HUP0302341A2 - Eljárás szilícium-dioxiddal töltött elasztomer-készítmények előállítására - Google Patents

Eljárás szilícium-dioxiddal töltött elasztomer-készítmények előállítására Download PDF

Info

Publication number: HUP0302341A2
Authority: HU; Hungary
Prior art keywords: rubber; silica; para; mixture; styrene
Prior art date: 2000-06-13

Application number

HU0302341A

Other languages

English (en)

Hungarian (hu)

Inventor

Timothy A. Mills

Hsien-Chang Wang

Wai Keung Wong

Original Assignee

Exxonmobil Chemical Patents Inc.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-06-13

Filing date

2001-05-09

Publication date

2003-10-28

2000-06-13 Priority claimed from US09/592,757 external-priority patent/US6624220B1/en

2001-05-09 Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.

2003-10-28 Publication of HUP0302341A2 publication Critical patent/HUP0302341A2/hu

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 266
239000000203 mixture Substances 0.000 title claims abstract description 186
239000000377 silicon dioxide Substances 0.000 title claims abstract description 130
238000000034 method Methods 0.000 title claims description 45
229920001971 elastomer Polymers 0.000 claims abstract description 114
239000005060 rubber Substances 0.000 claims abstract description 89
229920001577 copolymer Polymers 0.000 claims abstract description 78
238000002156 mixing Methods 0.000 claims abstract description 43
239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 36
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 21
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims abstract description 16
UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims abstract description 11
238000004519 manufacturing process Methods 0.000 claims abstract description 11
VDQOXWRCEPPGRE-UHFFFAOYSA-N 1-(2-bromoethenyl)-4-methylbenzene Chemical compound CC1=CC=C(C=CBr)C=C1 VDQOXWRCEPPGRE-UHFFFAOYSA-N 0.000 claims abstract description 9
HKMVWLQFAYGKSI-UHFFFAOYSA-N 3-triethoxysilylpropyl thiocyanate Chemical compound CCO[Si](OCC)(OCC)CCCSC#N HKMVWLQFAYGKSI-UHFFFAOYSA-N 0.000 claims abstract description 7
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 7
229920001897 terpolymer Polymers 0.000 claims abstract description 6
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 36
229910000077 silane Inorganic materials 0.000 claims description 36
239000006229 carbon black Substances 0.000 claims description 30
239000005062 Polybutadiene Substances 0.000 claims description 29
229920002857 polybutadiene Polymers 0.000 claims description 29
239000007822 coupling agent Substances 0.000 claims description 28
244000043261 Hevea brasiliensis Species 0.000 claims description 23
229920003052 natural elastomer Polymers 0.000 claims description 23
229920001194 natural rubber Polymers 0.000 claims description 23
229920001195 polyisoprene Polymers 0.000 claims description 15
229920003048 styrene butadiene rubber Polymers 0.000 claims description 15
229920005549 butyl rubber Polymers 0.000 claims description 13
229920001084 poly(chloroprene) Polymers 0.000 claims description 13
230000008569 process Effects 0.000 claims description 12
VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 claims description 10
229920005683 SIBR Polymers 0.000 claims description 9
150000001282 organosilanes Chemical group 0.000 claims description 9
ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 8
229920000459 Nitrile rubber Polymers 0.000 claims description 8
229920003049 isoprene rubber Polymers 0.000 claims description 8
HHZDRADWWVVISO-UHFFFAOYSA-N 2-methyl-3-(3-trimethoxysilylpropyl)thiirane-2-carboxylic acid Chemical compound CO[Si](OC)(OC)CCCC1SC1(C)C(O)=O HHZDRADWWVVISO-UHFFFAOYSA-N 0.000 claims description 6
239000003963 antioxidant agent Substances 0.000 claims description 6
OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 claims description 4
VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 claims description 4
WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 3
ZARCFEHBDQIZSJ-UHFFFAOYSA-N 1-triethoxysilylpropane-2-thiol Chemical compound CCO[Si](CC(C)S)(OCC)OCC ZARCFEHBDQIZSJ-UHFFFAOYSA-N 0.000 claims description 3
JSYFUEKVXFEXSX-UHFFFAOYSA-N 2-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CC(C)Cl JSYFUEKVXFEXSX-UHFFFAOYSA-N 0.000 claims description 3
PGPAJJPJQNBBDR-UHFFFAOYSA-N 2-methyl-4-trimethoxysilylhex-1-en-3-one Chemical compound CC(=C)C(=O)C(CC)[Si](OC)(OC)OC PGPAJJPJQNBBDR-UHFFFAOYSA-N 0.000 claims description 3
FSPIGXNLDXWYKZ-UHFFFAOYSA-N CCO[Si](CCC[S+]=C(N(C)C)SSSSC(N(C)C)=[S+]CCC[Si](OCC)(OCC)OCC)(OCC)OCC Chemical compound CCO[Si](CCC[S+]=C(N(C)C)SSSSC(N(C)C)=[S+]CCC[Si](OCC)(OCC)OCC)(OCC)OCC FSPIGXNLDXWYKZ-UHFFFAOYSA-N 0.000 claims description 3
SKFGZHGVWONCTD-UHFFFAOYSA-N CN(C)C(SSSSC(N(C)C)=[S+]CCC[Si](OC)(OC)OC)=[S+]CCC[Si](OC)(OC)OC Chemical compound CN(C)C(SSSSC(N(C)C)=[S+]CCC[Si](OC)(OC)OC)=[S+]CCC[Si](OC)(OC)OC SKFGZHGVWONCTD-UHFFFAOYSA-N 0.000 claims description 3
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 claims description 3
FPBXRRDHCADTAL-UHFFFAOYSA-N triethoxy(3-nitropropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC[N+]([O-])=O FPBXRRDHCADTAL-UHFFFAOYSA-N 0.000 claims description 3
ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 claims description 3
QPPXVBLDIDEHBA-UHFFFAOYSA-N trimethoxy(3-nitropropyl)silane Chemical compound CO[Si](OC)(OC)CCC[N+]([O-])=O QPPXVBLDIDEHBA-UHFFFAOYSA-N 0.000 claims description 3
JSXKIRYGYMKWSK-UHFFFAOYSA-N trimethoxy-[2-(2-trimethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CO[Si](OC)(OC)CCSSSSCC[Si](OC)(OC)OC JSXKIRYGYMKWSK-UHFFFAOYSA-N 0.000 claims description 3
JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 claims description 3
KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 claims 2
DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims 2
TVYXSFBEKKZTSF-UHFFFAOYSA-N 2-chloropropyl(triethoxy)silane Chemical compound CCO[Si](CC(C)Cl)(OCC)OCC TVYXSFBEKKZTSF-UHFFFAOYSA-N 0.000 claims 1
KQVVPOMBWBKNRS-UHFFFAOYSA-N 3-(1,3-benzothiazol-2-yl)propyl-triethoxysilane Chemical compound C1=CC=C2SC(CCC[Si](OCC)(OCC)OCC)=NC2=C1 KQVVPOMBWBKNRS-UHFFFAOYSA-N 0.000 claims 1
IABJHLPWGMWHLX-UHFFFAOYSA-N 3-(1,3-benzothiazol-2-yl)propyl-trimethoxysilane Chemical compound C1=CC=C2SC(CCC[Si](OC)(OC)OC)=NC2=C1 IABJHLPWGMWHLX-UHFFFAOYSA-N 0.000 claims 1
229910052799 carbon Inorganic materials 0.000 abstract description 3
229920000642 polymer Polymers 0.000 description 41
239000000945 filler Substances 0.000 description 26
239000000806 elastomer Substances 0.000 description 25
150000001875 compounds Chemical class 0.000 description 16
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 14
239000003795 chemical substances by application Substances 0.000 description 14
238000004073 vulcanization Methods 0.000 description 13
239000004594 Masterbatch (MB) Substances 0.000 description 12
-1 bromomethylstyrene Chemical class 0.000 description 12
239000000654 additive Substances 0.000 description 9
239000003921 oil Substances 0.000 description 9
235000019198 oils Nutrition 0.000 description 9
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 8
150000001993 dienes Chemical class 0.000 description 8
238000012545 processing Methods 0.000 description 8
235000014692 zinc oxide Nutrition 0.000 description 8
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 7
230000003993 interaction Effects 0.000 description 7
239000000126 substance Substances 0.000 description 7
229910052717 sulfur Inorganic materials 0.000 description 7
239000011787 zinc oxide Substances 0.000 description 7
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 6
239000011593 sulfur Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
239000000178 monomer Substances 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
235000021355 Stearic acid Nutrition 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
238000004040 coloring Methods 0.000 description 4
238000004132 cross linking Methods 0.000 description 4
230000007423 decrease Effects 0.000 description 4
239000012764 mineral filler Substances 0.000 description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
238000005096 rolling process Methods 0.000 description 4
239000008117 stearic acid Substances 0.000 description 4
239000004606 Fillers/Extenders Substances 0.000 description 3
241000063973 Mattia Species 0.000 description 3
230000003712 anti-aging effect Effects 0.000 description 3
229920003211 cis-1,4-polyisoprene Polymers 0.000 description 3
239000003431 cross linking reagent Substances 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
230000003014 reinforcing effect Effects 0.000 description 3
238000002444 silanisation Methods 0.000 description 3
239000000454 talc Substances 0.000 description 3
229910052623 talc Inorganic materials 0.000 description 3
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 2
RUROFEVDCUGKHD-UHFFFAOYSA-N 3-bromoprop-1-enylbenzene Chemical compound BrCC=CC1=CC=CC=C1 RUROFEVDCUGKHD-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
229920002943 EPDM rubber Polymers 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000012190 activator Substances 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
230000001588 bifunctional effect Effects 0.000 description 2
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238000013329 compounding Methods 0.000 description 2
238000010168 coupling process Methods 0.000 description 2
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PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
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125000005843 halogen group Chemical group 0.000 description 2
230000020169 heat generation Effects 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
239000003999 initiator Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
239000000049 pigment Substances 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
229920002959 polymer blend Polymers 0.000 description 2
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RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
239000004071 soot Substances 0.000 description 2
229920003051 synthetic elastomer Polymers 0.000 description 2
239000005061 synthetic rubber Substances 0.000 description 2
238000010998 test method Methods 0.000 description 2
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
229960002447 thiram Drugs 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 2
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
238000011925 1,2-addition Methods 0.000 description 1
MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
HLBZWYXLQJQBKU-UHFFFAOYSA-N 4-(morpholin-4-yldisulfanyl)morpholine Chemical compound C1COCCN1SSN1CCOCC1 HLBZWYXLQJQBKU-UHFFFAOYSA-N 0.000 description 1
WXACXMWYHXOSIX-UHFFFAOYSA-N 5-propan-2-ylidenecyclopenta-1,3-diene Chemical compound CC(C)=C1C=CC=C1 WXACXMWYHXOSIX-UHFFFAOYSA-N 0.000 description 1
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WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
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GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
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230000026030 halogenation Effects 0.000 description 1
238000005658 halogenation reaction Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229920006270 hydrocarbon resin Polymers 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
239000000463 material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
FIMHASWLGDDANN-UHFFFAOYSA-M methyl sulfate;tributyl(methyl)azanium Chemical compound COS([O-])(=O)=O.CCCC[N+](C)(CCCC)CCCC FIMHASWLGDDANN-UHFFFAOYSA-M 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
238000000465 moulding Methods 0.000 description 1
125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
230000019612 pigmentation Effects 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
230000001698 pyrogenic effect Effects 0.000 description 1
239000012763 reinforcing filler Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000565 sealant Substances 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
230000035882 stress Effects 0.000 description 1
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
229940124530 sulfonamide Drugs 0.000 description 1
150000003456 sulfonamides Chemical class 0.000 description 1
235000001508 sulfur Nutrition 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
150000003557 thiazoles Chemical class 0.000 description 1
150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
125000003396 thiol group Chemical group [H]S* 0.000 description 1
150000003585 thioureas Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000004636 vulcanized rubber Substances 0.000 description 1
239000001993 wax Substances 0.000 description 1
238000009736 wetting Methods 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000012991 xanthate Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Mechanical Engineering (AREA)
Compositions Of Macromolecular Compounds (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

HU0302341A 2000-06-13 2001-05-09 Eljárás szilícium-dioxiddal töltött elasztomer-készítmények előállítására HUP0302341A2 (hu)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US21104900P	2000-06-13	2000-06-13
US09/592,757 US6624220B1 (en)	1997-12-15	2000-06-13	Transparent and colorable elastomeric compositions
PCT/US2001/014975 WO2001096463A2 (en)	2000-06-13	2001-05-09	Method for preparing silica filled elastomeric compositions

Publications (1)

Publication Number	Publication Date
HUP0302341A2 true HUP0302341A2 (hu)	2003-10-28

Family

ID=26905764

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
HU0302341A HUP0302341A2 (hu)	2000-06-13	2001-05-09	Eljárás szilícium-dioxiddal töltött elasztomer-készítmények előállítására

Country Status (14)

Country	Link
EP (1)	EP1309657A2 (pl)
JP (1)	JP2004503412A (pl)
KR (1)	KR20030008157A (pl)
CN (1)	CN1177893C (pl)
AU (1)	AU2001259675A1 (pl)
BR (1)	BR0111626A (pl)
CA (1)	CA2413094A1 (pl)
CZ (1)	CZ20024077A3 (pl)
HU (1)	HUP0302341A2 (pl)
MX (1)	MXPA02012466A (pl)
PL (1)	PL359968A1 (pl)
RU (1)	RU2002134760A (pl)
TW (1)	TW539710B (pl)
WO (1)	WO2001096463A2 (pl)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2383474A1 (en) *	2002-04-26	2003-10-26	Bayer Inc.	Rubber composition for tire treads
US7201944B2 (en) *	2002-12-18	2007-04-10	Bridgestone Firestone North American Tire, Llc	Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention with bright steel
FR2856071B1 (fr) *	2003-06-16	2005-08-12	Atofina	Agent de couplage pour composition elastomerique comprenant une charge renforcante
KR100738655B1 (ko)	2005-09-28	2007-07-11	금호타이어 주식회사	점착성이 우수한 타이어 에이펙스용 고무 조성물
KR100718168B1 (ko)	2005-09-30	2007-05-15	금호타이어 주식회사	나노충진제와 커플링제를 포함하는 타이어용 고무조성물
WO2008071208A1 (en) *	2006-12-13	2008-06-19	Pirelli Tyre S.P.A.	Tire and crosslinkable elastomeric composition
US7625965B2 (en) *	2007-02-08	2009-12-01	Momentive Performance Materials Inc.	Rubber composition, process of preparing same and articles made therefrom
KR100871991B1 (ko) *	2007-09-27	2008-12-05	금호타이어 주식회사	타이어 트레드 고무조성물
JP5421525B2 (ja) *	2007-10-19	2014-02-19	住友ゴム工業株式会社	ブラダー用ゴム組成物およびそれを用いたタイヤ加硫用ブラダー
US7816435B2 (en) *	2007-10-31	2010-10-19	Momentive Performance Materials Inc.	Halo-functional silane, process for its preparation, rubber composition containing same and articles manufactured therefrom
EP2303951B1 (en) *	2008-07-24	2018-03-07	Industrias Negromex, S.a. De C.v.	Processes for making silane, hydrophobated silica, silica masterbatch and rubber products
EP2819854B1 (en) *	2012-03-02	2020-04-15	Cabot Corporation	Elastomeric composites containing modified fillers and functionalized elastomers
US10563015B2 (en)	2015-01-28	2020-02-18	Dow Silicones Corporation	Elastomeric compositions and their applications
US12534576B2 (en)	2015-01-28	2026-01-27	Dow Silicones Corporation	Elastomeric compositions and their applications
CN107641228B (zh) *	2016-07-20	2022-10-21	中国石油化工股份有限公司	有机硅烷的应用和橡胶组合物以及硫化橡胶及其制备方法
GB201613397D0 (en)	2016-08-03	2016-09-14	Dow Corning	Cosmetic composition comprising silicone materials
GB201613412D0 (en) *	2016-08-03	2016-09-14	Dow Corning	Elastomeric compositions and their applications
GB201613414D0 (en)	2016-08-03	2016-09-14	Dow Corning	Elastomeric compositions and their applications
GB201613399D0 (en)	2016-08-03	2016-09-14	Dow Corning	Cosmetic composition comprising silicone materials
GB201707437D0 (en)	2017-05-09	2017-06-21	Dow Corning	Lamination adhesive compositions and their applications
GB201707439D0 (en)	2017-05-09	2017-06-21	Dow Corning	Lamination Process
SG11202009972RA (en) *	2018-04-11	2020-11-27	Exxonmobil Chemical Patents Inc	Butyl rubber additives for improved tire tread performance
CN114829155B (zh) *	2019-12-17	2024-03-05	埃克森美孚化学专利公司	用于改进卡车和公共汽车子午线轮胎性能的官能化聚合物胎面添加剂
CN116285125B (zh) *	2023-03-28	2024-01-19	常州窗友塑胶有限公司	一种密封胶条及其制备方法

Family Cites Families (4)

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Publication number	Priority date	Publication date	Assignee	Title
FR2661915B1 (fr) *	1990-05-11	1993-12-24	Rhone Poulenc Chimie	Composition elastometrique a matrice halogenobutyl renforcee par une charge minerale siliceuse et son utilisation dans l'industrie pneumatique.
US5162409B1 (en) *	1991-08-02	1997-08-26	Pirelli Armstrong Tire Corp	Tire tread rubber composition
CA2125736A1 (en) *	1994-05-05	1995-11-06	David John Zanzig	Tire tread with quantitative silica reinforcement
WO1999031178A1 (en) *	1997-12-15	1999-06-24	Exxon Chemical Patents Inc.	Transparent and colorable elastomeric compositions

2001
- 2001-05-09 CA CA002413094A patent/CA2413094A1/en not_active Abandoned
- 2001-05-09 WO PCT/US2001/014975 patent/WO2001096463A2/en not_active Ceased
- 2001-05-09 KR KR1020027016958A patent/KR20030008157A/ko not_active Withdrawn
- 2001-05-09 RU RU2002134760/04A patent/RU2002134760A/ru not_active Application Discontinuation
- 2001-05-09 BR BR0111626-6A patent/BR0111626A/pt not_active IP Right Cessation
- 2001-05-09 JP JP2002510592A patent/JP2004503412A/ja not_active Withdrawn
- 2001-05-09 MX MXPA02012466A patent/MXPA02012466A/es not_active Application Discontinuation
- 2001-05-09 CZ CZ20024077A patent/CZ20024077A3/cs unknown
- 2001-05-09 HU HU0302341A patent/HUP0302341A2/hu unknown
- 2001-05-09 EP EP01933233A patent/EP1309657A2/en not_active Withdrawn
- 2001-05-09 AU AU2001259675A patent/AU2001259675A1/en not_active Abandoned
- 2001-05-09 PL PL35996801A patent/PL359968A1/pl not_active Application Discontinuation
- 2001-05-09 CN CNB018110495A patent/CN1177893C/zh not_active Expired - Fee Related
- 2001-06-12 TW TW090114191A patent/TW539710B/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
BR0111626A (pt)	2003-05-06
WO2001096463A3 (en)	2002-05-23
JP2004503412A (ja)	2004-02-05
WO2001096463A2 (en)	2001-12-20
CZ20024077A3 (cs)	2004-01-14
CN1436210A (zh)	2003-08-13
RU2002134760A (ru)	2004-07-27
AU2001259675A1 (en)	2001-12-24
TW539710B (en)	2003-07-01
PL359968A1 (pl)	2004-09-06
CA2413094A1 (en)	2001-12-20
MXPA02012466A (es)	2003-04-25
KR20030008157A (ko)	2003-01-24
EP1309657A2 (en)	2003-05-14
CN1177893C (zh)	2004-12-01

Legal Events

Date	Code	Title	Description
2007-02-28	FD9A	Lapse of provisional protection due to non-payment of fees

Publication	Publication Date	Title
HUP0302341A2 (hu)	2003-10-28	Eljárás szilícium-dioxiddal töltött elasztomer-készítmények előállítására
CN1254505C (zh)	2006-05-03	可着色的弹性体组合物
US20040014869A1 (en)	2004-01-22	Method for preparing silica filled elastomeric compositions
US6939921B2 (en)	2005-09-06	Colorable elastomeric composition
US20080242771A1 (en)	2008-10-02	Butyl Rubber Composition for Tire Treads
CN1228372C (zh)	2005-11-23	高牵引力和耐磨弹性体组合物
JP2002508425A (ja)	2002-03-19	透明な及び着色可能なエラストマー性組成物
KR20030008159A (ko)	2003-01-24	투명하고 착색가능한 탄성중합체성 조성물
JP2005520022A (ja)	2005-07-07	耐摩耗性エラストマー組成物
EP0650414A1 (en)	1995-05-03	Improved tire sidewall composition
JPH1135735A (ja)	1999-02-09	ゴム組成物
JP4605860B2 (ja)	2011-01-05	ゴム組成物及びそれを用いた空気入りタイヤ
JP4210376B2 (ja)	2009-01-14	タイヤトレッド用ゴム組成物
JP2000351873A (ja)	2000-12-19	ゴム組成物
JP2004002625A (ja)	2004-01-08	タイヤ用ゴム組成物
JP2005041946A (ja)	2005-02-17	ゴム組成物