FR3128706B1 - Procede d’extraction liquide-liquide de terres rares ou d’actinides via l’association d’un agent hydrotrope co-solvant a des extractants chelatants ou anioniques - Google Patents

Procede d’extraction liquide-liquide de terres rares ou d’actinides via l’association d’un agent hydrotrope co-solvant a des extractants chelatants ou anioniques

Info

Publication number
FR3128706B1
FR3128706B1 FR2111746A FR2111746A FR3128706B1 FR 3128706 B1 FR3128706 B1 FR 3128706B1 FR 2111746 A FR2111746 A FR 2111746A FR 2111746 A FR2111746 A FR 2111746A FR 3128706 B1 FR3128706 B1 FR 3128706B1
Authority
FR
France
Prior art keywords
liquid
rare earth
hydrotropic
actinides
chelating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2111746A
Other languages
English (en)
Other versions
FR3128706A1 (fr
Inventor
Thomas Zemb
Maangar Asmae El
Jean Duhamet
Stéphane Pellet-Rostaing
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Universite de Montpellier
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Commissariat a lEnergie Atomique CEA
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Universite de Montpellier
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Commissariat a lEnergie Atomique CEA, Ecole Nationale Superieure de Chimie de Montpellier ENSCM, Universite de Montpellier, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR2111746A priority Critical patent/FR3128706B1/fr
Priority to JP2024527098A priority patent/JP2024543049A/ja
Priority to EP22817527.9A priority patent/EP4426647A1/fr
Priority to PCT/EP2022/080663 priority patent/WO2023078989A1/fr
Priority to KR1020247013993A priority patent/KR20240099217A/ko
Priority to CN202280072742.8A priority patent/CN118176165A/zh
Publication of FR3128706A1 publication Critical patent/FR3128706A1/fr
Application granted granted Critical
Publication of FR3128706B1 publication Critical patent/FR3128706B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/10—Preparation or treatment, e.g. separation or purification
    • C01F17/17—Preparation or treatment, e.g. separation or purification involving a liquid-liquid extraction
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G43/00—Compounds of uranium
    • C01G43/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

L’invention concerne un procédé d’extraction liquide-liquide d’au moins un sel d’un métal choisi parmi les éléments du groupe des terres rares et du groupe des actinides à partir d’une phase aqueuse acide les contenant, ledit procédé comprenant notamment une étape de mélange d’une phase aqueuse acide comprenant ledit sel dudit métal et au moins un agent hydrotrope non ionique avec une phase organique comprenant au moins un agent hydrotrope non ionique et au moins un agent extractant. Figure pour l’abrégé : aucune
FR2111746A 2021-11-04 2021-11-04 Procede d’extraction liquide-liquide de terres rares ou d’actinides via l’association d’un agent hydrotrope co-solvant a des extractants chelatants ou anioniques Active FR3128706B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2111746A FR3128706B1 (fr) 2021-11-04 2021-11-04 Procede d’extraction liquide-liquide de terres rares ou d’actinides via l’association d’un agent hydrotrope co-solvant a des extractants chelatants ou anioniques
JP2024527098A JP2024543049A (ja) 2021-11-04 2022-11-03 共溶媒ヒドロトロープとアニオン性又はキレート性抽出剤との相乗的組み合わせによる希土類又はアクチニドの液‐液抽出法
EP22817527.9A EP4426647A1 (fr) 2021-11-04 2022-11-03 Procede d'extraction liquide-liquide de terres rares ou d'actinides via l'association synergique d'un hydrotrope co-solvant a des extractants chelatants ou anioniques
PCT/EP2022/080663 WO2023078989A1 (fr) 2021-11-04 2022-11-03 Procede d'extraction liquide-liquide de terres rares ou d'actinides via l'association synergique d'un hydrotrope co-solvant a des extractants chelatants ou anioniques
KR1020247013993A KR20240099217A (ko) 2021-11-04 2022-11-03 공용매 하이드로트로프와 음이온성 또는 킬레이트화 추출제의 상승적 결합을 통한 희토류 또는 악티나이드의 액체-액체 추출 공정
CN202280072742.8A CN118176165A (zh) 2021-11-04 2022-11-03 用于通过助溶剂水溶助剂与阴离子萃取剂或螯合萃取剂的协同组合液-液萃取稀土元素或锕系元素的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2111746A FR3128706B1 (fr) 2021-11-04 2021-11-04 Procede d’extraction liquide-liquide de terres rares ou d’actinides via l’association d’un agent hydrotrope co-solvant a des extractants chelatants ou anioniques
FR2111746 2021-11-04

Publications (2)

Publication Number Publication Date
FR3128706A1 FR3128706A1 (fr) 2023-05-05
FR3128706B1 true FR3128706B1 (fr) 2025-09-19

Family

ID=80999347

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2111746A Active FR3128706B1 (fr) 2021-11-04 2021-11-04 Procede d’extraction liquide-liquide de terres rares ou d’actinides via l’association d’un agent hydrotrope co-solvant a des extractants chelatants ou anioniques

Country Status (6)

Country Link
EP (1) EP4426647A1 (fr)
JP (1) JP2024543049A (fr)
KR (1) KR20240099217A (fr)
CN (1) CN118176165A (fr)
FR (1) FR3128706B1 (fr)
WO (1) WO2023078989A1 (fr)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2273507C1 (ru) * 2004-08-13 2006-04-10 Государственное унитарное предприятие Научно-производственное объединение "Радиевый институт им. В.Г. Хлопина" Экстракционная смесь для извлечения актинидных элементов из кислых растворов (варианты)
FR2948385B1 (fr) * 2009-07-27 2011-09-23 Commissariat Energie Atomique Procede de recuperation selective de l'americium a partir d'une phase aqueuse nitrique
FR2948384B1 (fr) * 2009-07-27 2011-09-23 Commissariat Energie Atomique Augmentation du facteur de separation entre l'americium et le curium et/ou entre des lanthanides dans une operation d'extraction liquide-liquide
FR3001961B1 (fr) * 2013-02-13 2015-03-06 Commissariat Energie Atomique Procede sol-gel pour separer des ions metalliques d'une solution aqueuse
FR3023847A1 (fr) * 2014-07-17 2016-01-22 Commissariat Energie Atomique Procede de separation du palladium des autres elements metalliques presents dans une phase aqueuse nitrique et ses utilisations

Also Published As

Publication number Publication date
WO2023078989A1 (fr) 2023-05-11
KR20240099217A (ko) 2024-06-28
FR3128706A1 (fr) 2023-05-05
JP2024543049A (ja) 2024-11-19
EP4426647A1 (fr) 2024-09-11
CN118176165A (zh) 2024-06-11

Similar Documents

Publication Publication Date Title
WO2008101396A1 (fr) Procédé de prétraitement d'un solvant d'extraction organique, produit prétraité et son utilisation
Wellens et al. A continuous ionic liquid extraction process for the separation of cobalt from nickel
El-Nadi Lanthanum and neodymium from Egyptian monazite: Synergistic extractive separation using organophosphorus reagents
Ning et al. Selective extraction and deep separation of V (V) and Cr (VI) in the leaching solution of chromium-bearing vanadium slag with primary amine LK-N21
Liu et al. Solvent extraction of Pr and Nd from chloride solutions using ternary extractant system of Cyanex 272, Alamine 336 and TBP
Sun et al. Extraction separation of rare-earth ions via competitive ligand complexations between aqueous and ionic-liquid phases
Zhang et al. A novel synergistic extraction method for recovering vanadium (V) from high-acidity chloride leaching liquor
RU2517651C1 (ru) Способ экстракционной очистки нитратных растворов, содержащих рзм
EP2929924B1 (fr) Procédé d'extraction et d'élimination des ions de métal de terres rares à partir d'une solution de placage
US8557202B1 (en) Separation method of zirconium and hafnium with acidic extractants
JP5600002B2 (ja) ウラン抽出サイクルにおける、硝酸水相（ｐｈａｓｅａｑｕｅｕｓｅｎｉｔｒｉｑｕｅ）から得られるウランからの化学元素の分離プロセス
CN101319276A (zh) 一种有机萃取剂的预萃取方法、产品及其应用
US3223476A (en) Extraction of metal values from acid solutions
FR3128706B1 (fr) Procede d’extraction liquide-liquide de terres rares ou d’actinides via l’association d’un agent hydrotrope co-solvant a des extractants chelatants ou anioniques
JP2009541763A5 (fr)
CN105568008B (zh) 预分高纯三出口萃取法
CN110791648B (zh) 一种从硫酸浸出液中萃取回收锗的方法
CN117660758A (zh) 一种协同萃取剂、从沉锂后液中强化分离铷铯制备单一铷铯盐的方法
Chagnes et al. Chemical degradation of trioctylamine and 1-tridecanol phase modifier in acidic sulfate media in the presence of vanadium (V)
MA63314B1 (fr) Traitement chimique de cendres de boues d'épuration
FR3068257B1 (fr) Carbamides pour la separation de l'uranium(vi) et du plutonium(iv) sans reduction du plutonium(iv)
CN1880489B (zh) 一种高浓度稀土溶液非皂化萃取全分离工艺
KR20130086858A (ko) 지르코늄과 하프늄 분리를 위한 용매추출 방법
CN101665870A (zh) 一种钒铬萃取分离过程中界面污物的预防方法
FR2406668A1 (fr) Procede pour extraire des metaux non ferreux de minerais grilles

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20230505

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5