GEP19970840B - A process for the preparation of propionic acid derivatives and stereochemical isomers thereof - Google Patents
A process for the preparation of propionic acid derivatives and stereochemical isomers thereofInfo
- Publication number
- GEP19970840B GEP19970840B GEAP19942324A GEAP1994002324A GEP19970840B GE P19970840 B GEP19970840 B GE P19970840B GE AP19942324 A GEAP19942324 A GE AP19942324A GE AP1994002324 A GEAP1994002324 A GE AP1994002324A GE P19970840 B GEP19970840 B GE P19970840B
- Authority
- GE
- Georgia
- Prior art keywords
- propionic acid
- preparation
- acid derivatives
- stereochemical isomers
- bromo
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 229940111131 antiinflammatory and antirheumatic product propionic acid derivative Drugs 0.000 title 1
- 150000005599 propionic acid derivatives Chemical class 0.000 title 1
- -1 bromo- Chemical class 0.000 abstract 3
- 150000003151 propanoic acid esters Chemical class 0.000 abstract 3
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Catalysts (AREA)
Abstract
A process for the preparation of the individual optical isomers of alpha - chloro- (or bromo-) propionic acid esters, which comprises reacting an (L)- lactic acid ester with thionyl chloride (or bromide) (a) in the presence of a base to give a (D)- alpha -chloro- (or bromo-) propionic acid ester or (b) in the absence of a base to give an (L)- alpha -chloro-(or bromo-) propionic acid ester. The products are useful as intermediates in the synthesis of certain herbicides.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB878721706A GB8721706D0 (en) | 1987-09-15 | 1987-09-15 | Fungicides |
| GB888801485A GB8801485D0 (en) | 1988-01-22 | 1988-01-22 | Fungicides |
| GB888806317A GB8806317D0 (en) | 1988-03-17 | 1988-03-17 | Fungicides |
| GB888814734A GB8814734D0 (en) | 1988-06-21 | 1988-06-21 | Fungicides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GEP19970840B true GEP19970840B (en) | 1997-02-11 |
Family
ID=27449984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GEAP19942324A GEP19970840B (en) | 1987-09-15 | 1994-12-29 | A process for the preparation of propionic acid derivatives and stereochemical isomers thereof |
Country Status (4)
| Country | Link |
|---|---|
| GE (1) | GEP19970840B (en) |
| LV (1) | LV10079A (en) |
| PL (1) | PL158290B1 (en) |
| RU (4) | RU2014320C1 (en) |
-
1988
- 1988-09-08 RU SU4356509 patent/RU2014320C1/en active
- 1988-09-08 PL PL27457288A patent/PL158290B1/en unknown
-
1989
- 1989-11-21 RU SU4742419 patent/RU2026282C1/en active
-
1990
- 1990-03-07 RU SU4743256 patent/RU2014321C1/en active
- 1990-03-12 RU SU904743319A patent/RU1836328C/en active
-
1992
- 1992-12-07 LV LV920262A patent/LV10079A/en unknown
-
1994
- 1994-12-29 GE GEAP19942324A patent/GEP19970840B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL274572A1 (en) | 1989-12-27 |
| LV10079A (en) | 1994-05-10 |
| RU2026282C1 (en) | 1995-01-09 |
| RU1836328C (en) | 1993-08-23 |
| RU2014320C1 (en) | 1994-06-15 |
| RU2014321C1 (en) | 1994-06-15 |
| PL158290B1 (en) | 1992-08-31 |
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