HRP20201190T1 - Pripravak deterdženta u obliku šumeće tablete - Google Patents

Pripravak deterdženta u obliku šumeće tablete Download PDF

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HRP20201190T1
HRP20201190T1 HRP20201190TT HRP20201190T HRP20201190T1 HR P20201190 T1 HRP20201190 T1 HR P20201190T1 HR P20201190T T HRP20201190T T HR P20201190TT HR P20201190 T HRP20201190 T HR P20201190T HR P20201190 T1 HRP20201190 T1 HR P20201190T1
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HRP20201190TT
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Jordi CAPARRÓS CASCO
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MARTÍ COMA, Lorena
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C11D3/323—Amides; Substituted amides urea or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Claims (20)

1. Pripravak deterdženta u obliku šumeće tablete naznačen time da sadrži: a) anionski surfaktant na bazi alkilsulfata koji ima ravni ili razgranati lanac C8-18 alkila u obliku natrijeve, kalijeve, amonijeve, monoetanolamonijeve, dietanolamonijeve ili trietanolamonijeve soli, b) šumeći sustav formiran organskom kiselinom topivom u vodi i anorganskom soli odabranom iz skupine koju čine alkalni karbonat, alkalni bikarbonat i njihove smjese, c) sredstvo za raspadanje koje sadrži kombinaciju škroba i natrijeve karboksimetil celuloze, i d) ureu.
2. Pripravak prema zahtjevu 1, naznačen time da je anionsko površinski aktivno sredstvo natrijeva sol alkilsulfata koji ima linearni C12-14 alkilni lanac ili linearni C12 alkilni lanac.
3. Pripravak prema zahtjevu 1 ili 2, naznačen time da je sadržaj anionske površinski aktivne tvari zastupljen između 2% i 20% težine u odnosu na ukupnu težinu komponenata a) do d).
4. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da je u vodi topiva organska kiselina bezvodna limunska kiselina.
5. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da je sadržaj u vodi topive organske kiseline zastupljen između 10% i 45% težine u odnosu na ukupnu težinu komponenata a) do d).
6. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da šumeći sustav sadrži smjesu natrijevog karbonata i natrijevog bikarbonata.
7. Pripravak prema zahtjevu 6, naznačen time daje težinski omjer natrijevog bikarbonata: natrijevog karbonata zastupljen između 20:1 i 1:20.
8. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da je sadržaj neorganske soli zastupljen između 15% i 45% težine u odnosu na ukupnu težinu komponenata od a) do d).
9. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da šumeći sustav sadrži bezvodnu limunsku kiselinu i mješavinu natrijevog karbonata i natrijevog bikarbonata.
10. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da je sadržaj sredstva za raspadanje zastupljen između 5% i 25% težine u odnosu na ukupnu težinu komponenata a) do d).
11. Pripravak prema zahtjevu 1, naznačen time da je težinski omjer škrob:natrijeva karboksimetil celuloza zastupljen između 10:1 i 1:10.
12. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da je sadržaj uree zastupljen između 5% i 25% težine u odnosu na ukupnu težinu komponenata a) do d).
13. Pripravak prema zahtjevu 1, naznačen time da sadrži natrijevu sol alkilsulfata s linearnim C12-14 alkil lancem ili linearnim C12 alkil lancem, šumeći sustav je pripremljen bezvodnom limunskom kiselinom i mješavinom natrijevog karbonata i natrijevog bikarbonata, a sredstvo za raspad je kombinacija škroba i natrijeve karboksimetil celuloze i uree.
14. Pripravak prema zahtjevu 13, naznačen time da je sadržaj anionske površinski aktivne tvari zastupljen između 4% i 10% težine u odnosu na ukupnu težinu komponenata a) do d), a sadržaj organske kiseline topive u vodi između 15% i 35% težine u odnosu na ukupnu masu sastojaka a) do d), sadržaj neorganske soli je između 25 i 35 mas.% u odnosu na ukupnu težinu sastojaka a) do d), težinski omjer natrijevog bikarbonata : natrijevog karbonata zastupljen između 3: 1 i 1: 3, sadržaj sredstava za razgradnju zastupljen između 10% i 15% težine u odnosu na ukupnu masu sastojaka a) do d), težinski omjer škrob : natrijev karboksimetil celuloza je između 3: 1 i 1: 1, a sadržaj uree između 10 i 12% težine u odnosu na ukupnu masu sastojaka a) do d).
15. Pripravak prema bilo kojem od prethodnih zahtjeva, naznačen time da sadrži najmanje jednu dodatnu komponentu odabranu iz skupine koju čine površinski aktivni tvari, građevinski materijali, alkalna sredstva, sredstva za izbjeljivanje, aktivatori izbjeljivanja, organski polimeri, sredstva protiv taloga, sredstva za uklanjanje kamenca, regulatori pjene, inhibitori prijenosa boje, sredstva za zgušnjavanje, enzimi, parfemi i njihove smjese.
16. Postupak za dobivanje sastava deterdženta u obliku šumeće tablete prema bilo kojem od patentnih zahtjeva 1 do 15, naznačen time da sadrži slijedeće korake: 1) miješanje sastojaka šumećeg sustava formiranih uz pomoć u vodi topivih organskih kiselina i anorganske soli odabrane iz skupine koju čine alkalni karbonat, alkalni bikarbonat i njihove smjese; 2) miješanje anionske površinski aktive tvari alkilsulfatnog tipa koja ima ravan ili razgranat C8-18 alkilni lanac u obliku natrija, kalija, amonijaka, monoetanolamonijeve, dietanolamonijeve ili trietanolamonijeve soli, sa ureom, 3) dodavanje smjese dobivene u koraku 2) smjesi dobivenoj u koraku 1), 4) miješanje komponenata sustava za raspadanje koji sadrži kombinaciju škroba i natrij karboksimetil celuloze, 5) dodavanju smjese dobivene u koraku 4) smjesi dobivenoj u koraku 2) i 6) prešanje praškaste smjese dobivene u koraku 5).
17. Postupak prema zahtjevu 16, naznačen time da su dodatne komponente dodane u smjesu dobivenu u koraku 5).
18. Postupak prema patentnom zahtjevu 17, naznačen time da je dodatna komponenta u tekućem obliku uključena u smjesu u krutom obliku dobivenom ranije u koraku 5) uz pomoć kombinacije precipitiranog amorfnog silicija i škroba kao nosača.
19. Upotreba pripravka deterdženta u obliku šumeće tablete prema zahtjevima 1 do 15 za naznačena time da je proizvodnju vodene otopine deterdženta.
20. Upotreba prema patentnom zahtjevu 19 za proizvodnju vodene otopine deterdženta naznačena time da je za pranje staklenog posuđa, za smanjenje tvrdoće vode, ručno i automatsko pranje posuđa, za automatsko pružanje sjaja posuđu, za uklanjanje masnoće s tvrdih površina, za čišćenje tvrdih površina, za dezinfekciju tvrdih površina, za pranje i omekšavanje odjeće i uklanjanje kamenca.
HRP20201190TT 2015-03-12 2016-03-09 Pripravak deterdženta u obliku šumeće tablete HRP20201190T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ES201530321A ES2586461B1 (es) 2015-03-12 2015-03-12 Composición detergente en forma de pastilla efervescente
PCT/ES2016/070149 WO2016142565A1 (es) 2015-03-12 2016-03-09 Composición detergente en forma de pastilla efervescente
EP16761134.2A EP3299446B1 (en) 2015-03-12 2016-03-09 Detergent composition in the form of an effervescent tablet

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US (1) US10774290B2 (hr)
EP (1) EP3299446B1 (hr)
JP (1) JP6810064B2 (hr)
KR (1) KR20170134476A (hr)
CN (1) CN107614670B (hr)
BR (1) BR112017019411A2 (hr)
CA (1) CA2978507A1 (hr)
CL (1) CL2017002285A1 (hr)
DK (1) DK3299446T3 (hr)
EA (1) EA037068B1 (hr)
ES (2) ES2586461B1 (hr)
HR (1) HRP20201190T1 (hr)
HU (1) HUE050036T2 (hr)
LT (1) LT3299446T (hr)
MA (1) MA42127B1 (hr)
MX (1) MX370794B (hr)
PL (1) PL3299446T3 (hr)
PT (1) PT3299446T (hr)
SI (1) SI3299446T1 (hr)
WO (1) WO2016142565A1 (hr)
ZA (1) ZA201706840B (hr)

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MX381933B (es) 2013-09-06 2025-03-11 Procter & Gamble Bolsitas que comprenden materiales de pared fibrosos solubles en agua y metodos para su fabricacion.
EP3118296A1 (de) * 2015-07-16 2017-01-18 Clearwhite GmbH Reinigungstablette für karaffen
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