GB702425A - Improvements in or relating to lubricating oil composition - Google Patents

Improvements in or relating to lubricating oil composition

Info

Publication number
GB702425A
GB702425A GB29946/51A GB2994651A GB702425A GB 702425 A GB702425 A GB 702425A GB 29946/51 A GB29946/51 A GB 29946/51A GB 2994651 A GB2994651 A GB 2994651A GB 702425 A GB702425 A GB 702425A
Authority
GB
United Kingdom
Prior art keywords
oil
calcium
alkyl
groups
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB29946/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Publication of GB702425A publication Critical patent/GB702425A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/20Natural rubber; Natural resins
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbased sulfonic acid salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088Neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089Overbased salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A lubricating oil is given anti-rusting properties by incorporating small amounts of an oil-soluble calcium petroleum sulphonate, an oil-miscible alkylphenoxypolyethoxyethanol having from 2-6 ether groups, and an alkaline-earth metal salt of an alkyl phenol sulphide. The sulphonates are salts of "mahogany" acids and may contain a stoichiometric amount of calcium or an excess thereof over the sulphonic acid. Molecular weights may be 750-1100, and the amount may be 0.4-10, preferably 0.5-5 per cent. of the final composition. The polyether alcohol contains a phenoxy radical having at least one, and preferably not more than two alkyl groups such as butyl up to dodecyl. Preferably there are 5 ether groups and one alkyl. particularly a tertiary alkyl derived from di-isobutene. The amount used is from 0.05 to about 3-4, the solubility limit, preferably from 0.2-2 per cent. of the total composition: The salts of alkyl phenol sulphides are those of Ca, Ba, Sr, Mg or mixtures of two of these. At least one mol of the metal compound may be used for each phenol radical to form the known high metal content sulphides. The benzene nucleus contains one or more alkyl groups, each of at least 4 carbon atoms. Preferably the benzene nuclei are connected by 1-4 sulphur atoms. The amount used is about 0.2-10, preferably 0.5-5 per cent. of the total composition. The weight rates of this salt to the calcium sulphonate should, preferably, be from 0.1-3.5. The lubricating oil may be a mineral oil, hydrogenated oil or white oil, synthetic oil from olefin polymerization, carbon oxides and hydrogen or hydrogenation of coal, coal tar or shale distillates, animal, vegetable or fish oils or mixtures thereof. Dyes, pour depressors, sulphurized oils, anti-oxidants, resins, rubber, voltolized oils, colloidal solids such as graphite or zinc oxide, and the like may be added. Examples compare the anti-rust effect of the three additives, calcium petroleum sulphonates, tert.-octyl phenyl ether alcohol having 5 ether groups and barium tert.-octyl phenol sulphide with that of one or two additives, and the effect of varying the ratio of this phenol sulphide salt to the calcium sulphonate. Other examples use the calcium-barium salt of tert.-octyl phenol sulphide and a polyether alcohol having 3 other groups.
GB29946/51A 1951-09-04 1951-12-21 Improvements in or relating to lubricating oil composition Expired GB702425A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US245058A US2681315A (en) 1951-09-04 1951-09-04 Lubricating oil composition

Publications (1)

Publication Number Publication Date
GB702425A true GB702425A (en) 1954-01-13

Family

ID=22925115

Family Applications (1)

Application Number Title Priority Date Filing Date
GB29946/51A Expired GB702425A (en) 1951-09-04 1951-12-21 Improvements in or relating to lubricating oil composition

Country Status (2)

Country Link
US (1) US2681315A (en)
GB (1) GB702425A (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3123570A (en) * 1964-03-03 Lubricating oil composition of improved
US3172855A (en) * 1965-03-09 Barium-calcium sulfonate complexes and lubricating compositions con- taining same
US2970960A (en) * 1953-11-27 1961-02-07 Sun Oil Co Lubricant composition containing naphthenic acid esters of polymeric polyhydric alcohols
US2739126A (en) * 1954-01-25 1956-03-20 Bray Chemical Company Corrosion preventive oils
US2893887A (en) * 1954-05-03 1959-07-07 Huber Corp J M Long flow carbon
US2833719A (en) * 1955-03-25 1958-05-06 Rohm & Haas Lubricating oil additive compositions and lubricating oil compositions
US2772238A (en) * 1955-06-24 1956-11-27 California Research Corp Foam-inhibited lubricating oils
US2873195A (en) * 1955-11-17 1959-02-10 Chesebrough Poud S Inc Rust inhibiting composition
US2833717A (en) * 1956-03-16 1958-05-06 Standard Oil Co Corrosion inhibiting lubricating oil
US3072506A (en) * 1957-04-13 1963-01-08 Houghton Chemie G M B H Quenching and cutting oil composition
US3090758A (en) * 1961-01-30 1963-05-21 Exxon Research Engineering Co Varnish removing hydraulic fluids
US3872048A (en) * 1970-09-28 1975-03-18 Us Navy Hydraulic and lubricating oil composition
US4138347A (en) * 1978-04-03 1979-02-06 Texaco Inc. Synthetic diester lubricating oils containing overbased calcium sulfonates and nonylphenol ethylene-oxide adducts
US4278555A (en) * 1978-11-15 1981-07-14 Ethyl Corporation Lubricant composition
US4479882A (en) * 1981-06-01 1984-10-30 Texaco Inc. Marine diesel cylinder oils containing polyalkoxylated phenoxy compounds for improved spreadability
US9809779B2 (en) 2012-12-27 2017-11-07 The Lubrizol Corporation Lubricating composition containing an acylated polyalkylene oxide
SG10201701993TA (en) 2013-03-12 2017-05-30 Lubrizol Corp Lubricating Composition Containing Lewis Acid Reaction Product
EP3024916B1 (en) * 2013-05-30 2019-06-26 The Lubrizol Corporation Lubricating composition containing an oxyalkylated hydrocarbyl phenol
EP2909292B1 (en) 2013-08-15 2017-10-04 The Lubrizol Corporation Method with lubricating composition containing a detergent
EP3227415B1 (en) 2014-12-03 2022-11-09 The Lubrizol Corporation Lubricating composition containing an oxyalkylated aromatic polyol compound
SG11201704171RA (en) 2014-12-03 2017-06-29 Lubrizol Corp Lubricating composition containing an oxyalkylated hydrocarbyl phenol

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2361804A (en) * 1941-02-18 1944-10-31 Union Oil Co Lubricating composition
US2366191A (en) * 1941-10-18 1945-01-02 Union Oil Co Diesel engine lubricating oil
US2398416A (en) * 1943-05-10 1946-04-16 California Research Corp Compounded oil
US2447607A (en) * 1944-12-30 1948-08-24 Standard Oil Dev Co Lubricant
GB616881A (en) * 1946-05-27 1949-01-28 Francis Hayward Ayden Improvements in or relating to lubricating compositions
US2485150A (en) * 1947-01-21 1949-10-18 Rohm & Haas Mineral oil compositions
US2485376A (en) * 1947-02-13 1949-10-18 Rohm & Haas Corrosion-resisting lubricating compositions

Also Published As

Publication number Publication date
US2681315A (en) 1954-06-15

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