FR3134576B1 - Procédé de préparation d’un sel de lithium fonctionnalisé - Google Patents

Procédé de préparation d’un sel de lithium fonctionnalisé

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Publication number
FR3134576B1
FR3134576B1 FR2203585A FR2203585A FR3134576B1 FR 3134576 B1 FR3134576 B1 FR 3134576B1 FR 2203585 A FR2203585 A FR 2203585A FR 2203585 A FR2203585 A FR 2203585A FR 3134576 B1 FR3134576 B1 FR 3134576B1
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FR
France
Prior art keywords
lithium salt
preparation
functionalized lithium
catalyst
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2203585A
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English (en)
Other versions
FR3134576A1 (fr
Inventor
Nadim Eid
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2203585A priority Critical patent/FR3134576B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to EP23725383.6A priority patent/EP4511357A1/fr
Priority to KR1020247038153A priority patent/KR20250005314A/ko
Priority to PCT/FR2023/050550 priority patent/WO2023203297A1/fr
Priority to CN202380034939.7A priority patent/CN119053583A/zh
Priority to JP2024561836A priority patent/JP2025513355A/ja
Priority to US18/857,911 priority patent/US20250282718A1/en
Publication of FR3134576A1 publication Critical patent/FR3134576A1/fr
Application granted granted Critical
Publication of FR3134576B1 publication Critical patent/FR3134576B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/48—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups having nitrogen atoms of sulfonamide groups further bound to another hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/34—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfuric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C307/00—Amides of sulfuric acids, i.e. compounds having singly-bound oxygen atoms of sulfate groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C307/02—Monoamides of sulfuric acids or esters thereof, e.g. sulfamic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/36—Amides or imides
    • C08F222/40—Imides, e.g. cyclic imides
    • C08F222/408—Imides, e.g. cyclic imides substituted imides comprising other heteroatoms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Cell Separators (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne un procédé de préparation d’un sel de lithium A comprenant l’étape a) de mise en contact d’un sel de lithium B comprenant au moins un groupement –S(O)2-F avec un composé C de formule (I) R-O-SiR1R2R3 en présence d’un catalyseur D pour former un mélange de produits comprenant ledit sel de lithium A comprenant au moins un groupement –S(O)2-OR ; ledit catalyseur D étant un composé ayant un pKa supérieur à 11 mesuré à 25°C. La présente invention concerne également un sel de lithium de formule (IIIa), (IIIb), (IIIc), (IIId), (IIIe), (IIIf), (IIIg), (IIIh), (IIIi), (IIIj), (IVa), (IVb), (IVc) ou (IVd).
FR2203585A 2022-04-19 2022-04-19 Procédé de préparation d’un sel de lithium fonctionnalisé Active FR3134576B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2203585A FR3134576B1 (fr) 2022-04-19 2022-04-19 Procédé de préparation d’un sel de lithium fonctionnalisé
KR1020247038153A KR20250005314A (ko) 2022-04-19 2023-04-18 작용성화된 리튬 염의 제조 방법
PCT/FR2023/050550 WO2023203297A1 (fr) 2022-04-19 2023-04-18 Procédé de préparation d'un sel de lithium fonctionnalisé
CN202380034939.7A CN119053583A (zh) 2022-04-19 2023-04-18 用于制备官能化锂盐的方法
EP23725383.6A EP4511357A1 (fr) 2022-04-19 2023-04-18 Procédé de préparation d'un sel de lithium fonctionnalisé
JP2024561836A JP2025513355A (ja) 2022-04-19 2023-04-18 官能化リチウム塩を調製するための方法
US18/857,911 US20250282718A1 (en) 2022-04-19 2023-04-18 Method for preparing a functionalised lithium salt

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2203585A FR3134576B1 (fr) 2022-04-19 2022-04-19 Procédé de préparation d’un sel de lithium fonctionnalisé
FR2203585 2022-04-19

Publications (2)

Publication Number Publication Date
FR3134576A1 FR3134576A1 (fr) 2023-10-20
FR3134576B1 true FR3134576B1 (fr) 2025-07-18

Family

ID=82385251

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2203585A Active FR3134576B1 (fr) 2022-04-19 2022-04-19 Procédé de préparation d’un sel de lithium fonctionnalisé

Country Status (7)

Country Link
US (1) US20250282718A1 (fr)
EP (1) EP4511357A1 (fr)
JP (1) JP2025513355A (fr)
KR (1) KR20250005314A (fr)
CN (1) CN119053583A (fr)
FR (1) FR3134576B1 (fr)
WO (1) WO2023203297A1 (fr)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3024146B1 (fr) 2014-07-23 2018-02-16 Cdp Innovation Nouveaux polymeres contenant des sels de lithium ou de sodium de bis(sulfonyl)imides greffes, leurs procedes de preparation et leurs utilisations comme electrolytes pour batteries
JP6366550B2 (ja) * 2015-08-24 2018-08-01 信越化学工業株式会社 導電性ポリマー用高分子化合物及びその製造方法
JP6651965B2 (ja) * 2016-04-14 2020-02-19 信越化学工業株式会社 単量体、高分子化合物、レジスト組成物及びパターン形成方法
FR3059993A1 (fr) 2016-12-08 2018-06-15 Arkema France Procede de sechage et de purification du sel de lithium de bis(fluorosulfonyl)imide

Also Published As

Publication number Publication date
JP2025513355A (ja) 2025-04-24
CN119053583A (zh) 2024-11-29
US20250282718A1 (en) 2025-09-11
WO2023203297A1 (fr) 2023-10-26
FR3134576A1 (fr) 2023-10-20
EP4511357A1 (fr) 2025-02-26
KR20250005314A (ko) 2025-01-09

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