FR3085162B1 - Procede de preparation de sels d'imidazolium dissymetriques - Google Patents
Procede de preparation de sels d'imidazolium dissymetriques Download PDFInfo
- Publication number
- FR3085162B1 FR3085162B1 FR1857566A FR1857566A FR3085162B1 FR 3085162 B1 FR3085162 B1 FR 3085162B1 FR 1857566 A FR1857566 A FR 1857566A FR 1857566 A FR1857566 A FR 1857566A FR 3085162 B1 FR3085162 B1 FR 3085162B1
- Authority
- FR
- France
- Prior art keywords
- preparing
- dissymetric
- imidazolium salts
- formula
- cycloalkylamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000004693 imidazolium salts Chemical class 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000004982 aromatic amines Chemical class 0.000 abstract 1
- -1 dicarbonyl compound Chemical class 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
- C07D233/58—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La présente invention concerne un procédé de préparation d'un sel d'imidazolium dissymétrique de formule (1) : comprenant la mise en contact d'une arylamine de formule R1-NH2 avec un composé dicarbonylé de formule R3-CO-CO-R4, du formaldéhyde, une cycloalkylamine R2-NH2 et de l'acide tétrafluoroborique, en l'absence de solvant organique.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1857566A FR3085162B1 (fr) | 2018-08-21 | 2018-08-21 | Procede de preparation de sels d'imidazolium dissymetriques |
| PCT/FR2019/051927 WO2020039135A1 (fr) | 2018-08-21 | 2019-08-19 | Procédé de préparation de sels d'imidazolium dissymétriques |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1857566A FR3085162B1 (fr) | 2018-08-21 | 2018-08-21 | Procede de preparation de sels d'imidazolium dissymetriques |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR3085162A1 FR3085162A1 (fr) | 2020-02-28 |
| FR3085162B1 true FR3085162B1 (fr) | 2020-12-04 |
Family
ID=65201117
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR1857566A Expired - Fee Related FR3085162B1 (fr) | 2018-08-21 | 2018-08-21 | Procede de preparation de sels d'imidazolium dissymetriques |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR3085162B1 (fr) |
| WO (1) | WO2020039135A1 (fr) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077414A (en) | 1990-03-29 | 1991-12-31 | E. I. Du Pont De Nemours And Company | Preparation of 1,3-disubstituted imidazolium salts |
| US7253289B2 (en) | 2001-01-22 | 2007-08-07 | Covalent Associates, Inc. | One-step process for the preparation of halide-free hydrophobic salts |
| US7109348B1 (en) | 2002-08-30 | 2006-09-19 | University Of New Orleans Research And Technology Foundation, Inc. | Synthesis of 1,3 distributed imidazolium salts |
| JP5583024B2 (ja) | 2007-12-12 | 2014-09-03 | ビーエーエスエフ ソシエタス・ヨーロピア | ジ置換されたイミダゾリウム塩の製造方法 |
| FR2999180B1 (fr) | 2012-12-12 | 2015-04-10 | Ecole Nationale Superieure De Chimie De Rennes | Procede de preparation de sels d'imidazolium dissymetriques |
| FR2999184B1 (fr) | 2012-12-12 | 2015-01-09 | Ecole Nationale Superieure De Chimie De Rennes | Complexes de ruthenium comprenant un diaminocarbene n-heterocyclique insature dissymetrique |
-
2018
- 2018-08-21 FR FR1857566A patent/FR3085162B1/fr not_active Expired - Fee Related
-
2019
- 2019-08-19 WO PCT/FR2019/051927 patent/WO2020039135A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| FR3085162A1 (fr) | 2020-02-28 |
| WO2020039135A1 (fr) | 2020-02-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PLFP | Fee payment |
Year of fee payment: 2 |
|
| PLSC | Publication of the preliminary search report |
Effective date: 20200228 |
|
| PLFP | Fee payment |
Year of fee payment: 3 |
|
| PLFP | Fee payment |
Year of fee payment: 4 |
|
| PLFP | Fee payment |
Year of fee payment: 5 |
|
| ST | Notification of lapse |
Effective date: 20240405 |