HK49697A - Naphthalenedicarboxylic acid esters - Google Patents

Naphthalenedicarboxylic acid esters Download PDF

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Publication number
HK49697A
HK49697A HK49697A HK49697A HK49697A HK 49697 A HK49697 A HK 49697A HK 49697 A HK49697 A HK 49697A HK 49697 A HK49697 A HK 49697A HK 49697 A HK49697 A HK 49697A
Authority
HK
Hong Kong
Prior art keywords
optically active
compounds
formula
alkenyl
alkyl
Prior art date
Application number
HK49697A
Other languages
German (de)
English (en)
Inventor
Dr. Kelly Stephen
Original Assignee
Rolic Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rolic Ag filed Critical Rolic Ag
Publication of HK49697A publication Critical patent/HK49697A/xx

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K19/58—Dopants or charge transfer agents
    • C09K19/586—Optically active dopants; chiral dopants
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/32—Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
    • C09K19/322—Compounds containing a naphthalene ring or a completely or partially hydrogenated naphthalene ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
    • C09K19/44—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40 containing compounds with benzene rings directly linked

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Liquid Crystal Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (8)

  1. Esters naphtalène-2,6-dicarboxyliques possédant l'activité optique, qui répondent à la formule générale dans laquelle C* représente un atome de carbone chiral et R¹ un groupe alkyle en C2-C12, alcényle en C2-C12, alcoxycarbonyle en C2-C12 ou alcényloxycarbonyle en C3-C12.
  2. Composés selon revendication 1, caractérisés en ce que R¹ représente un groupe à chaîne droite.
  3. Composés selon revendication 1 ou 2, caractérisés en ce que R¹ représente un groupe contenant au maximum 7 atomes de carbone.
  4. Mélange à cristaux liquides contenant un véhicule à cristaux liquides et un ou plusieurs composés de formule I de la revendication 1, possédant l'activité optique.
  5. Mélange à cristaux liquides selon revendication 4, caractérisé en ce que la proportion des composés de formule I possédant l'activité optique est de 0,1 à 30 % en poids.
  6. Mélange à cristaux liquides selon revendication 4 ou 5, caractérisé en ce qu'il contient un ou plusieurs composés de formule I possédant l'activité optique et un ou plusieurs composés choisis parmi ceux qui répondent aux formules générales dans lesquelles R² et R⁶ représentent chacun, indépendamment l'un de l'autre, un groupe alkyle ou alcényle ; R³ représente un groupe cyano, alkyle, alcoxy, alcényle, alcényloxy, alcoxyméthyle ou alcényloxyméthyle ; Z¹ représente une liaison covalente simple ou un groupe -CH2CH2-; n est égal à 0 ou 1 ; R⁴ représente un groupe alkyle, alcoxy, alcényle ou alcényloxy ; R⁵ représente un groupe cyano, alkyle, alcoxy, alcényle ou alcényloxy ; le cycle A est un cycle 1,4-phénylène ou trans-1,4-cyclohexylène ; et Z² représente une liaison covalente simple, -COO- ou-CH2CH2-.
  7. Procédé de préparation des esters naphtalène-2,6-dicarboxyliques de formule I de la revendication 1 possédant l'activité optique, caractérisé en ce que l'on estérifie l'acide naphtalène-2,6-dicarboxylique ou un dérivé approprié de cet acide par un composé, possédant l'activité optique et répondant à la formule générale dans laquelle C* et R¹ ont les significations indiquées dans la revendication 1.
  8. Utilisation de mélanges à cristaux liquides selon revendication 4 dans des applications optiques ou électrooptiques.
HK49697A 1990-03-27 1997-04-17 Naphthalenedicarboxylic acid esters HK49697A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH100990 1990-03-27

Publications (1)

Publication Number Publication Date
HK49697A true HK49697A (en) 1997-04-25

Family

ID=4200322

Family Applications (1)

Application Number Title Priority Date Filing Date
HK49697A HK49697A (en) 1990-03-27 1997-04-17 Naphthalenedicarboxylic acid esters

Country Status (6)

Country Link
US (1) US5230828A (fr)
EP (1) EP0449049B1 (fr)
JP (1) JP2944244B2 (fr)
KR (1) KR100192730B1 (fr)
DE (1) DE59104009D1 (fr)
HK (1) HK49697A (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59609705D1 (de) * 1995-03-03 2002-10-31 Rolic Ag Zug Photovernetzbare Naphthylderivate
KR20020079442A (ko) 2001-04-13 2002-10-19 미츠비시 가스 가가쿠 가부시키가이샤 광학 활성화합물 및 그것을 함유하는 액정조성물
JP2003012610A (ja) * 2001-06-26 2003-01-15 Mitsubishi Gas Chem Co Inc 光学活性化合物およびそれを含む液晶組成物
JP4696549B2 (ja) * 2004-10-29 2011-06-08 Ｄｉｃ株式会社 トリフルオロナフタレン誘導体
US8574454B2 (en) * 2006-12-22 2013-11-05 Rolic Ag Patternable liquid crystal polymer comprising thio-ether units
CN108717239B (zh) * 2017-11-20 2021-02-19 山东蓝贝易书信息科技有限公司 易热擦除型液晶膜写字板及制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1603075A (en) * 1977-10-24 1981-11-18 Secr Defence Liquid crystal esters containing naphthyl groups
GB8520715D0 (en) * 1985-08-19 1985-09-25 Secr Defence Secondary alcohol derivatives
DE3534778A1 (de) * 1985-09-30 1987-04-02 Hoechst Ag Chirale ester mesogener carbonsaeuren, ein verfahren zu deren herstellung und ihre verwendung als dotierstoff in fluessigkristall-phasen
WO1987005018A2 (fr) * 1986-02-17 1987-08-27 MERCK Patent Gesellschaft mit beschränkter Haftung Composes optiquement actifs
GB8610349D0 (en) * 1986-04-28 1986-06-04 Bdh Ltd 6-hydroxy-2-naphthoic acid derivatives
JPH02209990A (ja) * 1989-02-10 1990-08-21 Dainippon Ink & Chem Inc 強誘電性液晶組成物

Also Published As

Publication number Publication date
JP2944244B2 (ja) 1999-08-30
EP0449049A3 (en) 1993-01-20
EP0449049B1 (fr) 1994-12-28
KR100192730B1 (ko) 1999-06-15
EP0449049A2 (fr) 1991-10-02
JPH04221346A (ja) 1992-08-11
DE59104009D1 (de) 1995-02-09
US5230828A (en) 1993-07-27
KR910016659A (ko) 1991-11-05

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Legal Events

Date Code Title Description
PC Patent ceased (i.e. patent has lapsed due to the failure to pay the renewal fee)

Effective date: 20040315

PC Patent ceased (i.e. patent has lapsed due to the failure to pay the renewal fee)