HK7597A - A latex binder - Google Patents
A latex binderInfo
- Publication number
- HK7597A HK7597A HK7597A HK7597A HK7597A HK 7597 A HK7597 A HK 7597A HK 7597 A HK7597 A HK 7597A HK 7597 A HK7597 A HK 7597A HK 7597 A HK7597 A HK 7597A
- Authority
- HK
- Hong Kong
- Prior art keywords
- stage
- copolymer
- composition
- binder
- weight
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
- D06M13/412—N-methylolacrylamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
- D06M15/29—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing a N-methylol group or an etherified N-methylol group; containing a N-aminomethylene group; containing a N-sulfidomethylene group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/42—Acrylic resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/423—Polyamide resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/44—Fibrous material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0005—Acid electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Cell Separators (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polarising Elements (AREA)
- Nonmetallic Welding Materials (AREA)
- Organic Insulating Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Paper (AREA)
- Graft Or Block Polymers (AREA)
Claims (10)
- Composition à utiliser sur une fibre textile, la composition comprenant:(a) un polymère à deux stades, insoluble dans l'eau, comprenant un copolymère de premier stade et un copolymère de second stade, le copolymère de premier stade étant résistant aux acides, ayant une température de transition vitreuse supérieure à 80°C et étant formé d'au moins un monomère hydrophobe et d'au moins un monomère polyfonctionnel; le copolymère de second stade étant résistant aux acides, coagulable et stabilisé sur le plan ionique; le copolymère de premier stade et le copolymère de second stade étant incompatibles l'un avec l'autre;(b) un tensioactif ionique stabilisant;(c) un contre-ion pour le tensioactif stabilisant; et(d) un tensioactif non ionique.
- Composition selon la revendication 1, dans laquelle le copolymère de second stade est formé de 95-100 % dudit monomère hydrophobe et de 0-5% dudit monomère polyfonctionnel.
- Composition selon la revendication 1 ou 2, dans laquelle le tensioactif ionique stabilisant est anionique et le second copolymère comprend du méthacrylate de méthyle et du méthylolacrylamide.
- Composition selon l'une quelconque des revendications précédentes, dans laquelle le tensioactif ionique stabilisant est le laurylsulfate de sodium.
- Composition selon l'une quelconque des revendications précédentes, dans laquelle le copolymère de premier stade est formé de 95-99% dudit monomère hydrophobe et de 0,1-5% dudit monomère polyfonctionnel.
- Composition selon la revendication 4, dans laquelle le copolymère de premier stade est formé de 97-99% dudit monomère hydrophobe et de 1-3% dudit monomère polyfonctionnel.
- Composition selon la revendication 5, dans laquelle le copolymère de premier stade est formé de 95,8% dudit monomère hydrophobe et de 1,5% dudit monomère polyfonctionnel.
- Composition selon l'une quelconque des revendications précédentes, dans laquelle la masse moléculaire moyenne en poids du copolymère de premier stade est de 400 000 à 2 000 000, et la masse moléculaire moyenne en poids du copolymère de second stade est de 400 000 à 2 000 000.
- Composition selon l'une quelconque des revendications précédentes, dans laquelle le polymère à deux stades, insoluble dans l'eau, possède une granulométrie comprise entre 80 et 225 nm, de préférence entre 160 et 190 nm.
- Composition selon l'une quelconque des revendications précédentes, dans laquelle le poids du copolymère de premier stade, rapporté au poids du polymère à deux stades, insoluble dans l'eau, est de 1-85%, de préférence de 70-80%, et le poids du copolymère de second stade, rapporté au poids du polymère à deux stades, insoluble dans l'eau, est de 15-99%, de préférence de 20-30%.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/624,178 US5182179A (en) | 1990-12-07 | 1990-12-07 | Fiber binder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HK7597A true HK7597A (en) | 1997-01-24 |
Family
ID=24500991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HK7597A HK7597A (en) | 1990-12-07 | 1997-01-16 | A latex binder |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5182179A (fr) |
| EP (1) | EP0497047B1 (fr) |
| JP (1) | JPH04272274A (fr) |
| KR (1) | KR100209441B1 (fr) |
| CN (1) | CN1046376C (fr) |
| AT (1) | ATE144565T1 (fr) |
| AU (1) | AU652392B2 (fr) |
| BR (1) | BR9105285A (fr) |
| CA (1) | CA2055712A1 (fr) |
| DE (1) | DE69122848T2 (fr) |
| ES (1) | ES2093684T3 (fr) |
| FI (1) | FI915759A7 (fr) |
| HK (1) | HK7597A (fr) |
| IE (1) | IE914254A1 (fr) |
| MX (1) | MX174540B (fr) |
| NZ (1) | NZ240852A (fr) |
| ZA (1) | ZA919641B (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5212251A (en) * | 1990-09-24 | 1993-05-18 | Rohm And Haas Company | Alkali-resistant core-shell polymers |
| WO2005054365A1 (fr) * | 2003-11-26 | 2005-06-16 | E.I. Dupont De Nemours And Company | Procede d'obtention d'un agent de trempage a noyau et enveloppe et resines de polyoxymethylene de trempage |
| KR101481187B1 (ko) * | 2009-12-03 | 2015-01-09 | 현대자동차주식회사 | 연료전지용 기체확산층및 그 제조방법 |
| KR101282620B1 (ko) * | 2010-12-03 | 2013-07-12 | 기아자동차주식회사 | 냉해동 내구성이 우수한 연료전지 스택 및 그 제조방법 |
| CN103964708B (zh) * | 2014-05-04 | 2016-03-09 | 武汉理工大学 | 中高温耐酸腐蚀玻璃纤维浸润剂及其制备方法 |
| CN106079703A (zh) * | 2016-06-21 | 2016-11-09 | 如皋市光华科技创业服务有限公司 | 一种四合一强韧度新型材料 |
| CN113272395B (zh) * | 2019-03-29 | 2022-11-22 | 三井化学株式会社 | 二次电池隔膜用涂覆材料 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3745196A (en) * | 1969-05-26 | 1973-07-10 | Rohm & Haas | Low-temperature and oil-resistant core-shell acrylic polymers |
| US3676404A (en) * | 1970-06-09 | 1972-07-11 | Ici Ltd | Methyl methacrylate copolymers |
| US4110143A (en) * | 1974-10-21 | 1978-08-29 | W. R. Grace & Co. | Process for making a wettable polyolefin battery separator |
| US4181769A (en) * | 1976-06-17 | 1980-01-01 | Rohm And Haas Company | Heteropolymer acrylic latices and textiles treated therewith |
| US4107120A (en) * | 1976-06-17 | 1978-08-15 | Rohm And Haas Company | Heteropolymer acrylic latices and textiles treated therewith |
| US4351875A (en) * | 1978-09-25 | 1982-09-28 | Rohm And Haas Company | Heteropolymer acrylic latices and textiles treated therewith |
| US4277384A (en) * | 1978-09-25 | 1981-07-07 | Rohm And Haas Company | Heteropolymer acrylic latices and textiles treated therewith |
| CA1185033A (fr) * | 1980-03-10 | 1985-04-02 | Manfred Heimberg | Preparation de reseaux copolymeriques de faible viscosite et a haute teneur en solides |
| US4363856A (en) * | 1980-06-30 | 1982-12-14 | Texon Inc. | Battery separator material |
| US4529677A (en) * | 1982-02-02 | 1985-07-16 | Texon Incorporated | Battery separator material |
| DE8307549U1 (de) * | 1983-03-16 | 1984-08-23 | Grace Gmbh, 2000 Norderstedt | Separator fuer bleiakkumulatoren |
| DE3443964A1 (de) * | 1984-12-01 | 1986-06-12 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von polymer-dispersionen, die blockfeste filme bilden |
| US5004777A (en) * | 1985-08-27 | 1991-04-02 | Rohm And Haas Company | Imide polymers |
| JP2706729B2 (ja) * | 1989-01-28 | 1998-01-28 | 日本エヌエスシー株式会社 | 鉛蓄電池ガラスマツト用バインダーの製法 |
| US4975320A (en) * | 1989-02-01 | 1990-12-04 | Air Products And Chemicals, Inc. | Nonwoven products bonded with binder emulsions of copolymers of vinyl acetate/ethylene/incompatible comonomer/latent crosslinking comonomer |
-
1990
- 1990-12-07 US US07/624,178 patent/US5182179A/en not_active Expired - Fee Related
-
1991
- 1991-11-15 CA CA002055712A patent/CA2055712A1/fr not_active Abandoned
- 1991-12-03 AU AU88804/91A patent/AU652392B2/en not_active Ceased
- 1991-12-03 KR KR1019910022036A patent/KR100209441B1/ko not_active Expired - Fee Related
- 1991-12-04 EP EP91311267A patent/EP0497047B1/fr not_active Expired - Lifetime
- 1991-12-04 AT AT91311267T patent/ATE144565T1/de not_active IP Right Cessation
- 1991-12-04 ES ES91311267T patent/ES2093684T3/es not_active Expired - Lifetime
- 1991-12-04 DE DE69122848T patent/DE69122848T2/de not_active Expired - Fee Related
- 1991-12-04 NZ NZ240852A patent/NZ240852A/xx unknown
- 1991-12-05 FI FI915759A patent/FI915759A7/fi not_active Application Discontinuation
- 1991-12-05 MX MX9102399A patent/MX174540B/es not_active IP Right Cessation
- 1991-12-06 JP JP3323037A patent/JPH04272274A/ja active Pending
- 1991-12-06 BR BR919105285A patent/BR9105285A/pt not_active Application Discontinuation
- 1991-12-06 ZA ZA919641A patent/ZA919641B/xx unknown
- 1991-12-06 IE IE425491A patent/IE914254A1/en not_active Application Discontinuation
- 1991-12-07 CN CN91111461A patent/CN1046376C/zh not_active Expired - Fee Related
-
1997
- 1997-01-16 HK HK7597A patent/HK7597A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU652392B2 (en) | 1994-08-25 |
| MX174540B (es) | 1994-05-23 |
| CA2055712A1 (fr) | 1992-06-08 |
| ES2093684T3 (es) | 1997-01-01 |
| FI915759L (fi) | 1992-06-08 |
| FI915759A7 (fi) | 1992-06-08 |
| MX9102399A (es) | 1993-08-01 |
| US5182179A (en) | 1993-01-26 |
| KR100209441B1 (ko) | 1999-07-15 |
| JPH04272274A (ja) | 1992-09-29 |
| BR9105285A (pt) | 1992-08-18 |
| ATE144565T1 (de) | 1996-11-15 |
| CN1066307A (zh) | 1992-11-18 |
| EP0497047B1 (fr) | 1996-10-23 |
| AU8880491A (en) | 1992-06-11 |
| IE914254A1 (en) | 1992-06-17 |
| ZA919641B (en) | 1992-08-26 |
| EP0497047A1 (fr) | 1992-08-05 |
| CN1046376C (zh) | 1999-11-10 |
| DE69122848D1 (de) | 1996-11-28 |
| DE69122848T2 (de) | 1997-04-03 |
| FI915759A0 (fi) | 1991-12-05 |
| KR920012637A (ko) | 1992-07-27 |
| NZ240852A (en) | 1993-04-28 |
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