FR3149318B3 - Procédé de craquage à l'ammoniac intégré à l'électricité renouvelable pour des opex réduites et une flexibilité accrue - Google Patents

Procédé de craquage à l'ammoniac intégré à l'électricité renouvelable pour des opex réduites et une flexibilité accrue Download PDF

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Publication number
FR3149318B3
FR3149318B3 FR2400154A FR2400154A FR3149318B3 FR 3149318 B3 FR3149318 B3 FR 3149318B3 FR 2400154 A FR2400154 A FR 2400154A FR 2400154 A FR2400154 A FR 2400154A FR 3149318 B3 FR3149318 B3 FR 3149318B3
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France
Prior art keywords
ammonia cracking
cracking process
energy
increased flexibility
electricity
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FR2400154A
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English (en)
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FR3149318A3 (fr
Inventor
Swatantra Kumar Shrivastava
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Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR2400154A priority Critical patent/FR3149318B3/fr
Publication of FR3149318A3 publication Critical patent/FR3149318A3/fr
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/04Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of inorganic compounds
    • C01B3/047Decomposition of ammonia
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0266Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/085Methods of heating the process for making hydrogen or synthesis gas by electric heating
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0888Methods of cooling by evaporation of a fluid
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0888Methods of cooling by evaporation of a fluid
    • C01B2203/0894Generation of steam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288Evaporation of one or more of the different feed components
    • C01B2203/1294Evaporation by heat exchange with hot process stream

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Dans la présente invention, les mesures d'efficacité énergétique au sein du processus de craquage de l'ammoniac vont au-delà de l'obtention d'une configuration d'exportation de vapeur nulle. Un schéma de processus comprenant toutes les mesures d'efficacité énergétique associées à une meilleure intégration de la chaleur est ciblé, où l'énergie externe de l'OSBL peut être utilisée pour réduire la consommation d'ammoniac. Cette énergie externe est de préférence moins chère que le NH3 alimentation, alors seulement une réduction de H2 Le TCO est attendu. Par intermittence, les énergies renouvelables sont disponibles en abondance et à des prix très bas (inférieurs à ceux du NH3 sur une base par MJ). L'approche décrite dans la présente invention consiste à intégrer l'électricité dans le craquage de l'ammoniac sans réduction de l'efficacité globale (NH3 PCS+ Electricité pour H spécifiques2 production). Figure d’abrégé : Fig. 2
FR2400154A 2024-01-08 2024-01-08 Procédé de craquage à l'ammoniac intégré à l'électricité renouvelable pour des opex réduites et une flexibilité accrue Active FR3149318B3 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR2400154A FR3149318B3 (fr) 2024-01-08 2024-01-08 Procédé de craquage à l'ammoniac intégré à l'électricité renouvelable pour des opex réduites et une flexibilité accrue

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2400154A FR3149318B3 (fr) 2024-01-08 2024-01-08 Procédé de craquage à l'ammoniac intégré à l'électricité renouvelable pour des opex réduites et une flexibilité accrue
FR2400154 2024-01-08

Publications (2)

Publication Number Publication Date
FR3149318A3 FR3149318A3 (fr) 2024-12-06
FR3149318B3 true FR3149318B3 (fr) 2025-05-23

Family

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FR2400154A Active FR3149318B3 (fr) 2024-01-08 2024-01-08 Procédé de craquage à l'ammoniac intégré à l'électricité renouvelable pour des opex réduites et une flexibilité accrue

Country Status (1)

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FR (1) FR3149318B3 (fr)

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Publication number Publication date
FR3149318A3 (fr) 2024-12-06

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