FR3105235B1 - Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate - Google Patents

Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate Download PDF

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Publication number
FR3105235B1
FR3105235B1 FR1914994A FR1914994A FR3105235B1 FR 3105235 B1 FR3105235 B1 FR 3105235B1 FR 1914994 A FR1914994 A FR 1914994A FR 1914994 A FR1914994 A FR 1914994A FR 3105235 B1 FR3105235 B1 FR 3105235B1
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FR
France
Prior art keywords
polyester
depolymerizing
filler
polyethylene terephthalate
improved process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1914994A
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English (en)
Other versions
FR3105235A1 (fr
Inventor
Yacine Haroun
Adrien Mekki-Berrada
Olivier Thinon
Cyprien Charra
Le Cocq Damien Leinekugel
Gondim Paiva Mayara Azim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1914994A priority Critical patent/FR3105235B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to AU2020409450A priority patent/AU2020409450A1/en
Priority to US17/786,139 priority patent/US20230357531A1/en
Priority to BR112022011735A priority patent/BR112022011735A2/pt
Priority to EP20817009.2A priority patent/EP4077509A1/fr
Priority to MX2022006683A priority patent/MX2022006683A/es
Priority to PCT/EP2020/084850 priority patent/WO2021122095A1/fr
Priority to CA3157436A priority patent/CA3157436A1/fr
Priority to JP2022537557A priority patent/JP7857862B2/ja
Priority to KR1020227022920A priority patent/KR20220119054A/ko
Priority to CN202080087305.4A priority patent/CN114787259B/zh
Priority to TW109144393A priority patent/TWI868278B/zh
Publication of FR3105235A1 publication Critical patent/FR3105235A1/fr
Priority to ZA2022/05083A priority patent/ZA202205083B/en
Priority to SA522433068A priority patent/SA522433068B1/ar
Application granted granted Critical
Publication of FR3105235B1 publication Critical patent/FR3105235B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
    • C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/14—Monocyclic dicarboxylic acids
    • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
    • C07C63/26—1,4 - Benzenedicarboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/916—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

L’invention concerne un procédé de dépolymérisation d’une charge polyester comprenant du PET, ledit procédé comprenant, préalablement à l’étape de dépolymérisation par glycolyse et aux étape de purification de l’effluent de dépolymérisation, une étape améliorée de conditionnement de la charge dans laquelle la charge polyester est conditionnée en température et pression puis mélangée à un effluent diol dans un mélangeur statique ou dynamique afin notamment de réduire sensiblement la viscosité de la charge. Figure 1 à publier
FR1914994A 2019-12-19 2019-12-19 Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate Active FR3105235B1 (fr)

Priority Applications (14)

Application Number Priority Date Filing Date Title
FR1914994A FR3105235B1 (fr) 2019-12-19 2019-12-19 Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate
CN202080087305.4A CN114787259B (zh) 2019-12-19 2020-12-07 将包含聚对苯二甲酸乙二醇酯的聚酯解聚的改善方法
BR112022011735A BR112022011735A2 (pt) 2019-12-19 2020-12-07 Método aprimorado de despolimerização de um poliéster contendo tereftalato de polietileno
EP20817009.2A EP4077509A1 (fr) 2019-12-19 2020-12-07 Procédé amélioré de dépolymérisation d'un polyester comprenant du polyéthylène téréphtalate
MX2022006683A MX2022006683A (es) 2019-12-19 2020-12-07 Proceso mejorado de despolimerizacion de un poliester que contiene tereftalato de polietileno.
PCT/EP2020/084850 WO2021122095A1 (fr) 2019-12-19 2020-12-07 Procédé amélioré de dépolymérisation d'un polyester comprenant du polyéthylène téréphtalate
CA3157436A CA3157436A1 (fr) 2019-12-19 2020-12-07 Procede ameliore de depolymerisation d'un polyester comprenant du polyethylene terephtalate
JP2022537557A JP7857862B2 (ja) 2019-12-19 2020-12-07 ポリエチレンテレフタラートを含むポリエステルを脱重合するための改良された方法
AU2020409450A AU2020409450A1 (en) 2019-12-19 2020-12-07 Improved method for depolymerizing a polyester comprising polyethylene terephthalate
US17/786,139 US20230357531A1 (en) 2019-12-19 2020-12-07 Improved process for depolymerizing a polyester comprising polyethylene terephthalate
KR1020227022920A KR20220119054A (ko) 2019-12-19 2020-12-07 폴리에틸렌 테레프탈레이트를 포함하는 폴리에스테르의 개선된 탈중합 방법
TW109144393A TWI868278B (zh) 2019-12-19 2020-12-16 經改良之用於將含聚對苯二甲酸乙二酯之聚酯解聚合的方法
ZA2022/05083A ZA202205083B (en) 2019-12-19 2022-05-09 Improved method for depolymerizing a polyester comprising polyethylene terephthalate
SA522433068A SA522433068B1 (ar) 2019-12-19 2022-06-19 عملية مُحسَّنة لإزالة بلمرة بوليستر مشتمل على بولي إيثيلين تيريفثالات

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1914994A FR3105235B1 (fr) 2019-12-19 2019-12-19 Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate
FR1914994 2019-12-19

Publications (2)

Publication Number Publication Date
FR3105235A1 FR3105235A1 (fr) 2021-06-25
FR3105235B1 true FR3105235B1 (fr) 2022-10-07

Family

ID=69903514

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1914994A Active FR3105235B1 (fr) 2019-12-19 2019-12-19 Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate

Country Status (14)

Country Link
US (1) US20230357531A1 (fr)
EP (1) EP4077509A1 (fr)
JP (1) JP7857862B2 (fr)
KR (1) KR20220119054A (fr)
CN (1) CN114787259B (fr)
AU (1) AU2020409450A1 (fr)
BR (1) BR112022011735A2 (fr)
CA (1) CA3157436A1 (fr)
FR (1) FR3105235B1 (fr)
MX (1) MX2022006683A (fr)
SA (1) SA522433068B1 (fr)
TW (1) TWI868278B (fr)
WO (1) WO2021122095A1 (fr)
ZA (1) ZA202205083B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3124187B1 (fr) * 2021-06-17 2024-04-12 Ifp Energies Now Procédé de dépolymérisation d’une charge polyester comprenant un pre-melange etage de la charge
EP4674903A1 (fr) 2024-07-05 2026-01-07 Reju Procédé de recyclage de compositions comprenant du polyester et des fibres contenant de la cellulose

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5635584A (en) 1995-12-07 1997-06-03 Eastman Chemical Company Process including glycolysis and subsequent purification for recycling polyester materials
DE19811280C2 (de) * 1998-03-12 2002-06-27 Inventa Fischer Gmbh Verfahren und Vorrichtung zur Rückgewinnung von linearem Polyester
JP3715812B2 (ja) 1998-12-10 2005-11-16 株式会社アイエス ポリエチレンテレフタレート廃棄物のケミカルリサイクル方法
US6630601B1 (en) 1999-08-04 2003-10-07 Aies Company Limited Methods for the preparation or purification of bis-β-hydroxyethyl terephthalate
JP2003055300A (ja) * 2001-08-17 2003-02-26 Is:Kk ビス−β−ヒドロキシエチルテレフタレートの製造法
JP2004196880A (ja) * 2002-12-17 2004-07-15 Kubota Corp ポリエチレンテレフタレートの解重合方法および装置
US7192988B2 (en) 2004-09-30 2007-03-20 Invista North America S.Ar.L. Process for recycling polyester materials
US9255194B2 (en) 2013-10-15 2016-02-09 International Business Machines Corporation Methods and materials for depolymerizing polyesters
FR3053691B1 (fr) * 2016-07-05 2018-08-03 IFP Energies Nouvelles Procede de depolymerisation d'un polyester comprenant du polyethylene terephtalate opaque

Also Published As

Publication number Publication date
AU2020409450A1 (en) 2022-06-09
WO2021122095A1 (fr) 2021-06-24
TW202130726A (zh) 2021-08-16
KR20220119054A (ko) 2022-08-26
BR112022011735A2 (pt) 2022-08-30
CA3157436A1 (fr) 2021-06-24
JP2023506978A (ja) 2023-02-20
EP4077509A1 (fr) 2022-10-26
FR3105235A1 (fr) 2021-06-25
TWI868278B (zh) 2025-01-01
CN114787259A (zh) 2022-07-22
MX2022006683A (es) 2022-07-11
SA522433068B1 (ar) 2024-11-11
US20230357531A1 (en) 2023-11-09
JP7857862B2 (ja) 2026-05-13
CN114787259B (zh) 2023-12-26
ZA202205083B (en) 2024-09-25

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