GB838043A - Film-forming compositions - Google Patents
Film-forming compositionsInfo
- Publication number
- GB838043A GB838043A GB26550/58A GB2655058A GB838043A GB 838043 A GB838043 A GB 838043A GB 26550/58 A GB26550/58 A GB 26550/58A GB 2655058 A GB2655058 A GB 2655058A GB 838043 A GB838043 A GB 838043A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- pyrrolidone
- extrusion
- methyl
- hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- -1 ethylene, propylene, isobutylene Chemical group 0.000 abstract 5
- 238000001125 extrusion Methods 0.000 abstract 4
- 229920002620 polyvinyl fluoride Polymers 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 abstract 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 abstract 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 abstract 2
- HCPDKGKTCAHBCY-UHFFFAOYSA-N 1,1-difluoro-2-methylprop-1-ene Chemical group CC(C)=C(F)F HCPDKGKTCAHBCY-UHFFFAOYSA-N 0.000 abstract 1
- GGYVTHJIUNGKFZ-UHFFFAOYSA-N 1-methylpiperidin-2-one Chemical compound CN1CCCCC1=O GGYVTHJIUNGKFZ-UHFFFAOYSA-N 0.000 abstract 1
- GHELJWBGTIKZQW-UHFFFAOYSA-N 1-propan-2-ylpyrrolidin-2-one Chemical compound CC(C)N1CCCC1=O GHELJWBGTIKZQW-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- KKBHSBATGOQADJ-UHFFFAOYSA-N 2-ethenyl-1,3-dioxolane Chemical compound C=CC1OCCO1 KKBHSBATGOQADJ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- IYZVTTRRGCJXGK-UHFFFAOYSA-N 3,3-dimethylpyrrolidin-2-one Chemical compound CC1(C)CCNC1=O IYZVTTRRGCJXGK-UHFFFAOYSA-N 0.000 abstract 1
- PIJBSAHLEOMSSJ-UHFFFAOYSA-N 3-(1,2,2,2-tetrafluoroethoxy)prop-1-ene Chemical compound FC(F)(F)C(F)OCC=C PIJBSAHLEOMSSJ-UHFFFAOYSA-N 0.000 abstract 1
- QMXPTUUFGSTIKK-UHFFFAOYSA-N 5-ethylpyrrolidin-2-one Chemical compound CCC1CCC(=O)N1 QMXPTUUFGSTIKK-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 abstract 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 abstract 1
- 229960004419 dimethyl fumarate Drugs 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 239000001530 fumaric acid Substances 0.000 abstract 1
- YVIVRJLWYJGJTJ-UHFFFAOYSA-N gamma-Valerolactam Chemical compound CC1CCC(=O)N1 YVIVRJLWYJGJTJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000001192 hot extrusion Methods 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002688 maleic acid derivatives Chemical class 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- VQGWOOIHSXNRPW-UHFFFAOYSA-N n-butyl-2-methylprop-2-enamide Chemical compound CCCCNC(=O)C(C)=C VQGWOOIHSXNRPW-UHFFFAOYSA-N 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical compound C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 abstract 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 abstract 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 abstract 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 abstract 1
- 238000010791 quenching Methods 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229920002545 silicone oil Polymers 0.000 abstract 1
- 229960002317 succinimide Drugs 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000057 synthetic resin Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 229920006163 vinyl copolymer Polymers 0.000 abstract 1
- 229920001567 vinyl ester resin Polymers 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/14—Homopolymers or copolymers of vinyl fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/14—Homopolymers or copolymers of vinyl fluoride
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A film-forming synthetic resin composition comprises essentially a particulate vinyl fluoride polymer or copolymer in intimate admixture with at least one organic compound <FORM:0838043/IV (a)/1> where R is a divalent saturated C3-5 hydrocarbon radical, of which 3 or 4 carbon atoms are in the ring and Z is hydrogen or an alkyl radical containing up to 8 carbon atoms. The copolymers may be derived from a predominant amount of vinyl fluoride copolymerized with another mono-ethylenic monomer such as a hydrocarbon, e.g. ethylene, propylene, isobutylene or styrene; a halogen-substituted olefin, e.g. vinyl chloride or bromide, 1,1-dichloro- or fluoro-ethylene, di- or tri-fluorochloroethylene, tetrafluoroethylene, trifluoropropylene or difluoro-isobutylene; a vinyl ester, e.g. of formic, acetic, propionic, butyric, pivalic, benzoic, stearic or an inorganic acid; an alkenyl ether, e.g. vinyl ethyl ether, tetrafluoroethyl allyl ether or vinyl dioxolane; a vinyl ketone, e.g. methyl vinyl ketone; an N-vinyl imide, e.g. succinimide or phthalimide; acrylic or methacrylic acid or such derivatives as esters, nitriles, amides, anhydrides or acid halides thereof, e.g. methyl, beta-hydroxyethyl or allyl methacrylate, acrylonitrile or N-butyl methacrylamide; a derivative of maleic or fumaric acid, e.g. diethyl maleate or dimethyl fumarate; or a propenyl ester, e.g. allyl or isopropenyl acetate. Specified organic compounds of the above formula are: 2-pyrrolidone; N-methyl-2-pyrrolidone; N - iso-propyl - 2 - pyrrolidone; 5 - methyl - 2 - pyrrolidone; 5 - ethyl - 2 - pyrrolidone; 3,3-dimethyl-2-pyrrolidone; 2-piperidone and N-methyl-2-piperidone. Examples describe in some detail the formation of films from polyvinyl fluoride and each of the above N-compounds by a variety of techniques, viz:-extrusion into baths of first hot then cold white mineral oil and removal of oil and N-compound with acetone; dispersion on a metal belt or plate and heating in an oven or hot silicone oil or by infra-red rays followed by volatilization of the N-compound in a current of hot air; extrusion from a slotted hopper into a bath of cold water and volatilization of the N-compound in a current of hot air. The preferred concentration of polyvinyl fluoride in the composition varies with the film-forming technique to be employed, viz:25-40% (weight) for extrusion into coalescing hot oil; 10-60% for extrusion on to a plate or belt and coalescing by heat; 20-85% for hot extrusion into a cold quench bath. Specification 605,445 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US67976157A | 1957-08-22 | 1957-08-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB838043A true GB838043A (en) | 1960-06-22 |
Family
ID=22361766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB26550/58A Expired GB838043A (en) | 1957-08-22 | 1958-08-18 | Film-forming compositions |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE570578A (en) |
| DE (1) | DE1154939B (en) |
| FR (1) | FR1217664A (en) |
| GB (1) | GB838043A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3242246A (en) * | 1963-06-14 | 1966-03-22 | Sealectro Corp | Method of preparing polytetrafluoroethylene articles |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2953818A (en) | 1958-02-14 | 1960-09-27 | Du Pont | Process for producing polyvinyl fluoride film from mixture of polyvinyl fluoride particles and latent solvent therefor |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE463077A (en) * | 1943-11-19 | |||
| GB653256A (en) * | 1947-10-03 | 1951-05-09 | Ici Ltd | Improvements in and relating to the coating of porous or absorbent materials |
| FR1058152A (en) * | 1952-06-09 | 1954-03-15 | Process for the production of plastic sheets | |
| FR1121288A (en) * | 1954-03-27 | 1956-07-31 | Basf Ag | Process for the production of coatings, impregnations and shaped bodies, free of plasticizers, obtained from polyvinyl chloride |
-
1958
- 1958-08-08 FR FR772138A patent/FR1217664A/en not_active Expired
- 1958-08-18 GB GB26550/58A patent/GB838043A/en not_active Expired
- 1958-08-20 DE DEP21220A patent/DE1154939B/en active Pending
- 1958-08-22 BE BE570578A patent/BE570578A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3242246A (en) * | 1963-06-14 | 1966-03-22 | Sealectro Corp | Method of preparing polytetrafluoroethylene articles |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1217664A (en) | 1960-05-05 |
| DE1154939B (en) | 1963-09-26 |
| BE570578A (en) | 1959-09-15 |
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