IE33845L - Polymerization of olefins. - Google Patents
Polymerization of olefins.Info
- Publication number
- IE33845L IE33845L IE152169A IE152169A IE33845L IE 33845 L IE33845 L IE 33845L IE 152169 A IE152169 A IE 152169A IE 152169 A IE152169 A IE 152169A IE 33845 L IE33845 L IE 33845L
- Authority
- IE
- Ireland
- Prior art keywords
- reaction product
- ethylene
- polymerized
- ticl
- isoprene
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 15
- 239000007795 chemical reaction product Substances 0.000 abstract 11
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 7
- 239000005977 Ethylene Substances 0.000 abstract 7
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 3
- -1 aliphatic diene Chemical class 0.000 abstract 3
- 150000001993 dienes Chemical class 0.000 abstract 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 3
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 239000000395 magnesium oxide Substances 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 abstract 1
- 101100188555 Arabidopsis thaliana OCT6 gene Proteins 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- RTQCAYKHUMWCEM-UHFFFAOYSA-N [Mg].ClO Chemical compound [Mg].ClO RTQCAYKHUMWCEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract 1
- 239000001095 magnesium carbonate Substances 0.000 abstract 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1,245,507. Polymerizing olefins. SOLVAY & CIE. 13 Nov., 1969 [2 Dec., 1968; 6 Oct., 1969], No. 55626/69. Heading C3P. Olefins are (co)polymerized in the presence of a catalytic system comprising (a) a solid complex produced by reacting a halogenated derivative of a transition metal with a solid support, and (b) an organometallic activator comprising the reaction product of a diolefin and a compound of the formula AlR 3 wherein R is hydrogen or a monovalent hydrocarbon radical, the ratio, P, of the number of radicals derived from said diolefin to the number of radicals R in the said product being between 0 25 and 3. The catalytic systems are preferably used to polymerize at least two alphaolefins (e.g. ethylene with propylene and/or butene-1) optionally with a diolefin (e.g. a non-conjugated aliphatic diene, a non-conjugated monocyclic diene or an alicyclic diene having an endocyclic bridge) to produce a rubbery product. In the examples: (a) ethylene is polymerized in hexane in the presence of hydrogen utilizing reaction products of isoprene and triisobutyl aluminium (having various values of P) and the reaction product of TiCl 4 and a magnesium oxide support; (b) ethylene and butene are copolymerized in hexane in the presence of hydrogen utilizing the reaction product of isoprene and triisobutylaluminium (P= 2) and the reaction product of TiCl 4 and a magnesium carbonate support; (c) ethylene is polymerized in hexane in the presence of hydrogen and titanium tetraoctylate (to give a wide M.wt. range and a low density polymer) using the catalyst specified in (b) above; (d) ethylene is polymerized in hexane and in the presence of hydrogen utilizing a reaction product of triisobutyl aluminium and isoprene (P=2 3) and the reaction product of TiCl 4 and a magnesium hydroxychloride support; (e) ethylene and propylene are polymerized in hexane utilizing the reaction product of triisobutyl aluminium and isoprene (P=1 9) and the reaction product of TiCl 4 and vinyl alcohol/vinyl chloride/vinyl acetate copolymer support; and (f) ethylene and propylene are bulk polymerized utilizing the reaction product of triisobutyl aluminium and isoprene (P =1 9) and the reaction product of TiCl 4 and a magnesium oxide support.
[GB1245507A]
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR176286 | 1968-12-02 | ||
| FR6934083A FR2024673A6 (en) | 1969-10-06 | 1969-10-06 | Olefin polymerisation catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE33845L true IE33845L (en) | 1970-06-02 |
| IE33845B1 IE33845B1 (en) | 1974-11-13 |
Family
ID=26182350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE152169A IE33845B1 (en) | 1968-12-02 | 1969-11-07 | Process for the (co)polymerization of olefins |
Country Status (10)
| Country | Link |
|---|---|
| AT (1) | AT303376B (en) |
| BE (1) | BE742354A (en) |
| CA (1) | CA946098A (en) |
| CH (1) | CH505859A (en) |
| DE (1) | DE1959820C3 (en) |
| DK (1) | DK125026B (en) |
| GB (1) | GB1245507A (en) |
| IE (1) | IE33845B1 (en) |
| NL (1) | NL140249B (en) |
| RO (1) | RO62109A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5134142B2 (en) * | 1972-10-28 | 1976-09-24 | ||
| FR2571728B1 (en) * | 1984-10-16 | 1987-01-23 | Atochem | TIME-IMPROVED ACTIVITY-CATALYST FOR PROPYLENE POLYMERIZATION - POLYMERIZATION PROCESS |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB887313A (en) * | 1957-12-31 | 1962-01-17 | Ici Ltd | Polymerisation catalysts |
| NL129645C (en) * | 1960-03-30 | 1900-01-01 | ||
| US3149136A (en) * | 1960-03-30 | 1964-09-15 | Du Pont | Aluminum diene polymers |
| NL133354C (en) * | 1962-02-06 | |||
| FR1543296A (en) * | 1966-08-09 | 1968-10-25 | Hoechst Ag | Process for the preparation of polyolefins with a broad molecular weight distribution |
| FR1529845A (en) * | 1967-05-10 | 1968-06-21 | Solvay | Improvements in olefin polymerization |
-
1969
- 1969-10-24 CH CH1594469A patent/CH505859A/en not_active IP Right Cessation
- 1969-11-07 IE IE152169A patent/IE33845B1/en unknown
- 1969-11-13 GB GB5562669A patent/GB1245507A/en not_active Expired
- 1969-11-13 NL NL6917082A patent/NL140249B/en not_active IP Right Cessation
- 1969-11-25 CA CA 68375 patent/CA946098A/en not_active Expired
- 1969-11-28 BE BE742354D patent/BE742354A/xx not_active IP Right Cessation
- 1969-11-28 DE DE19691959820 patent/DE1959820C3/en not_active Expired
- 1969-12-01 DK DK635569A patent/DK125026B/en unknown
- 1969-12-02 AT AT1125569A patent/AT303376B/en active
- 1969-12-02 RO RO6173269A patent/RO62109A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE742354A (en) | 1970-05-28 |
| CH505859A (en) | 1971-04-15 |
| NL6917082A (en) | 1970-06-04 |
| IE33845B1 (en) | 1974-11-13 |
| GB1245507A (en) | 1971-09-08 |
| DK125026B (en) | 1972-12-18 |
| NL140249B (en) | 1973-11-15 |
| RO62109A (en) | 1978-01-15 |
| DE1959820A1 (en) | 1970-07-23 |
| AT303376B (en) | 1972-11-27 |
| DE1959820B2 (en) | 1974-08-29 |
| DE1959820C3 (en) | 1983-12-01 |
| CA946098A (en) | 1974-04-23 |
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