FR3135983B1 - Procédé de préparation d’une composition de caoutchouc diénique. - Google Patents

Procédé de préparation d’une composition de caoutchouc diénique. Download PDF

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Publication number
FR3135983B1
FR3135983B1 FR2205203A FR2205203A FR3135983B1 FR 3135983 B1 FR3135983 B1 FR 3135983B1 FR 2205203 A FR2205203 A FR 2205203A FR 2205203 A FR2205203 A FR 2205203A FR 3135983 B1 FR3135983 B1 FR 3135983B1
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FR
France
Prior art keywords
preparing
rubber composition
productive
elastomeric matrix
diene rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2205203A
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English (en)
Other versions
FR3135983A1 (fr
Inventor
François Jean-Baptiste-Dit-Dominique
Kahina Mammeri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
Compagnie Generale des Etablissements Michelin SCA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale des Etablissements Michelin SCA filed Critical Compagnie Generale des Etablissements Michelin SCA
Priority to FR2205203A priority Critical patent/FR3135983B1/fr
Priority to PCT/EP2023/061796 priority patent/WO2023232383A1/fr
Priority to US18/870,060 priority patent/US20250346744A1/en
Priority to CN202380041958.2A priority patent/CN119278229A/zh
Priority to EP23724787.9A priority patent/EP4532589A1/fr
Publication of FR3135983A1 publication Critical patent/FR3135983A1/fr
Application granted granted Critical
Publication of FR3135983B1 publication Critical patent/FR3135983B1/fr
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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/0008Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/203Solid polymers with solid and/or liquid additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/247Heating methods
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/0008Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
    • B60C2011/0016Physical properties or dimensions
    • B60C2011/0025Modulus or tan delta
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00Characterised by the use of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2315/00Characterised by the use of rubber derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2409/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2415/00Characterised by the use of rubber derivatives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

L’invention concerne un procédé de préparation d’une composition de caoutchouc qui comprend une matrice élastomère qui comporte du caoutchouc naturel et un élastomère diénique synthétique, un agent de modification qui comprend un dipôle oxyde de nitrile et une fonction imidazole N-substituée, une charge renforçante qui comprend plus de 50% en masse d’une silice, un agent de couplage silane et un système de vulcanisation, lequel procédé comprend un malaxage préalable de la matrice élastomère seule avant de procéder aux étapes de malaxage dites non productive et productive. Le procédé permet un bon compromis entre les propriétés d’hystérèse, de rigidité et la quantité d’agent de modification.
FR2205203A 2022-05-31 2022-05-31 Procédé de préparation d’une composition de caoutchouc diénique. Active FR3135983B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR2205203A FR3135983B1 (fr) 2022-05-31 2022-05-31 Procédé de préparation d’une composition de caoutchouc diénique.
PCT/EP2023/061796 WO2023232383A1 (fr) 2022-05-31 2023-05-04 Procédé de préparation d'une composition de caoutchouc diénique
US18/870,060 US20250346744A1 (en) 2022-05-31 2023-05-04 Method for preparing a diene rubber composition
CN202380041958.2A CN119278229A (zh) 2022-05-31 2023-05-04 用于制备二烯橡胶组合物的方法
EP23724787.9A EP4532589A1 (fr) 2022-05-31 2023-05-04 Procédé de préparation d'une composition de caoutchouc diénique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2205203A FR3135983B1 (fr) 2022-05-31 2022-05-31 Procédé de préparation d’une composition de caoutchouc diénique.
FR2205203 2022-05-31

Publications (2)

Publication Number Publication Date
FR3135983A1 FR3135983A1 (fr) 2023-12-01
FR3135983B1 true FR3135983B1 (fr) 2024-05-31

Family

ID=82482774

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2205203A Active FR3135983B1 (fr) 2022-05-31 2022-05-31 Procédé de préparation d’une composition de caoutchouc diénique.

Country Status (5)

Country Link
US (1) US20250346744A1 (fr)
EP (1) EP4532589A1 (fr)
CN (1) CN119278229A (fr)
FR (1) FR3135983B1 (fr)
WO (1) WO2023232383A1 (fr)

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1679315A1 (fr) 1997-08-21 2006-07-12 General Electric Company Agents de couplage à base de mercaptosilanes bloqués, utiles dans des caoutchoucs à charge
EP1326871B1 (fr) 2000-10-13 2006-02-01 Société de Technologie Michelin Organosilane polyfonctionnel utilisable comme agent de couplage et son procede d'obtention
WO2002031041A1 (fr) 2000-10-13 2002-04-18 Societe De Technologie Michelin Composition de caoutchouc comportant a titre d'agent de couplage un organosilane polyfonctionnel
WO2003002649A1 (fr) 2001-06-28 2003-01-09 Societe De Technologie Michelin Bande de roulement pour pneumatique renforcee d'une silice a tres basse surface specifique
JP4536374B2 (ja) 2001-06-28 2010-09-01 ソシエテ ド テクノロジー ミシュラン 低い比表面積のシリカで強化されたタイヤトレッド
ES2254847T3 (es) 2001-08-06 2006-06-16 Degussa Ag Compuestos de organosilicio.
JP4515761B2 (ja) 2001-08-13 2010-08-04 ロディア・シミ シリカの製造方法、特定の細孔寸法及び/又は粒度分布を有するシリカ並びにそれらの特に重合体強化のための使用
EP1423459B1 (fr) 2001-08-13 2008-02-27 Société de Technologie Michelin Composition de caoutchouc dienique pour pneumatique comprenant une silice specifique comme charge renforcante
CA2458002C (fr) 2001-08-24 2010-08-17 Michelin Recherche Et Technique S.A. Pneu non pneumatique
US7928258B2 (en) 2004-08-20 2011-04-19 Momentive Performance Materials Inc. Cyclic diol-derived blocked mercaptofunctional silane compositions
US7510670B2 (en) 2006-02-21 2009-03-31 Momentive Performance Materials Inc. Free flowing filler composition based on organofunctional silane
FR2898077B1 (fr) 2006-03-01 2011-03-04 Peugeot Citroen Automobiles Sa Bandage non pneumatique pour une roue de vehicule, notamment une roue de vehicule automobile
FR2908410A1 (fr) 2006-11-10 2008-05-16 Rhodia Recherches & Tech Procede de preparation d'alcoxysilanes (poly)sulfures et nouveaux produits intermediaires dans ce procede
FR2940290B1 (fr) 2008-12-22 2010-12-31 Michelin Soc Tech Agent de couplage mercaptosilane bloque
FR3012458B1 (fr) 2013-10-25 2015-10-30 Michelin & Cie Composition de caoutchouc comprenant un additif compose 1,3-dipolaire portant une fonction imidazole
FR3012451B1 (fr) 2013-10-25 2016-11-11 Michelin & Cie Compose 1,3-dipolaire portant une fonction imidazole

Also Published As

Publication number Publication date
US20250346744A1 (en) 2025-11-13
CN119278229A (zh) 2025-01-07
EP4532589A1 (fr) 2025-04-09
WO2023232383A1 (fr) 2023-12-07
FR3135983A1 (fr) 2023-12-01

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