GB683084A - Manufacture of new condensation products, being more especially improved tanning agents and their application - Google Patents
Manufacture of new condensation products, being more especially improved tanning agents and their applicationInfo
- Publication number
- GB683084A GB683084A GB15236/50A GB1523650A GB683084A GB 683084 A GB683084 A GB 683084A GB 15236/50 A GB15236/50 A GB 15236/50A GB 1523650 A GB1523650 A GB 1523650A GB 683084 A GB683084 A GB 683084A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cresol
- phenol
- anisole
- condensation
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007859 condensation product Substances 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 10
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 abstract 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 9
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 8
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 5
- 229930003836 cresol Natural products 0.000 abstract 5
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 4
- 239000004202 carbamide Substances 0.000 abstract 4
- 230000005494 condensation Effects 0.000 abstract 4
- 238000009833 condensation Methods 0.000 abstract 4
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 229920002492 poly(sulfone) Polymers 0.000 abstract 3
- 150000007513 acids Chemical class 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Substances OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 abstract 1
- 229950005308 oxymethurea Drugs 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/18—Chemical tanning by organic agents using polycondensation products or precursors thereof
- C14C3/20—Chemical tanning by organic agents using polycondensation products or precursors thereof sulfonated
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Condensation products with good tanning properties are obtained by condensing in an acid medium formaldehyde, urea or thiourea and a polysulphone formed by heating under vacuum at 150-190 DEG C. a monosulphonic acid of phenol, cresol or anisole; (see Group IV (b)). Dimethylol urea or similar condensation products may be used instead of free urea, thiourea and formaldehyde. For each mol. urea or thiourea about 2 mols. formaldehyde are used and between 3 and 13, preferably between 4 and 6 mols. of phenol, cresol or anisole. The condensation is performed at from room to boiling temperature, preferably 40-80 DEG C. The products are prepared for tanning by neutralizing with alkali and acidifying with an organic acid, e.g. formic or acetic acid. Examples are given using polysulphones derived from phenol, anisole, raw cresol and o-cresol. Specifications 493,997, 504,994 and 595,211 are referred to.ALSO:Polysulphones for condensation with formaldehyde and urea or thiourea to produce tanning agents (see Group IV (a)), are made by heating monosulphonic acids of phenol, cresol or anisole under vacuum to a temperature of between 150 DEG and 190 DEG C., preferably 170 DEG C. The vacuum should be less than 20 mm., preferably 10-12 mm. pressure. Condensation occurs with elimination of water derived from the sulphonic acid groups and nuclear hydrogen atoms. Examples are given of the sulphonation of phenol, anisole, raw cresol and o-cresol, with subsequent condensation of the resulting sulphonic acids under the stated conditions. Specifications 493,997, 504,994 and 595,211 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH683084X | 1949-06-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB683084A true GB683084A (en) | 1952-11-19 |
Family
ID=4528632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15236/50A Expired GB683084A (en) | 1949-06-20 | 1950-06-19 | Manufacture of new condensation products, being more especially improved tanning agents and their application |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB683084A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3404075A (en) * | 1962-04-05 | 1968-10-01 | Geigy Chem Corp | Electrodeposition of tin |
| US4009996A (en) * | 1973-11-08 | 1977-03-01 | Ciba-Geigy Corporation | Reaction products of phenolsulphonic acid-urea-formaldehyde as tanning agents and process for their manufacture |
| FR2512074A1 (en) * | 1981-08-28 | 1983-03-04 | Sandoz Sa | PROCESS FOR SEALING ANODIZED ALUMINUM SURFACES |
| US4830632A (en) * | 1986-05-05 | 1989-05-16 | Ciba-Geigy Corporation | Aqueous composition from a sulfonated phenol, an amine and a tanning salt, process for the production thereof and use thereof as a tanning agent |
| US5360453A (en) * | 1992-01-28 | 1994-11-01 | Ciba-Geigy Corporation | Process for pickling and pretanning raw hides |
| US5427594A (en) * | 1992-01-28 | 1995-06-27 | Ciba-Geigy Corporation | Process for pickling raw hides |
-
1950
- 1950-06-19 GB GB15236/50A patent/GB683084A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3404075A (en) * | 1962-04-05 | 1968-10-01 | Geigy Chem Corp | Electrodeposition of tin |
| US4009996A (en) * | 1973-11-08 | 1977-03-01 | Ciba-Geigy Corporation | Reaction products of phenolsulphonic acid-urea-formaldehyde as tanning agents and process for their manufacture |
| FR2512074A1 (en) * | 1981-08-28 | 1983-03-04 | Sandoz Sa | PROCESS FOR SEALING ANODIZED ALUMINUM SURFACES |
| US4830632A (en) * | 1986-05-05 | 1989-05-16 | Ciba-Geigy Corporation | Aqueous composition from a sulfonated phenol, an amine and a tanning salt, process for the production thereof and use thereof as a tanning agent |
| AU604697B2 (en) * | 1986-05-05 | 1991-01-03 | Ciba Specialty Chemicals Holding Inc. | An aqueous composition from a sulfonated phenol, an amine and a tanning salt, process for the production thereof and use thereof as a tanning agent |
| US5360453A (en) * | 1992-01-28 | 1994-11-01 | Ciba-Geigy Corporation | Process for pickling and pretanning raw hides |
| US5427594A (en) * | 1992-01-28 | 1995-06-27 | Ciba-Geigy Corporation | Process for pickling raw hides |
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