IE34210L - Catalytic epoxidation of olefins. - Google Patents
Catalytic epoxidation of olefins.Info
- Publication number
- IE34210L IE34210L IE700404A IE40470A IE34210L IE 34210 L IE34210 L IE 34210L IE 700404 A IE700404 A IE 700404A IE 40470 A IE40470 A IE 40470A IE 34210 L IE34210 L IE 34210L
- Authority
- IE
- Ireland
- Prior art keywords
- catalyst
- zirconium
- compounds
- epoxidation
- april
- Prior art date
Links
- 238000006735 epoxidation reaction Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 3
- 229910052726 zirconium Inorganic materials 0.000 abstract 3
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229910052909 inorganic silicate Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- KJSMVPYGGLPWOE-UHFFFAOYSA-N niobium tin Chemical compound [Nb].[Sn] KJSMVPYGGLPWOE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000002910 rare earth metals Chemical class 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 abstract 1
- 150000003755 zirconium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/14—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by free hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/46—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by amide or nitrile radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
1,249,082. Epoxidation catalysts. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 1 April, 1970 [2 April, 1969], No. 15376/70. Heading B1E. [Also in Division C2] Catalysts for use in the epoxidation of olefinic compounds by treatment with organic hydroperoxides comprise zirconium in chemical combination with silica and/or an inorganic silicate. Preferably the catalyst has a specific surface area of at least 1m<SP>2</SP>/g. In addition to the zirconium compound there may be present in the catalyst a promoter, e.g. a compound of magnesium, calcium, strontium or barium. There may also be present in the catalyst up to 10% by weight of an oxide or hydroxide of boron, tin niobium, tantalum, chromium, molybdenum, tungsten, rhenium, uranium, bismuth or a rare earth metal (atomic number 57-71). For comparative purposes examples are given of the use as catalyst of zirconium on a number on non-siliceous supports, metals other than zirconium on silica and various metallic compounds without siliceous compounds.
[GB1249082A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81292369A | 1969-04-02 | 1969-04-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE34210L true IE34210L (en) | 1970-10-02 |
| IE34210B1 IE34210B1 (en) | 1975-03-05 |
Family
ID=25210976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE404/70A IE34210B1 (en) | 1969-04-02 | 1970-04-01 | A process for epoxidizing olefins with organic hydroperoxides |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS5030050B1 (en) |
| AT (1) | AT302986B (en) |
| BE (1) | BE748315A (en) |
| BR (1) | BR7017926D0 (en) |
| CH (1) | CH543498A (en) |
| DE (1) | DE2015505C3 (en) |
| DK (1) | DK133747B (en) |
| ES (1) | ES378131A1 (en) |
| FR (1) | FR2042771A5 (en) |
| GB (1) | GB1249082A (en) |
| IE (1) | IE34210B1 (en) |
| NL (1) | NL144937B (en) |
| NO (1) | NO127502B (en) |
| SE (1) | SE361311B (en) |
| ZA (1) | ZA702169B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3024536A1 (en) * | 1980-06-28 | 1982-02-04 | Hoechst Ag, 6000 Frankfurt | ALUMINUM SILICATE CATALYST |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3391214A (en) * | 1967-06-12 | 1968-07-02 | Shell Oil Co | Isoprene production from isopentane via hydroperoxide |
-
1970
- 1970-04-01 GB GB05376/70A patent/GB1249082A/en not_active Expired
- 1970-04-01 ZA ZA702169A patent/ZA702169B/en unknown
- 1970-04-01 BR BR217926/70A patent/BR7017926D0/en unknown
- 1970-04-01 CH CH483270A patent/CH543498A/en not_active IP Right Cessation
- 1970-04-01 BE BE748315D patent/BE748315A/en unknown
- 1970-04-01 IE IE404/70A patent/IE34210B1/en unknown
- 1970-04-01 DK DK163770AA patent/DK133747B/en unknown
- 1970-04-01 JP JP45027355A patent/JPS5030050B1/ja active Pending
- 1970-04-01 SE SE04444/70A patent/SE361311B/xx unknown
- 1970-04-01 AT AT298070A patent/AT302986B/en active
- 1970-04-01 NL NL707004585A patent/NL144937B/en not_active IP Right Cessation
- 1970-04-01 ES ES378131A patent/ES378131A1/en not_active Expired
- 1970-04-01 NO NO01189/70*[A patent/NO127502B/no unknown
- 1970-04-01 DE DE2015505A patent/DE2015505C3/en not_active Expired
- 1970-04-01 FR FR7011642A patent/FR2042771A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL144937B (en) | 1975-02-17 |
| DE2015505B2 (en) | 1979-11-22 |
| DK133747C (en) | 1976-11-29 |
| AT302986B (en) | 1972-11-10 |
| JPS5030050B1 (en) | 1975-09-29 |
| DE2015505A1 (en) | 1970-10-08 |
| FR2042771A5 (en) | 1971-02-12 |
| NO127502B (en) | 1973-07-02 |
| ZA702169B (en) | 1971-11-24 |
| BE748315A (en) | 1970-10-01 |
| NL7004585A (en) | 1970-10-06 |
| DE2015505C3 (en) | 1980-08-07 |
| IE34210B1 (en) | 1975-03-05 |
| BR7017926D0 (en) | 1973-01-11 |
| CH543498A (en) | 1973-10-31 |
| GB1249082A (en) | 1971-10-06 |
| ES378131A1 (en) | 1972-06-01 |
| SE361311B (en) | 1973-10-29 |
| DK133747B (en) | 1976-07-12 |
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