HUT68268A - Adsorbent material for removing pollutants - Google Patents
Adsorbent material for removing pollutants Download PDFInfo
- Publication number
- HUT68268A HUT68268A HU9401367A HU9401367A HUT68268A HU T68268 A HUT68268 A HU T68268A HU 9401367 A HU9401367 A HU 9401367A HU 9401367 A HU9401367 A HU 9401367A HU T68268 A HUT68268 A HU T68268A
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- Prior art keywords
- weight
- cement
- porous
- adsorption material
- granules
- Prior art date
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- 239000000463 material Substances 0.000 title claims abstract description 24
- 239000003463 adsorbent Substances 0.000 title abstract description 12
- 239000003344 environmental pollutant Substances 0.000 title abstract 2
- 231100000719 pollutant Toxicity 0.000 title abstract 2
- 239000000654 additive Substances 0.000 claims abstract description 15
- 239000004568 cement Substances 0.000 claims abstract description 13
- 239000011148 porous material Substances 0.000 claims abstract description 4
- 239000010457 zeolite Substances 0.000 claims abstract description 3
- 239000008187 granular material Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 239000007900 aqueous suspension Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 239000000975 dye Substances 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000000378 calcium silicate Substances 0.000 abstract description 2
- 229910052918 calcium silicate Inorganic materials 0.000 abstract description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005871 repellent Substances 0.000 abstract 2
- 239000002480 mineral oil Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 241000233866 Fungi Species 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000019462 natural additive Nutrition 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 238000011045 prefiltration Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28011—Other properties, e.g. density, crush strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3028—Granulating, agglomerating or aggregating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1055—Coating or impregnating with inorganic materials
- C04B20/1077—Cements, e.g. waterglass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Public Health (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
A találmány porózus, hidrofób anyagot tartalmazó adszorpci ós anyagra vonatkozik, amely alkalmas káros anyagok, igy például benzinfélék, ásványi és szintetikus olajok és más hasonlók megkötésére.FIELD OF THE INVENTION The present invention relates to a porous adsorbent containing a hydrophobic material which is capable of absorbing harmful substances such as gasoline, mineral and synthetic oils and the like.
A DE-A1 38 00 873 számú szabadalmi leírásból ismert, hogy porózus anyagokat, így például krétát hidrofobizálnak, majd ezt az anyagot a megfelelő szemcseméretben, különösen finom és közepes szemcsézetben a talajba befoglalják és ily módon alkalmazzák folyékony és/vagy áramlóképes folyadékokkal vitt káros anyagok elválasztására.A jelen találmány bejelentőjének egy korábbi javaslata szerint ólaj-a-vízben típusú emulziókat alkalmaznak betonkövek előállításánál, amelynél könnyű adalékanyagokat egy olaj-a-vízben típusú emulzióval és cementtel homogénen elkevernek és betonná vagy betonkővé feldolgozzák. Az így kapott beton ill. betonkő esetében a könnyű adalékanyag mennyisége általában 10 tömeg % alatt van és a betonkő még a szokásos egyéb természetes adalékanyagokat is tartalmazza, így például homokot, kavicsot, stb.It is known from DE-A1 38 00 873 to hydrophobize porous materials such as chalk and to incorporate this material into the soil at appropriate particle size, especially fine and medium particle size, and thereby to apply harmful substances carried by liquid and / or fluid fluids. According to an earlier proposal of the applicant of the present invention, oil-in-water emulsions are used in the preparation of concrete stones, where light additives are homogeneously mixed with an oil-in-water emulsion and cement and processed into concrete or concrete stone. The concrete and thus obtained. In the case of concrete, the amount of lightweight aggregate is generally less than 10% by weight, and the concrete contains even the usual other natural additives such as sand, gravel, etc.
A találmány célja olyan adszorpciós anyag biztosítása, amely egyszerűen előállítható és amely különleges aprítás nélkül közvetlenül mint szabadon folyó, ömlesztett anyag rendelkezésre áll és ily módon tetszés szerint alkalmazható. A találmány szerinti adszorpciós anyag mint adalékanyag szintén alkalmazható kell legyen a helyszínen bekevert betonoknál a benzinfélék és ásványi és szintetikus olajok és más hasonló anyagok lebontására, valamint adszorpciós, szűrő- és töltőanyag céljára.Ilyen esetekben egy adag anyagot például a talajba dolgozunk be vagy egy megfelelő szűrőben alkalmazzuk. E feladat megoldásához a találmány szerinti porózus anyag egy könnyű adalékanyag,különösen kalcium-szilikát vagy absodan vagy zeoloitbázisú gömbformájú porózus granulátum és a hidrofobizáló adalék mellett még 1,5 - 10 t % cementet tartalmaz, igy a könnyű adalékanyag, a hidrofobizáló anyag és a cement elkeverésével közvetlenül olyan terméket nyerünk, amely megtartja a könnyű adalékanyag eredeti szemcsézetét. a feleslegben lévő víz a cementtel kötést létesít, anélkül, hogy lényeges csomósodás vagy agglomeráció következne be és olyan szemcsézet biztosítható, amelynél a maximális szemcsenagyság legfeljebb az eredeti szemcseméret 3-4-szerese. Ily módon egy különlegesen könnyű, szabadon folyó és ömleszthető anyagot biztosítunk, amelynél a költséges szárítási lépés elhagyható anélkül, hogy a hidrofob kiindulási anyag csomosodása bekövetkezne.A maximális szemcsenagyság előnyösen <15 mm, még előnyösebben <5 mm.It is an object of the present invention to provide an adsorbent material which is readily prepared and directly available as a free-flowing bulk material without special comminution and can thus be used as desired. The adsorbent material of the present invention may also be used as an additive for the mixing of on-site concrete with petrol and mineral and synthetic oils and the like, as well as for adsorption, filtration and filler material. filter. In order to accomplish this task, the porous material of the present invention comprises, in addition to a light additive, in particular, calcium silicate or spherical granules of an absodan or zeolite-based spherical granule and a hydrophobizing additive containing 1.5 to 10% by weight of cement. mixing directly produces a product which retains the original granulate of the light additive. the excess water establishes a bond with the cement without significant agglomeration or agglomeration and provides a particle size where the maximum particle size is up to 3-4 times the original particle size. In this way, a particularly light, free flowing and bulking material is provided, whereby the costly drying step can be omitted without lumping of the hydrophobic starting material. The maximum particle size is preferably <15 mm, more preferably <5 mm.
Míg az 1,5 - 10 t% mennyiségű cement mindenekelőtt azt biztosítja, hogy az adszorpciós anyag előállításánál csomosodás nem következik be, ez a cementmennyiség arra is megfelel, hogy további adalékanygokat, igy például homokot vagy kavicsot és vizet keverjünk be és így közvetlenül a helyszínen felhasználható betont állítsunk elő.While 1.5 to 10% by weight of cement first of all ensures that no adsorption occurs in the production of adsorbent material, this amount of cement is also suitable for mixing additional additives such as sand or gravel and water directly on site to make usable concrete.
A gombákkal szembeni ellenállást valamint a benzifélék és ásványi vagy szintetikus eredetű olajok jobb lebontását azzal biztosítjuk, hogy a hidrofobizált granulátumhoz még 2 - 10 ti mennyiségben vas-oxid színezéket, előnyösen vas^oxid feketét adagolunk.The resistance to fungi and the better degradation of benzene and mineral or synthetic oils are ensured by the addition of 2 to 10 µl of iron oxide dye, preferably iron oxide black, to the hydrophobized granulate.
A találmány szerinti adszorpciós anyag az előállítás után közvetlenül csomagolható és a granulátummal töltött csomagok, így például zsákok könnyen szállíthatók, ahol előny, hogy a hidrofobizált és cementtel reagáltatott granulátum térfogatsúlya 0,5 - 0,7, előnyösen 0,58 - 0,65 g/cm3 közötti érték. Ez a térfogatsúly lehetővé teszi, hogy 100 1 térfogatú egységek könnyen, mechanikai segítség nélkül szállíthatók.The adsorbent material according to the invention can be packaged immediately after preparation and packed with granules, such as bags, whereby the hydrophobised and cementitious granules preferably have a bulk weight of 0.5-0.7 g, preferably 0.58-0.65 g. / cm 3 . This volumetric weight allows 100 l units to be transported easily without mechanical assistance.
A találmány szerinti eljárással a fenti adszorpciós anyagot úgy állítjuk elő, hogy a porózus könnyű adalékanyagot egy olaj-a-vízben szuszpenzióban - amely 3 - 13 t% zsírsavat és/vagy karbonsavviaszt tartalmaz - adott eseetben paraffin és víz hozzáadásával keverünk, majd a kapott keveréket 1,5 - 10 t% cementtel reagáltajuk és az így nyert anyagot csomagoljuk. A cement adagolásával a porózus könnyű adalékanyag olaj-a-vízben szuszpenzióban való elkeverésénél a hidrofobizálással egyidejűleg a felesleges vizet is megkötjük. E kötési folyamatnál hő szabadul fel és ez a hidratációs hő a hidrofobizált termék gyors szárítását eredményezi, miáltal a kapott termék költséges szárítási művelet nélkül közvetlenül csomagolható. A granulátum és a szuszpenzió tömegaránya 1,5 - 3:1, előnyösen 2:1 és a festékanyag a cementtel együtt adagolható.According to the process of the present invention, the above adsorbent material is prepared by mixing the porous light additive in an oil-in-water suspension containing from 3 to 13% by weight of fatty acid and / or carboxylic acid wax, optionally with the addition of paraffin and water. 1.5 to 10% by weight of cement and the resulting material is packaged. By adding cement, the excess water is cured while mixing the porous light additive in an oil-in-water slurry while hydrophobizing. In this curing process, heat is released and this hydration heat results in rapid drying of the hydrophobized product, whereby the resulting product can be packaged directly without costly drying. The weight ratio of granulate to suspension is 1.5 to 3: 1, preferably 2: 1 and the dye can be added together with the cement.
A felhasználásra kerülő porózus könnyű adalékanyag térfogatsúlya előnyösen 0,4 - 0,5, különösen 0,42 - 0,45 g/cm3, és az olaj-a-vízben szuszpenzióval valamint a cementtel való elkeverés után közvetlenül olyan terméket nyerünk, amelynek térfogatsúlya 0,5 - 0,7, előnyösen 0,58 - 0,65 g/cm3.The porous lightweight additive used preferably has a bulk density of 0.4-0.5 g, in particular 0.42-0.45 g / cm 3 , and immediately after mixing with the oil-in-water suspension and the cement, a product having a bulk density of 0.5-0.7 g, preferably 0.58-0.65 g / cm 3 .
A fentiek szerint előállított találmány szerinti adszorpciós anyag különösen alkalmas kiorozott szénhidrogének elválasztására és közvetlenül alkalmazható előszűrőként például kémiai tisztítóknál. Az adszorpciós anyag hasonlóképpenThe adsorbent material of the invention prepared as above is particularly suitable for the separation of chlorinated hydrocarbons and can be used directly as a pre-filter, for example in chemical purifiers. The adsorption material is likewise
alkalmas szennyvíztisztításnál olajmegkötőanyagként a földön és a tengeren egyaránt, továbbá használható betonadalékként, töltőanyagként, így például fugáknál, valamint szűrőként benzinleválasztóknál, stb. A találmány szerinti adszorpciós anyag szemcsézete igen széleskörű felhasználhatóságot tesz lehetővé, amelyek közül nem utolsósorban a helyszínen bekeverhető betonoknál való felhasználhatóságot kell megemlíteni.Suitable as oil binder for wastewater treatment, both on land and at sea, and as a concrete additive, filler such as joints, and as a filter in petrol separators, etc. The particle size of the adsorbent material according to the invention allows a very wide range of applications, not least of which is the use in the field of concrete for on-site mixing.
Claims (8)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT187492 | 1992-09-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HU9401367D0 HU9401367D0 (en) | 1994-09-28 |
| HUT68268A true HUT68268A (en) | 1995-06-28 |
Family
ID=3522884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU9401367A HUT68268A (en) | 1992-09-21 | 1993-09-21 | Adsorbent material for removing pollutants |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0619759A1 (en) |
| CZ (1) | CZ119694A3 (en) |
| HU (1) | HUT68268A (en) |
| SK (1) | SK57394A3 (en) |
| WO (1) | WO1994006555A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE202010011640U1 (en) * | 2010-08-20 | 2011-11-21 | Rehau Ag + Co. | dry mortar |
| RU2481282C1 (en) * | 2011-12-29 | 2013-05-10 | Юлия Алексеевна Щепочкина | Mixture for producing porous aggregate |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56100883A (en) * | 1980-01-16 | 1981-08-13 | Chiyoda Kagaku Kenkyusho:Kk | Oil absorbing agent |
| JPS6020985A (en) * | 1983-07-15 | 1985-02-02 | Wakaba Kagaku Kk | Composition for disposal of oil |
| JPS6051651A (en) * | 1983-08-31 | 1985-03-23 | 株式会社トクヤマ | Manufacture of formed body |
| DE3717848A1 (en) * | 1987-05-27 | 1988-12-08 | Rwk Rhein Westfael Kalkwerke | Inorganic material and process for the production thereof |
| JPH041242A (en) * | 1990-04-18 | 1992-01-06 | Nippon Steel Corp | Production of oil-absorbing aggregate from zeolite and the like and oil-absorbing aggregate prepared therewith |
| JP3192653B2 (en) * | 1990-08-30 | 2001-07-30 | 美智子 遠藤 | How to solidify waste tempura oil |
| JPH04219185A (en) * | 1990-12-18 | 1992-08-10 | Nippon Steel Corp | Oil absorptive aggregate and production thereof |
| ES2072140T3 (en) * | 1991-01-09 | 1995-07-01 | Gattinger Heidemarie | USE OF EMULSIONS OF THE OIL TYPE IN WATER, AS WELL AS A PROCEDURE FOR THE PRODUCTION OF CONCRETE BLOCKS WITH SPECIAL PROPERTIES. |
-
1993
- 1993-09-21 HU HU9401367A patent/HUT68268A/en unknown
- 1993-09-21 WO PCT/AT1993/000146 patent/WO1994006555A1/en not_active Ceased
- 1993-09-21 CZ CZ941196A patent/CZ119694A3/en unknown
- 1993-09-21 SK SK573-94A patent/SK57394A3/en unknown
- 1993-09-21 EP EP93920582A patent/EP0619759A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| CZ119694A3 (en) | 1994-12-15 |
| WO1994006555A1 (en) | 1994-03-31 |
| EP0619759A1 (en) | 1994-10-19 |
| SK57394A3 (en) | 1994-11-09 |
| HU9401367D0 (en) | 1994-09-28 |
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