP3762355A1 (fr) 2018-03-07 2019-03-04 Procédé de production du 2,3,3,3-tétrafluoropropène
CN201980015511.1A CN111770908A (zh) 2018-03-07 2019-03-04 2,3,3,3-四氟丙烯的生产工艺
US16/976,599 US11084768B2 (en) 2018-03-07 2019-03-04 Process for the production of 2,3,3,3-tetrafluoropropene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1851954 2018-03-07
FR1851954A FR3078700B1 (fr) 2018-03-07 2018-03-07 Procede de production du 2,3,3,3-tetrafluoropropene

Publications (2)

Publication Number Publication Date
FR3078700A1 FR3078700A1 (fr) 2019-09-13
FR3078700B1 true FR3078700B1 (fr) 2020-07-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1851954A Expired - Fee Related FR3078700B1 (fr) 2018-03-07 2018-03-07 Procede de production du 2,3,3,3-tetrafluoropropene

Country Status (5)

Country Link
US (1) US11084768B2 (fr)
EP (1) EP3762355A1 (fr)
CN (1) CN111770908A (fr)
FR (1) FR3078700B1 (fr)
WO (1) WO2019170991A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3023286B1 (fr) 2014-07-02 2018-02-16 Arkema France Procede de fabrication de tetrafluoropropene
FR3078699B1 (fr) 2018-03-07 2020-02-21 Arkema France Procede de production du 2,3,3,3-tetrafluoropropene
FR3078698B1 (fr) 2018-03-07 2020-02-21 Arkema France Procede de production du 2-chloro-3,3,3-trifluoropropene
FR3081158B1 (fr) 2018-05-16 2020-07-31 Arkema France Procede de production du 1-chloro-3,3,3-trifluoropropene.
FR3083232B1 (fr) 2018-06-27 2021-11-12 Arkema France Procede de production du 1-chloro-3,3,3-trifluoropropene
FR3086287B1 (fr) 2018-09-26 2020-09-18 Arkema France Stabilisation du 1-chloro-3,3,3-trifluoropropene
CN116143583B (zh) * 2023-04-19 2023-07-07 山东澳帆新材料有限公司 一种2,3,3,3-四氟丙烯和1,3,3,3-四氟丙烯的联产制备方法
WO2026015158A2 (fr) * 2024-07-09 2026-01-15 The Chemours Company Fc, Llc Procédé d'hydrofluoration en phase vapeur non catalytique pour la fabrication de hcfo-1233xf et de hcfo-1232xf à partir de hco-1230xa

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FR3078699B1 (fr) 2018-03-07 2020-02-21 Arkema France Procede de production du 2,3,3,3-tetrafluoropropene
FR3078698B1 (fr) 2018-03-07 2020-02-21 Arkema France Procede de production du 2-chloro-3,3,3-trifluoropropene

Also Published As

Publication number Publication date
WO2019170991A1 (fr) 2019-09-12
EP3762355A1 (fr) 2021-01-13
US20210002188A1 (en) 2021-01-07
US11084768B2 (en) 2021-08-10
FR3078700A1 (fr) 2019-09-13
CN111770908A (zh) 2020-10-13

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