GB1213402A - Preparation of chlorinated derivatives of ethylene - Google Patents
Preparation of chlorinated derivatives of ethyleneInfo
- Publication number
- GB1213402A GB1213402A GB797768A GB797768A GB1213402A GB 1213402 A GB1213402 A GB 1213402A GB 797768 A GB797768 A GB 797768A GB 797768 A GB797768 A GB 797768A GB 1213402 A GB1213402 A GB 1213402A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chloride
- ethylene
- produced
- reactor
- chlorinated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 title 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 abstract 4
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 3
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 229950011008 tetrachloroethylene Drugs 0.000 abstract 3
- 239000005977 Ethylene Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 abstract 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 abstract 2
- 229960003280 cupric chloride Drugs 0.000 abstract 2
- 229940045803 cuprous chloride Drugs 0.000 abstract 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 2
- 239000000155 melt Substances 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- KFUSEUYYWQURPO-UHFFFAOYSA-N 1,2-dichloroethene Chemical class ClC=CCl KFUSEUYYWQURPO-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 abstract 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- 229960003750 ethyl chloride Drugs 0.000 abstract 1
- 238000004508 fractional distillation Methods 0.000 abstract 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- -1 rare earth metal chloride Chemical class 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 235000005074 zinc chloride Nutrition 0.000 abstract 1
- 239000011592 zinc chloride Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/005—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out at high temperatures in the presence of a molten material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/00063—Temperature measurement of the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00182—Controlling or regulating processes controlling the level of reactants in the reactor vessel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,213,402. Chlorinated ethylenes. BRITISH PETROLEUM CO. Ltd. 13 Feb., 1969 [19 Feb., 1968], No. 7977/68. Heading C2C. Vinyl chloride is produced in a single-step process in which ethylene is contacted with a melt containing both cuprous and cupric chloride so that the cupric chloride is reduced to cuprous chloride which is reoxidized by treatment with hydrogen chloride and oxygen and/or chlorine, the process being carried out in a single reactor with (a) ethylene and (b) hydrogen chloride and/or oxygen being fed to two zones within the reactor. The melt optionally also contains an alkali metal chloride, zinc chloride, lead chloride, cadmium chloride, a rare earth metal chloride or a mixture thereof. Other chlorinated hydrocarbons, e.g. ethyl chloride, 1,2 - dichloroethane, 1,1,2 - trichloroethane, dichloroethylenes, trichloroethylene and perchloroethylene, may be produced as by-products and may be recycled to the reactor. In a modification of the process, perchloroethylene may be obtained by operating under conditions such that inter alia perchlorethylene and vinyl chloride are produced, separating and recovering the former by fractional distillation and recycling the latter together with other chlorinated hydrocarbon by-products.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB797768A GB1213402A (en) | 1968-02-19 | 1968-02-19 | Preparation of chlorinated derivatives of ethylene |
| DE19691907764 DE1907764A1 (en) | 1968-02-19 | 1969-02-15 | Process for the preparation of alkenyl halides |
| FR6903933A FR2002165A1 (en) | 1968-02-19 | 1969-02-17 | |
| NL6902511A NL6902511A (en) | 1968-02-19 | 1969-02-18 | |
| BE728634D BE728634A (en) | 1968-02-19 | 1969-02-19 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB797768A GB1213402A (en) | 1968-02-19 | 1968-02-19 | Preparation of chlorinated derivatives of ethylene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1213402A true GB1213402A (en) | 1970-11-25 |
Family
ID=9843404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB797768A Expired GB1213402A (en) | 1968-02-19 | 1968-02-19 | Preparation of chlorinated derivatives of ethylene |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE728634A (en) |
| DE (1) | DE1907764A1 (en) |
| FR (1) | FR2002165A1 (en) |
| GB (1) | GB1213402A (en) |
| NL (1) | NL6902511A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49117406A (en) * | 1973-03-22 | 1974-11-09 | ||
| US4092370A (en) * | 1971-09-27 | 1978-05-30 | Sumitomo Chemical Company, Limited | Process for producing tetrachloroethylene from tetrachloromethane using a molten salt catalyst |
| US4130595A (en) * | 1975-02-04 | 1978-12-19 | E. I. Du Pont De Nemours And Company | Melt oxychlorination process |
-
1968
- 1968-02-19 GB GB797768A patent/GB1213402A/en not_active Expired
-
1969
- 1969-02-15 DE DE19691907764 patent/DE1907764A1/en active Pending
- 1969-02-17 FR FR6903933A patent/FR2002165A1/fr not_active Withdrawn
- 1969-02-18 NL NL6902511A patent/NL6902511A/xx unknown
- 1969-02-19 BE BE728634D patent/BE728634A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4092370A (en) * | 1971-09-27 | 1978-05-30 | Sumitomo Chemical Company, Limited | Process for producing tetrachloroethylene from tetrachloromethane using a molten salt catalyst |
| JPS49117406A (en) * | 1973-03-22 | 1974-11-09 | ||
| US4130595A (en) * | 1975-02-04 | 1978-12-19 | E. I. Du Pont De Nemours And Company | Melt oxychlorination process |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2002165A1 (en) | 1969-10-17 |
| NL6902511A (en) | 1969-08-21 |
| DE1907764A1 (en) | 1969-09-18 |
| BE728634A (en) | 1969-08-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1464803A (en) | Process for recovery of 1,3-dichloropropene from allyl chloride still-bottoms | |
| GB1323038A (en) | Treatment of dichloroethane pyrolysis product | |
| GB1205831A (en) | Process for the recovery of the halogen content of halogenated hydrocarbons | |
| GB1454028A (en) | Production of vinyl chloride | |
| ES8505911A1 (en) | Process for the preparation of higher chloromethanes. | |
| GB1218417A (en) | Process for the simultaneous preparation of vinyl chloride, 1,1-dichloroethylene and 1,2-dichloroethylenes | |
| GB1211388A (en) | Process for producing vinyl chloride | |
| GB1230604A (en) | ||
| GB1193830A (en) | Production of Chlorocarbons | |
| GB1377084A (en) | Process for the recovery of antimony | |
| ES453061A1 (en) | Ethylene/chlorine elimination process | |
| GB1213839A (en) | Process for obtaining tetrachloroethanes | |
| CA1043359A (en) | Dehydrochlorination of 1,2-dichloroethane | |
| GB1335998A (en) | Production of chlorinated ethylene derivatives | |
| GB573532A (en) | Improvements in or relating to the splitting-off of hydrogen halide from halogenatedhydrocarbons | |
| ES427421A1 (en) | Production of trichloro-ethylene from waste C{HD 2 {B chlorinated hydrocarbons | |
| GB1266676A (en) | ||
| GB1378105A (en) | Production of propylene | |
| GB1351700A (en) | Production of chlorinated hydrocarbons | |
| GB1056522A (en) | Manufacture of chlorinated ethanes | |
| GB1437151A (en) | ||
| GB1281278A (en) | Manufacture of chlorinated hydrocarbons | |
| GB1281481A (en) | Production of trichloroethylene | |
| GB1438246A (en) | Purification of chlorinated hydrocarbons contaminated with bromo hydrocarbons | |
| DE2413148C3 (en) | Process for the production of chlorinated hydrocarbons by oxychlorination |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |