FR3090825B3 - Méthode de contrôle en continu de la température des tubes dans un four de reformage de méthane à la vapeur - Google Patents

Méthode de contrôle en continu de la température des tubes dans un four de reformage de méthane à la vapeur Download PDF

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Publication number
FR3090825B3
FR3090825B3 FR1873593A FR1873593A FR3090825B3 FR 3090825 B3 FR3090825 B3 FR 3090825B3 FR 1873593 A FR1873593 A FR 1873593A FR 1873593 A FR1873593 A FR 1873593A FR 3090825 B3 FR3090825 B3 FR 3090825B3
Authority
FR
France
Prior art keywords
reforming
tubes
temperature
burner
furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1873593A
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English (en)
Other versions
FR3090825A3 (fr
Inventor
Daniel Gary
Diana Tudorache
Fouad Ammouri
Gonzalo Navarro
De Carvalho Leonel Couto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR1873593A priority Critical patent/FR3090825B3/fr
Publication of FR3090825A3 publication Critical patent/FR3090825A3/fr
Application granted granted Critical
Publication of FR3090825B3 publication Critical patent/FR3090825B3/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D21/00Arrangement of monitoring devices; Arrangement of safety devices
    • F27D21/0014Devices for monitoring temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00Subject matter not provided for in other groups of this subclass
    • F27D99/0001Heating elements or systems
    • F27D99/0033Heating elements or systems using burners
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816Heating by flames
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1614Controlling the temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2900/00Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
    • F23C2900/03002Combustion apparatus adapted for incorporating a fuel reforming device

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Méthode de contrôle en mode continu de la régulation de la température dans un four de reformage pour la mise en œuvre d’un procédé de reformage, le four contenant des tubes de reformage munis de catalyseur de reformage et au moins un brûleur, le procédé de reformage comprenant au moins les étapes d’alimentation des tubes de reformage munis de catalyseur de reformage avec un mélange gazeux de reformage, alimentation du au moins un brûleur en combustible et comburant, combustion du mélange combustible et comburant au sein du au moins un brûleur de sorte à fournir aux tubes de la chaleur pour le reformage, reformage du mélange gazeux d’alimentation pour produire un gaz de synthèse, la méthode utilisant un système de contrôle de distribution (DCS) dédié au dit contrôle pour assurer le réglage de l’alimentation des brûleurs ainsi que celle des tubes, et la méthode comprenant au moins les étapes de réalisation en continu de au moins une mesure de température de tube de reformage contenu dans le dit four, utilisation de la au moins une mesure de température de tube de reformage pour générer une valeur de température utilisée comme indicateur TIC pour le DCS, ajustement de l’alimentation en combustible et/ou comburant du au moins un brûleur, et/ ou ajustement de l’alimentation en mélange de gaz à reformer en réponse à la mesure de ladite température de tube. Figure de l’abrégé : Fig. 3
FR1873593A 2018-12-20 2018-12-20 Méthode de contrôle en continu de la température des tubes dans un four de reformage de méthane à la vapeur Active FR3090825B3 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR1873593A FR3090825B3 (fr) 2018-12-20 2018-12-20 Méthode de contrôle en continu de la température des tubes dans un four de reformage de méthane à la vapeur

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1873593A FR3090825B3 (fr) 2018-12-20 2018-12-20 Méthode de contrôle en continu de la température des tubes dans un four de reformage de méthane à la vapeur

Publications (2)

Publication Number Publication Date
FR3090825A3 FR3090825A3 (fr) 2020-06-26
FR3090825B3 true FR3090825B3 (fr) 2020-12-11

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FR1873593A Active FR3090825B3 (fr) 2018-12-20 2018-12-20 Méthode de contrôle en continu de la température des tubes dans un four de reformage de méthane à la vapeur

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FR (1) FR3090825B3 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12583743B2 (en) * 2022-09-23 2026-03-24 Praxair Technology, Inc. Method for carbon formation free operation of reformers

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FR3090825A3 (fr) 2020-06-26

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