HUE032189T2 - Fémlemez ZnAlMg bevonattal és különleges mikroszerkezettel, valamint eljárás elõállítására - Google Patents

Fémlemez ZnAlMg bevonattal és különleges mikroszerkezettel, valamint eljárás elõállítására Download PDF

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Publication number
HUE032189T2
HUE032189T2 HUE13762578A HUE13762578A HUE032189T2 HU E032189 T2 HUE032189 T2 HU E032189T2 HU E13762578 A HUE13762578 A HU E13762578A HU E13762578 A HUE13762578 A HU E13762578A HU E032189 T2 HUE032189 T2 HU E032189T2
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tais
ess ess
legalább
detail detail
production method
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HUE13762578A
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English (en)
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Christian Allely
Luc Diez
Amorim Tiago Machado
Jean-Michel Mataigne
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Arcelormittal
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C18/00—Alloys based on zinc
    • C22C18/04—Alloys based on zinc with aluminium as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/12—Aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C23C2/29—Cooling or quenching
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/40—Plates; Strips
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • C23C28/025—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only with at least one zinc-based layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12556—Organic component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12785—Group IIB metal-base component
    • Y10T428/12792—Zn-base component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12785—Group IIB metal-base component
    • Y10T428/12792—Zn-base component
    • Y10T428/12799—Next to Fe-base component [e.g., galvanized]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
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    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12951—Fe-base component
    • Y10T428/12972—Containing 0.01-1.7% carbon [i.e., steel]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
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    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12951—Fe-base component
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    • Y10T428/12979—Containing more than 10% nonferrous elements [e.g., high alloy, stainless]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12993—Surface feature [e.g., rough, mirror]

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Description

NIET Ai. SHEET WITH A 2NALMG COATING HAVING A PARTICULAR MICROSTRUCTURE. AND
CORRESPONDING PRODUCTION METHOD !H |kví( w'i\ K > * « s « u s««u* * ‘ * mosás x.'í>s:áj&amp; comprising Al mà -Mg, 1% -tcosaisKiaf of fis«rssebfi: coaling beshg Zn. and ifievthsfel« »mpwnsies ssstd ipossábly one :>r «κ«β seiseSesi from among &amp;^Sh< 5¾ Tfi CDs, Mny So, i..a, (.i. Cr, TA os 4S, she:«tms«#:fey w«ígbí sáíÍLL?si8l domes# I« the nsdai coding isslsssthsts·
Mai galvanises! ssoasissgs «undsiwsg essessfidiy of sksc md Í.U b?, ,§,4% fiy oWgfis ob glíMmmíKö as« drádfikmsdfy used fur their guod protection uptnst ewtosioo.
Those snetal cosLkgs sse non ehsehmged «««duly by coatings cosnprisisîg *b*c. «»<i nsagswsiium ansl ssium tm -"Jk^ '! u\\ ni vn'K P <κ ou5« Y- fis ««gus.
Such mttai coatsssgs «w cssheetis dy retmod so herein a*
The dsscssnscsLs, US 3,::-0:1,04:1 sissxi FF T Π9 S04 diseios.« such coatings. IN? ssddssson of magnevium mgrufirasisly s«crea*es she i.«f?:i>sis>ss íssííssLsíxx.« ispsksm red txsse *%fThese csxmsigsg which soxssbies a seduesum iss shesr Shiektsess a? sas kecscss« of she gnssrssnSec of potoetusn agalssst cosrossiuss sx^a's sime ssx consistas shicksHss. l'hast abeass as a is-uisdtxi fos «sample, Sor xss« k ike slsSssXiiSwA Heebscal apphssîîcss or esmslxucUors ÎlçliSss
llseÿesst fek Äal k:|iiSkls Midre or sábbiheh fisMshtrtg b> ««s??:· 1st tisese fields. Äetsiht^ as« pssfisfed ; ísppfisficed? eobSSiucbosyifibfiiT
Li tiw <ii.se of p:'í'4&amp;:aasfcd sheds,. Sh« «mire shoes mes»; SabricaSioss srseth<-.i ss. implcssusessed by sh« stcobstssLer, thxss< redneing she^sis, a «ul constraints a&amp;sociesed «Ith she panning psneexss sus the ut. er. J boveyee L A noted shut kso«« meut coatings snoy be prein«-. to ik-tamunsshm nrssblesas. of ihe paira layers, ieeshng b) losmbcossodoss ® ft he bboefe : Ao oMed of she I«yes5b«ss Is io posÄ« ősidőd sheeb «Los« sotyossOo s^sHtssoeeTs Imrmmû :!R · «s- psibtsd
To ösA cskJ» the mv««tl>»s firstly relates, U> a shsíot a<v'Otd«oa So ciasm I 1 Si« yhc,-:S may aäax hn.'Lab; Sb« <:ha<ss.t«>«tK s, >>f daims 2 b) 1T, taken alone or isi «onsbio.niörä. Thosm-eístksn ssLio reiataa bs atmihod aceoftinsg to«latm' 13. TL.e iVißSLob sissy also csissgxrHc iisa shäfac.ißristies of s:í&amp;ííkíí l.dandlAv^^á^^'.iariihxOOtttfhtáte' %ë iîsvcssbosï sviU Ksbv be hlsis-tj-ss«si by axiaxipies giveis L5s- í'!Í«íSíSSÍs>s'i ö!XÍy; ssskI wLL«oi:bkLasiosx; Wsh refeses-v« to sh« aecossipaixyissg figures;, wfiereiss; • figssre 1 shssx-vs <i serhemsssit: secsiossssi ysoxe ifiosSrabssg slxe «soeior« of s shed stecordiog to she in«eabou atler paisifirsgi
Figiises 2 so ï as« seheso&amp;Les ;;Î!oxvsixg the iOfesisAAsobsk oFtke ssjRses of the ssxprocessed sssessl cossfiixgs ofthex-fices ofPtgtav I, ·· Figure 5 ha ifclsimi&amp;k shOkhsst resultsof\leta»i?h&amp;i«>» Unis·s'otitMfed ® ssampk tdaíe stsistpffíTg t<> the isv> tutiosi íOS.xgiked xjSh jJivi-is xfsjc.tí äh; ssot a«x\'(thftg t.t? the xtvw'.tiosk Síid fissure ft λ s ichamaík' s.hoxsxg csere«* dsekí) :.'χγόχ «xd the ;χ>·-κ·:;χ»χ p-wuxid of οχχοχ» ßlme* 3 bee: ä <'f Ηχχχ; ι usksijss üsös Ά%. eh\t Ί. ' ."sexxl ο» vXx'o Ό <sK Ήχ í'w' s tx Ä ΟΧ. 3 \\· MíX:. II. O»« uotes thkt the selsdvs rhicMk».*.» H the ÂtÂÏsifc various layers covaritsg « Smel» :·®βψΜ0. m Fî^ïiï* 1 Τίκ; ooatmgs ? psessîxt ost the nvo tares. 5 ariimgp^ itikl ostty ο;-« oiil be déSPÓhsi! s» detail belotv · Alternatively. fsxn s:howss t, oxly ose fai.-o S has ä -rosiUns '?;;
Tbe UÖSSS.lng ? gOiiSfSlh hiss « ihx.fr:;;:>. h;';>-> thsk Of ;:'í.y;!SÍ Ui iS JifO ßtkf ä$ ifUettUCSi U'· grOtCCt tiki SatSSX'äti,' dsgaiyfeeffesleu; lié KHsiùîg ;ΐ ehmgfisee «me. shrtrèltbw aet! megessSsäk, the àhmmïtum eosttehilby weight t.x of dt« metäh odbíiitg ? isi beiwêèrs 3 $ «hifii .83¾. XMe: sksgnesbtm oteísílst^jNiag'T is hsáwsm ?..? múé.m, h %. : »hw k η >k ' xx-xtei < 1 n k^ > Sl η Π í ' tOet<o ok, Use x.xHu rdt.' M < «3 ·Ntut is grestter 'hex «,» v$*íí H HAX orw» gfs.sk·* 5.h;»s or sjual .to 9,50, G!' kW· greater ihass or íksskU Us hHá.
M ihssshstod itt 1 iguses. '2 to -t. site ei>istksg ? ha* a partis olar tetvroaructuni with s lurmiliaf ts#t 13 off s -·π. ¢. i e ϊ s >. >\ ' \sv » t (O' d ’ met a xo \ ' \ tsskhss oigBoked hg souks. FX to .: »X fsXHsi U-XM '!'t!k t'iX ;V xessxrv ?«;>-; MO '.i"0;.ti;U;>"> tt si otUSMÎ .SkóMM SOX tkíí oftlk CvXiííOg
The esUirfSméltse di'S.sxv'e of the tasodt.« ,xs:ks!>. !.i «say vaty tjuUe tartxngly :o (t> gfikna. es.|«fci»TI) oeai »o». x:h .' ( i"ihs> eo. Oi's-sp HÄ'd b> «Ioä t"*af v khGse jtveetuH.- v.tll no* he ifc^erifeeu. 'Apmt tfous ths; lartielht imUi* Ü nierijiooe-i alsovc. the nocnnkxsetofe at the auH'ate ftiki «» a'.^s-.-ectiosu. roey eesoprlsei eitetll etäksettls of ddâsdâitfeï: I3: iTtâ hiftafe eetsslie ZdMgiKm. vslsÄäre:»fli*i8ö detfiîkea'ttk: ts; she iirsprovoJ daleko»atiof$ ses.íi.tsu!oe ohiaintuü soxoniisigti) she tKvan|&amp;m<
To achieve ties·, she eecumofated sôttàce coûter«» ofdeoUrltcs H oi An sshd llosvdfe f?::if tsíííkfy:esslsíítse kc iisnsS^t so ife V eie· k» ike .'I o (he χολ -X.îx
Pfofessthiv. Ose aeuíouslsted sotfsee oonient ofd«ndï(t«s TS of Zx «ä theoator »uriWc 25 i» she t»xf stfsts is. Isíssőhssk S.Ö*··* or eve» 3.^¾ <>r eve« 2.0'»·» w even T 0%. oiki «xaa prefetebly scse. while the content of flow ws. 5 7 of hittsuy eo*«eilc Z«-MaXtk at the ««set ütrissoe 2 Î >» the eaw stafts, is lessdhäst ÎéO*4 os «vési 10.03¾ xi· evoo 1103¾ er levesilid?1 % eusidildsttl^ieem· äk f" i.'ätsk'.x οχ > w' X > iide xi >fs\". ><t hsstÄfs . teetk dss '! Mk.i ' 0' x> >trt k«<i0 cjst.kt: t>e' iv.'ktae stsi-'é \SiM>au<e> .>.χοχ„,. .j^.^sx x-x the w'k&amp;tkss.e tx -iex. xx >ttoe >0 hi.e'\ k sw-J suo >x!'g s> the («v«-otK>».
In smv evetttvlhe aeesixiklsäted stssikse i.s'.xseisi of sieskhiíes; <sf hsxasy «tsieeiic Ζ>"2ΛΙ a; the tnssef ktrhsee 2t 1rs hte s.io sake h less than 1.034 while the seexitktisted .sttrfiute eovtietit of istew of MgZx? at the osstes-siktssce 21 ist themw ^sűtaa i.Ä etui fie: sémiikéi esmfetts am^fcblysisarat
Sbbsküb, the i^pBCSive cause túl eted eantenH sî: î»$x scetioa. of daoáriits; öS hns&amp;rv esstoetia ί«?Λ; ;«s>í OÍMgXnj t.>h-.s* tsn; pstdertshly i-r-oro. 1 ' ^'s. » , ' V. V l l ' B S'i'xki i^s s> ' ., (\ax i! V X A, p „»*> da« diätes tA of An. Ûowess 17 of bss&amp;vy oatuíse fn-MgZxt;, fientiotes of hifissy eiiiaeise Zo/AS aií>í odea, of MssZif> ifcswewr, >fcpend>ttg on stse pse^et-ce of tdthitoml optional detsents tnefttksneiS below. its« mrR*trtMure:tt«fcy 4&amp;M¥ tons prise snistf unó« no; os öthat m rí ia í ; « ,o eu ,o u ui ii', the: liiü'idiss' «saisi« 13 s*f Ubísoív easocsse.
Jbe aeusnüíisteU· semee ix-ntenss IV each stotetore at«, fos cxan-spl®, tn**M»ed by fià.mg É Jpbik >1$: ttfetnOS Wl»S» « MtítM* «ί ϋ',ηΟίΛΪΟΟη >0 S Sí- „ Xs's no i,i,'B ,", SO tht> SoW st ít, χί O , osil ΛχΟ fSO^khif"·' bs»t OpítíSWihv sSi^te&amp;aed by organic xoîvoatï .»sing « scaoníag·daen-otí microscope·· 3&amp;r «ÄisfiNmft»8)»'s?.oa« exttaefe «te eaoto«s. <*f th« Énâmates^BW-.ÜI» and fen váltókká*, fos· xixaoxple, with the sollwsre Aosí.ySiS Doeu 5.0 from Oîpæg«*.ié# Ô*8Â rise Meco«.isxe> í&amp;ta x>f íhe antes unface fl «y ih< unom.«' Síi pcc-xt«·« rbtí u.eopïiox'y í.üx· *s «.«uiksiaxi η-χ the ^itmtsittted sufthcc content of ifi® shoe«.«® in «-.testies*
The pasat íitms 9 ;««! fi «re, far cssfsspk-. based on polymers. ThcsB pel y mars mm be poiyxäsieis ex-hÁgettáíed vinyl fxdysís&amp;ss Msóls ss. phsst isais. 8VDF .. .
Tbc: films 9 and f1 typically hsye thfahssessss bosomon i asddidfoss.
To snake tin- «beet I., bob can, fos m&amp;ampi«, fair« tbs Miowing steps. Ί he tnstafiatian used may comprise a single ime cy, ior «xanipte, two iifisÄr ,, ·<· ο,'* iho s xSoS ,.i 'äo p s t Jfe p,s oss g it i <. -.'·,:) sä» 0 Sóst >JífV', ", kts"s bv osotf du. <, (0<r, ht os> sh ^incsth o> Näsdtfx xíUm,?s in V í iL»v, ίο ,','\<,ί'·|\ os> b\ o&amp;\ >'í > \ >oín o \, > arj wav vonvMv.rs,>i wbete s:n.'g.-sv;si!; iitsi."; arc sím d. I« a itísi : iltssi-ía ísts-jf : *« : ife :s«®ta f m$ü of?!* :oss® -wmm 3, Âàtesà : for: essrppió %: ! hst osilissg
Siísd í|s®íi:ö5tsf rollisg, Si:i«;:fertîî:íítie S«fÄitPW$|lhi$Ä bot dipping. í'he b:s'-h h a. bath of m>'hea aim- containing nu»$nc$hun atni ahaniaium. The bath snay ai so oxiphb sip 0.3% by weighs <.>s addition;;* apsasnai dc;sn.'s9a oais as SS, bî\ lsb, l i, i. a, Ma, Sts, fss. Css, Os Niot 8i. U.Nv'sdji rsiie„n V i\ t -aw ,jkf,r!>« x,'> ,ht ii owMi'si \ ,ϋ,ηΐ'ϊ> j«> th ^dheswnof BöííliSigs ?' on pst' $<iib;,smU' f The peive-n skhlsx! in the art who Knows shdt etfve«s on the cb»«>wte»istics otieoatbg^ 7. will osoTfeem m »siiastio» ot she .sss^ht-áfter asroiiîlhasiy, the Htrth »«»>· contais» resklutii elesttents t^omtstg k«m: ;1:e si.ippjy ingots s»s' sciisitif:^ tsont Sh; sssssnsx® i1; tisc soisst-ote 3 ss: si<e hash, sxsch sa. ban ist an sinosint op to 0,5¾¾ h\ !,s. eight ássd sssnaisHy heswacn Ö.t xs-as i> 4v » fe» \xe$ghi. Ίϊ 'íi'l' X MB S, «M iis X '·, 'Í if ii 8' S P 'Bi Ϊ, A bi, 'U\ ' { ' < S'id * 0 0 At 'he s-'iSissoac <4 tha lists» tbs sabs-trate t has ii:' s!aifie'SSiO!'j tisvtperatoae '11 sue« ihas; ί >.»4 K Sai 0,6S'n iΜ» is) ;5> S0W< e>;p(-li)5s-1 Ί i,t tftei· I ; is -axpressad in degasas Kdvin, 1 lochim fcwtwisR iotnpgmîtn^ifhttllsw« tvstit ihtlá «r siffMiigtsfa :
BncMíopssscd iiithaiassiaibsí iibiiíis ? f ôsrïgÿaIiy, tbis|ssnspariiis.ayiM K ikmrissin<;;.:t ob sîk:ihn« s nteasnteroeéf Sake« « few sví«írs®:wp«fs«äiäs: fknst Mw bath b>' a py-mmeiräo tedoape &amp;t»t1 then application saht thermal model to esksdaie she tempsüratnre 'Π I > 'ΟΧ S ! J\ (.1 X \ X O -.. < («I -, < « ! i * ·..·-( < \ ï H» , i" ' Î i'< » 'f Í N Ip tt't SUK ttv > gAtOv ' 5 of the halb. ihm cooling may ke achtes od to blosting, ins-si cooling pa on the too χ mi aces 5 of the suhsöste < by mmm of cooling ehsmism. whose gat. presst«« ca« Ue regtthtsed. ff is aise possible to adptst the displacement speed iíí ibe substrate < to nw rnonne rone >e esen the tomperaiorc of the substrate 3 at the erorsmie to this :«>ae tbs example, Λ ftcr deposition «t the «o&amp;tntss b the xubdiate ' «. tor exas(ipi|:^|^l^m«»ftt#:*Bt^ias spypnga gas:: o ( cttK we ot fh< > dots ,,e - tv. ν\ίΙΚ«Ί S'. 'at tOX 'SO '0 * (it is I Vitt I V xO t hf
Alternatively, brushing may ho ssnrned out to remove the coating 7 deposited mt It diffikb I btythai bfly one of the lace;. 5 of the shoe; i «bd ttliintstek he coated wish a coaling '0
Contmtk-d coding of tits, sir of e&amp;i.h csoting ? is próbádért at a hsgkn xpced or ptoferahiy eousl to iS 't w between the xiast os'the soiidilkation (ho whin she te.ngx-.wnire. of ehe coating '7 huk pet below the wpskhss teseperattifet sad the cod of stPidiftcatksn |i e when the coding ? reaches the soildos temperáiméi hiúra ptsAoiihiy, the cooling cale oi lia:. or esdt, coaling 7 bsrweea dte et art of the solid; ho&amp;two sad the void of void· ikwmo w higher than v'i eswd so 20't'-s lie taddkis shÄd msytidi: fee cnlgsoied to dimes if to wöítósrdeo sod give it ;s ro;;gho'..'ss famhtahitgtts xtshscsparni finishing, 1 ho hand may opwsnsily bo wound hefote hdng pot to a pte-iaetpset'mg IttSfe 1 ho ««ter aurtheosc 3 I of the coatings 7 are possibly mthjec;. ts> a degress a tog step Iptîgop iredphedt step in order to inaeags the paint asiheskm soxt gpirpsioa reslstasiee.
Assy deg.te<iBis>g as-st sarfaço inssrintesu steps may tbclttde other sahoteps sodh as fsosistg, drying ,,¾ TPs paisdiiig psoovv» eoti then he performed* fs»· eaatnpb, hy äspöstmss of fsvo sascessivs Saysss of poinPg tisttieiy a ptientry layer and a fmishmg layer sshich is gttnaody the estse to schisvs: the oopser lilri· 9, or by 4«p«sitkav ot a single lay«s: of ptntit, ivlstdi s* ipínaraliy the case to aoinsva the lower him- îls.l.OtharomtmWif^ ;©î. jbyess cao be «sad tit some variants,
The depíisiooií of layers ot paint tnay be powided, foresasnpie, b> ohh;r cosners.
Pads (kpontiois >;f a L,et ol pana o ocnetalb hdhot>:d: t\y &amp; böüeg stop o· ass nvsn.
The sheet pThus obtainediôati he winsncl again hetbre hsingi sSsf; ipisssiPiy ftnishsd sod àssen-ihlod: by useiT wills otfiSi sheets I w other itetos.
fest I font- ptepKtfcs a vösnpte sheet I «««mittsg ?< the intestUon astd samples of sheets not areothing to tiw inv<mtson by varying the i t immersion retttpamttira msd the t,,- and of the samples. The tmtmspomhng jriSOtvtsfttiCfitiOS arenoslysesl ns deiemtino the existing stts;etnres atsd thdr aceunsnlateii anriace ctintews.
* Accosting?;;: the ΐ·ΐ<-®ϊΗί·:>ί·: 1¾¾¾ ' 'UC kd'iCv k k' ϋ?ω»Μ«ϊ»3ΐί'' - v'.'siSv s s..S«ipSe of dk'vt i vU.\\>>ditig tO thsT tnVWfOit ml stkXt’i i*''t vkCUf <.!<«&amp; , ) í ' ! ' η n Ku V sv «v ii ifs Κ'\ί ν' k V v.v vNvnn>v'U sii'ik' nmo
Msüî {«Cu~d\ dk' S-U'US U"'ki! !' iM w OtiOg thiCkjO.-sCS \;t F;«ii. 1'5i«:söm^!sHäb8\0iUs^mti^ 7 ol öf Ä nsd 3 5ys COOKoit 0>f .SaW ,\s UKÎÎi'iîîfc'ilîi; tí'í" &amp;m nt'täk; idtsdixtít !îl PigOiC S, ÎÎÎÎKU COiiittig vUUiP'UsiUUîiS ÎOÏÎr.d god ¢.1: ', î uC'' '* V* í V i s< V, o K·'- and I '\ «! U U, V dues V* iOk } «<\ t i) viud < 0ϋ<.
The utiermiritcuire oi'îh-e -Suret it-rcurding so the înveatkfn cousu.;.s $o!ci> oî'ternstry eutecik and s» «Stirhud ("i lOUk ".C'Î ü a <.00(«k· kfh 3t 5 ,v'S’îsC\;h, v 5 h i«V (λ kîkfun ’Su' Síi V hiwv Λ koopsi itkk r> V 'îTv'üK'îî îvvsi' ;fo -o S' V cull r ·, k : b \ 5 >A ;> ? ; * 4 ( \ ; d cjck'st Fkor ptcdi-ah. thv s;sack icsUd ara poosphisk-d, cooked udh &amp; u;>V r of Cv!':aphiïu.'ss;t virus suviîchsxâ tu ÜK' s:.i!«'asa« wish δ lrsm:%'îde hlssi«, Ílie iíSKssImus« dslgubaîlôs-s sv$#s.$t.*# gïvvu ;·ο ths'urdimna lu F ige sc r.
Uv o S\ ό; s- Uu'das'ii'-tut*" ' stusihv^k'o^'! ".d k« iä\-idk'i ! .Kki'-'Kog ίο sbe it>so'«;!0,s i'iiitifdy svtarpikânglv. d u ίοοοά diát uiakíösug; the icrsodiskd coukuts >' aStfretum«« and m;sgiKki«;n feyoîfd ths val««* of the istvenoo«. defes (orates títe tacisisiacc ίο ddsuhstadttn and Ικοκο io corrosion. ftrist*8fe .t#*saÖ> beüt-va -ihat thss good;«gsistsnea tu ®mmm; asá^^atní-is· dog is 1hg pgsiíMte .w ,. v'sä'ik k *1 <d the i JVMtkv* ~ *S'uh Situas vSii "-Sv s«'ölei tiiv',d vuupäiitg iurkveen ^«tr ddhítötü skuadiitíBS;midis« lâihbils:?· stäsluk 1¾ ΠιΚ- ä > t'k' ;,>v\ ;v..,\-cnv,c >>;' Säiii Rik - . tkk Rigiik'd ü, Jhi tvitkcS'S! ΪΤίΟίΠΧ Î ^ ν'» Sík- uU'k'f oiiftviCi Fl vd vî S^ t Üg ' hv Kl 0 sJCCv Jiss \ '1 ' UKSv ' i I vl !i ! tedik '1
So Sógora 6v sSk. corrosion patridtoi tviatSve sc- « ídetvacc calomel vkxoooio kO.urokoS io ΚΠ (Ff d-d is shosad Ost idd: ahsSJSSSä and diS Ckdröid; ii«;iSSig;öfs dte ©rdSkid«. (Sis'fdiiSiiäidS ;Sd k ííOitípöFálOít SOfkgs'iäkäg::
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US11371129B2 (en) 2017-12-28 2022-06-28 Nippon Steel Corporation Molten Zn-based plated steel sheet having superior corrosion resistance after being coated
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JP2004360056A (ja) * 2003-06-09 2004-12-24 Nisshin Steel Co Ltd 黒色化溶融Ｚｎ−Ａｌ−Ｍｇ系合金めっき鋼板及びその製造方法
RU2417273C2 (ru) * 2006-03-20 2011-04-27 Ниппон Стил Корпорейшн Стальной материал с высокой коррозионной стойкостью, получаемый с помощью горячего цинкования методом погружения
EP2119804A1 (fr) * 2008-05-14 2009-11-18 ArcelorMittal France Procédé de fabrication d'une bande métallique revêtue présentant un aspect amélioré
JP2011157579A (ja) * 2010-01-29 2011-08-18 Nisshin Steel Co Ltd 粗面化溶融Ｚｎ−Ａｌ−Ｍｇ合金めっき鋼板およびその製造方法、ならびに溶融Ｚｎ−Ａｌ−Ｍｇ合金めっき鋼板と熱可塑性樹脂成形体とが接合された複合体およびその製造方法
KR20120075235A (ko) * 2010-12-28 2012-07-06 주식회사 포스코 고내식 용융아연합금 도금강판과 그 제조방법
JP5901389B2 (ja) * 2011-03-31 2016-04-06 日新製鋼株式会社 溶融Ａｌ、Ｍｇ含有Ｚｎめっき鋼板
JP5097305B1 (ja) * 2012-04-25 2012-12-12 日新製鋼株式会社 黒色めっき鋼板

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