ID22443A - Metallosena heterosiklik dan polimerisasi katalis - Google Patents

Metallosena heterosiklik dan polimerisasi katalis

Info

Publication number
ID22443A
ID22443A IDW990456A ID990456A ID22443A ID 22443 A ID22443 A ID 22443A ID W990456 A IDW990456 A ID W990456A ID 990456 A ID990456 A ID 990456A ID 22443 A ID22443 A ID 22443A
Authority
ID
Indonesia
Prior art keywords
metallosena
heterosiclic
catalyst polymerization
polymerization
catalyst
Prior art date
Application number
IDW990456A
Other languages
English (en)
Inventor
John A Ewen
Michael J Elder
Robert L Jones Jr
Yuri A Dubitsky
Original Assignee
Montelll Technology Co Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montelll Technology Co Bv filed Critical Montelll Technology Co Bv
Publication of ID22443A publication Critical patent/ID22443A/id

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/52Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
    • C07D333/62Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
    • C07D333/68Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C07D333/70Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 2
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D495/00Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/05Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Indole Compounds (AREA)
IDW990456A 1996-11-15 1997-11-12 Metallosena heterosiklik dan polimerisasi katalis ID22443A (id)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96118369 1996-11-15

Publications (1)

Publication Number Publication Date
ID22443A true ID22443A (id) 1999-10-14

Family

ID=8223400

Family Applications (1)

Application Number Title Priority Date Filing Date
IDW990456A ID22443A (id) 1996-11-15 1997-11-12 Metallosena heterosiklik dan polimerisasi katalis

Country Status (21)

Country Link
US (2) US7238818B2 (id)
EP (2) EP1327636B1 (id)
KR (1) KR100536794B1 (id)
CN (1) CN1113890C (id)
AR (1) AR009613A1 (id)
AU (1) AU733813B2 (id)
BR (1) BR9715006B1 (id)
CA (1) CA2271861C (id)
DE (2) DE69735068T2 (id)
ES (2) ES2197377T3 (id)
HU (1) HUP9904527A2 (id)
ID (1) ID22443A (id)
IL (1) IL129600A0 (id)
NO (1) NO992352L (id)
PE (1) PE52899A1 (id)
PL (1) PL188107B1 (id)
RU (1) RU2194708C2 (id)
TR (1) TR199901635T2 (id)
TW (1) TW394779B (id)
WO (1) WO1998022486A1 (id)
ZA (1) ZA9710211B (id)

Families Citing this family (118)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9715006B1 (pt) * 1996-11-15 2011-06-28 metalocenos heterocìclicos, ligantes, sistema catalìtico e processo para a polimerização de monÈmeros polimerizáveis por adição.
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
HUP0001331A2 (hu) 1997-11-12 2000-08-28 Montell Technology Company B.V. Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
DE19903306A1 (de) * 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
KR20020034193A (ko) 1999-09-22 2002-05-08 간디 지오프레이 에이치. 올레핀 중합을 위한 촉매 시스템 및 방법
EP1226206B1 (en) 1999-11-04 2003-10-22 ExxonMobil Chemical Patents Inc. Propylene copolymer foams and their use
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
AU780051B2 (en) 1999-12-21 2005-02-24 Exxonmobil Chemical Patents Inc Adhesive alpha-olefin inter-polymers
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
BR0010277A (pt) 1999-12-28 2002-01-15 Basell Technology Co Bv Compostos metalocênicos heterocìclicos e seu uso em sistemas catalìticos para a produção de polìmeros olefìnicos
WO2001048040A1 (en) 1999-12-28 2001-07-05 Basell Technology Company B.V. Process for the preparation of ethylene polymers
EP1226193B1 (en) 1999-12-28 2006-07-19 Basell Polyolefine GmbH Process for the preparation of ethylene polymers
WO2001053360A1 (en) * 2000-01-18 2001-07-26 Basell Technology Company B.V. Process for producing substantially amorphous propylene-based polymers
WO2001062764A1 (en) 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
US20040072975A1 (en) 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
GB0007002D0 (en) * 2000-03-22 2000-05-10 Borealis Polymers Oy Catalysts
DE10025412A1 (de) 2000-05-24 2001-11-29 Basell Polypropylen Gmbh Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE10028432A1 (de) 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
US7183332B2 (en) 2000-12-22 2007-02-27 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
EP1265933B1 (en) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Catalyst components for the polymerization of olefins
ATE409180T1 (de) 2001-05-15 2008-10-15 Basell Polyolefine Gmbh Synthese von zyklopentadien derivaten
US7417006B2 (en) 2001-05-21 2008-08-26 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
DE10126265A1 (de) 2001-05-29 2002-12-05 Basell Polyolefine Gmbh Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte
EP1395619B1 (en) 2001-06-12 2011-08-10 Basell Polyolefine GmbH Process for the polymerization of 1-butene
US7074864B2 (en) 2001-06-12 2006-07-11 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
US7241903B2 (en) 2001-06-22 2007-07-10 Basell Polyolefine Gmbh Metallocenes, use in catalyst system for producing olefin polymers
DE10145453A1 (de) 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
CN1255441C (zh) 2001-09-14 2006-05-10 巴塞尔聚烯烃股份有限公司 烯烃的聚合方法
JP2005510590A (ja) 2001-11-27 2005-04-21 バセル ポリオレフィン ジーエムビーエイチ ポリマー組成物の処理の方法
EP1448578B1 (en) 2001-11-30 2006-07-26 Basell Polyolefine GmbH Metallocene compounds and process for the preparation of propylene polymers
US6916892B2 (en) 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
AU2003279668A1 (en) 2002-06-26 2004-01-19 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
US7700690B2 (en) * 2002-06-26 2010-04-20 Basell Poliolefine Italia S.R.L. Impact-resistant polyolefin compositions
WO2004007569A1 (en) 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of catalyst systems
JP2005538245A (ja) 2002-07-15 2005-12-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 担体を有する触媒組成物の製造方法
US20060089253A1 (en) * 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
JP2005536566A (ja) 2002-08-22 2005-12-02 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
EP1539843B1 (en) 2002-09-06 2009-10-14 Basell Polyolefine GmbH Process for the copolymerization of ethylene
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
JP2006504834A (ja) 2002-11-04 2006-02-09 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 改良された活性を有する触媒組成物の製造方法
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US7534848B2 (en) 2002-12-04 2009-05-19 Basell Polyolefine Gmbh 1-butene copolymers and process for preparing them
DE10260095A1 (de) 2002-12-19 2004-07-01 Basell Polyolefine Gmbh Verfahren zur Herstellung von heterocyclischen Ketonen
US7507688B2 (en) 2002-12-20 2009-03-24 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
CA2510061A1 (en) 2002-12-20 2004-07-08 Basell Polyolefin Gmbh Copolymers of ethylene with .alpha.-olefins
US7195806B2 (en) 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
ATE364641T1 (de) 2003-04-03 2007-07-15 Basell Polyolefine Gmbh Herstellung von hochmolekularen polyolefinen in gegenwart einer organischen übergangsmetallverbindung in einem gasphasen- wirbelschichtreaktor
WO2004092228A1 (en) 2003-04-17 2004-10-28 Basell Poliolefine Italia S.R.L. Gas-phase olefin polymerization process
WO2004104052A1 (en) 2003-05-21 2004-12-02 Basell Polyolefine Gmbh Transition-metal complexes with tridentate, nitrogen-containing ligands
JP4709748B2 (ja) 2003-07-04 2011-06-22 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン重合方法
DE10352139A1 (de) 2003-11-04 2005-06-09 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem und Verfahren zur Herstellung von Polyolefinen
US7544826B2 (en) 2003-12-16 2009-06-09 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
JP2007514685A (ja) 2003-12-19 2007-06-07 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
US7442667B2 (en) 2003-12-23 2008-10-28 Bosell Polyolefine Gmbh Preparation of supported cocatalysts
KR20060118564A (ko) 2003-12-23 2006-11-23 바젤 폴리올레핀 게엠베하 올레핀 중합용 촉매계
US7335250B2 (en) 2004-02-06 2008-02-26 Ivoclar Vivadent Ag Dental composites based on X-ray-opaque mixed oxides prepared by flame spraying
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
WO2005095468A2 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefin
WO2005095473A1 (en) * 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004039877A1 (de) 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
WO2006053911A1 (en) 2004-11-22 2006-05-26 Basell Polyolefine Gmbh Propylene based terpolymers
US7169864B2 (en) 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
JP2008523231A (ja) * 2004-12-13 2008-07-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン繊維
DE102004061618A1 (de) * 2004-12-17 2006-06-22 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
WO2006067214A1 (en) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Fibres having elastic properties
KR100753477B1 (ko) * 2005-01-31 2007-08-31 주식회사 엘지화학 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
JP2008534705A (ja) 2005-03-23 2008-08-28 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン類の重合法
JP5294842B2 (ja) 2005-03-23 2013-09-18 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィンの重合プロセス
DE102005014395A1 (de) 2005-03-24 2006-09-28 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
EP1877453A1 (en) 2005-05-03 2008-01-16 Basell Polyolefine GmbH Process for the polymerization of alpha olefins
EP1879959B1 (en) 2005-05-11 2011-07-06 Basell Poliolefine Italia S.r.l. Polymerization process for preparing polyolefin blends
US7232869B2 (en) 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
DE102005035477A1 (de) 2005-07-26 2007-02-01 Basell Polyolefine Gmbh Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren
EP1926738B1 (en) * 2005-09-19 2009-12-09 Basell Polyolefine GmbH Synthesis of cyclopentadienedithiophene derivatives
JP2009511681A (ja) * 2005-10-14 2009-03-19 バーゼル・ポリオレフィン・ゲーエムベーハー ハロゲン化マグネシウム上に担持された複合触媒系
DE102005056775A1 (de) * 2005-11-28 2007-05-31 Basell Polyolefine Gmbh Verfahren für den Katalysatorwechsel in einem Gasphasenwirbelschichtreaktor
US7868197B2 (en) * 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
EP2245076B1 (en) 2007-12-19 2011-08-31 Basell Polyolefine GmbH Ethylene terpolymers
EP2247424B1 (en) * 2008-02-29 2012-07-04 Basell Poliolefine Italia S.r.l. Polyolefin compositions
EP2367854B1 (en) 2008-12-17 2012-11-28 Basell Polyolefine GmbH Catalyst system for olefin polymerization, its production and use
US8859451B2 (en) 2009-12-18 2014-10-14 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
CN102712715B (zh) 2010-01-21 2014-10-29 巴塞尔聚烯烃股份有限公司 在低聚催化剂存在下制备乙烯共聚物组合物的方法
US8916662B2 (en) 2010-04-12 2014-12-23 Lotte Chemical Corporation Method for preparing olefin-diene copolymer using transition metal compound containing thiophene-fused cyclopentadienyl ligand
JP5567208B2 (ja) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション オレフィン重合用触媒組成物およびこれを用いたポリオレフィンの製造方法
KR100986301B1 (ko) 2010-04-12 2010-10-07 아주대학교산학협력단 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합
JP5567209B2 (ja) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション オレフィン重合用担持触媒およびこれを用いたポリオレフィンの製造方法
JP5546678B2 (ja) 2010-04-12 2014-07-09 ロッテ ケミカル コーポレーション チオフェン−縮合環シクロペンタジエニルリガンドを含む遷移金属化合物を使用したポリプロピレンの製造方法
US8999875B2 (en) 2010-05-28 2015-04-07 Basell Polyolefine Gmbh Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use
WO2011160828A1 (en) 2010-06-25 2011-12-29 Basell Polyolefine Gmbh Process for the production of high-strength polyolefin compositions and polyolefin compositions produced by this process
US8893725B2 (en) 2011-01-28 2014-11-25 R. J. Reynolds Tobacco Company Polymeric materials derived from tobacco
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
CN104558058B (zh) * 2013-10-12 2017-08-08 中国科学院长春应用化学研究所 茂金属配合物及其制备方法、催化剂组合物
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
KR101616200B1 (ko) * 2014-10-27 2016-04-27 롯데케미칼 주식회사 저온 내충격성이 우수한 폴리프로필렌 수지 조성물 및 수지 성형품
SG11201703851UA (en) 2014-11-25 2017-06-29 Univation Tech Llc Methods of controlling polyolefin melt index
EP3694811B1 (en) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Supported catalyst system
KR102165484B1 (ko) 2018-05-10 2020-10-14 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물 및 이를 포함하는 올레핀 중합 촉매
WO2020056119A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
EP3927765A1 (en) 2019-02-20 2021-12-29 Fina Technology, Inc. Polymer compositions with low warpage
CN110372813B (zh) * 2019-08-19 2022-06-28 迈瑞尔实验设备(上海)有限公司 一种用于催化乙烯聚合制备聚乙烯蜡的催化剂组合物及其应用
WO2022018293A1 (en) * 2020-07-23 2022-01-27 Borealis Ag Metallocene complexes and catalysts made therefrom
CN112403525B (zh) * 2020-12-03 2021-12-31 大连理工大学 一种具有配体分子內异面结构的金属有机框架催化剂的制备方法及其应用
CN114716485B (zh) * 2021-01-04 2024-08-06 中国石油化工股份有限公司 一种茂金属、催化剂组合物及其在合成基础油中的应用
BR112023019645A2 (pt) 2021-04-26 2023-11-07 Fina Technology Folhas de polímero catalisadas de sítio único finas
US20240209124A1 (en) 2021-04-30 2024-06-27 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS588686B2 (ja) 1978-12-01 1983-02-17 チッソ株式会社 α↓−オレフイン重合体の製造方法
JPS5950246B2 (ja) 1979-10-16 1984-12-07 三井化学株式会社 成形用オレフイン共重合体の製法
DE3007725A1 (de) 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn Verfahren zur herstellung von polyethylen, polypropylen und copolymeren
US4935474A (en) 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5122583A (en) 1987-02-02 1992-06-16 Fina Technology, Inc. Efficiency of a pre-polymerized catalyst
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4975403A (en) 1987-09-11 1990-12-04 Fina Technology, Inc. Catalyst systems for producing polyolefins having a broad molecular weight distribution
US5225500A (en) 1988-07-15 1993-07-06 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US4892851A (en) 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5155080A (en) 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5036034A (en) 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene
EP0427697B1 (en) 1989-10-10 1996-05-08 Fina Technology, Inc. Metallocene catalysts with Lewis acids and aluminum alkyls
FR2654564B1 (fr) 1989-11-10 1992-01-17 Renault Interface de ligne pour un reseau de transmission d'informations.
US5416228A (en) 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
WO1993014132A1 (en) 1992-01-06 1993-07-22 The Dow Chemical Company Improved catalyst composition
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5434116A (en) * 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
EP0590486A3 (en) * 1992-09-24 1994-08-24 Idemitsu Kosan Co Polymerization catalysts and process for producing polymers
US5459117A (en) 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
IT1271406B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti
US5539124A (en) * 1994-12-19 1996-07-23 Occidental Chemical Corporation Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring
IT1272923B (it) * 1995-01-23 1997-07-01 Spherilene Srl Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
US6403772B1 (en) * 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
BR9715006B1 (pt) * 1996-11-15 2011-06-28 metalocenos heterocìclicos, ligantes, sistema catalìtico e processo para a polimerização de monÈmeros polimerizáveis por adição.
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins

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