IE34988L - Phenol-formaldehyde resins; insulating materials - Google Patents
Phenol-formaldehyde resins; insulating materialsInfo
- Publication number
- IE34988L IE34988L IE710283A IE28371A IE34988L IE 34988 L IE34988 L IE 34988L IE 710283 A IE710283 A IE 710283A IE 28371 A IE28371 A IE 28371A IE 34988 L IE34988 L IE 34988L
- Authority
- IE
- Ireland
- Prior art keywords
- phenol
- moles
- hcho
- ccl
- reacting
- Prior art date
Links
- 239000011810 insulating material Substances 0.000 title abstract 2
- 229920001568 phenolic resin Polymers 0.000 title abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 abstract 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004088 foaming agent Substances 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920003987 resole Polymers 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005909 Kieselgur Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229930003836 cresol Natural products 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 239000011152 fibreglass Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 abstract 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 abstract 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 abstract 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920002545 silicone oil Polymers 0.000 abstract 1
- 239000008259 solid foam Substances 0.000 abstract 1
- 238000005728 strengthening Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/18—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenols substituted by carboxylic or sulfonic acid groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
1283113 Phenol-formaldehyde resins FIBREGLASS Ltd P BODEN P J CROOK M E HALL and S P RILEY 19 April 1971 [13 March 1970] 12311/70 Headings C3C and C3R A phenol -HCHO resin comprises the product of reaction of 1 part wt. of a composition produced by reacting a phenol with concentrated H 2 SO 4 in a ratio of 0À8 to 1À5 moles H 2 SO 4 per mole phenol, and then adding per mole of phenol a quantity of HCHO in the range having a lower limit of 0À3 moles and an upper limit of 0À8 moles when using 0À8 moles H 2 SO 4 and decreasing to 0À5 moles when using 1À5 moles H 2 SO 4 ; with from 0À1-8 parts wt. of a phenol-HCHO resole produced by reacting a phenol and HCHO in the ratio of at least 0À9 moles HCHO per mole phenol in the presence of a basic catalyst. The phenol may be a cresol, 3,5-xylenol or hydroquinone or phenol itself. A solid foam may be produced by reacting the composition with the resole in the presence of a surfactant and a foaming agent. Preferred foaming agents are selected from low boiling point aliphatic hydrocarbons and halogenated derivatives thereof such as CCl 4 , CCl 3 F, CCl 2 F 2 , CF 2 ClCFCl 2 , C 2 Cl 2 F 4 , CHCl 2 F, CH 2 Cl 2 , CH 3 Cl, C 5 H 12 , C 6 H 14 , C 7 H 16 , and C 6 H 5 SO 2 -NHNH 2 . The surfactant is preferably a silicone oil, but may be polyoxyethylene sorbitan monopalmitate or monolaurate. Inorganic fillers such as diatomaceous earth and strengthening materials such as glass beads, glass fibres or glass flake may be incorporated in the foam. Uses.-Fire-retardant insulating material.
[GB1283113A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB02311/70A GB1283113A (en) | 1970-03-13 | 1970-03-13 | Improvements in or relating to insulating materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE34988L true IE34988L (en) | 1971-09-13 |
| IE34988B1 IE34988B1 (en) | 1975-10-15 |
Family
ID=10002187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE283/71A IE34988B1 (en) | 1970-03-13 | 1971-03-08 | Improvements in or relating to insulating materials |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE764222A (en) |
| CA (1) | CA988243A (en) |
| DE (1) | DE2112061A1 (en) |
| FR (1) | FR2081919B1 (en) |
| GB (1) | GB1283113A (en) |
| IE (1) | IE34988B1 (en) |
| NL (1) | NL7103184A (en) |
| ZA (1) | ZA711543B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU519442A1 (en) * | 1972-01-04 | 1976-06-30 | Предприятие П/Я Г-4059 | The method of producing foam |
| FR2205553A1 (en) * | 1972-11-07 | 1974-05-31 | Poudres & Explosifs Ste Nale | Phenolic resin foam formation - using mixt. of blowing agents having different gas evolution temperatures |
| SE7709470L (en) * | 1976-09-01 | 1978-03-02 | Vnii Sintetischeskich Smol | ACID AGENTS AND PROCEDURES FOR THE PREPARATION OF THE SAME |
| DE2834794C2 (en) * | 1978-08-09 | 1983-06-01 | Schaum-Chemie W. Bauer GmbH & Co KG, 4300 Essen | Process for the production of a foamed plastic |
| JPS62501077A (en) * | 1985-06-10 | 1987-04-30 | ザ ダウ ケミカル カンパニ− | Method for producing closed-cell phenolaldehyde foam with low K factor |
| GB9001368D0 (en) * | 1990-01-20 | 1990-03-21 | Bp Chem Int Ltd | Blowing agents |
| KR100725240B1 (en) * | 2007-01-31 | 2007-06-04 | 한국스미더스 오아시스 주식회사 | Oil-absorbing foam manufacturing method, foams produced through the foam and foams using the same |
-
1970
- 1970-03-13 GB GB02311/70A patent/GB1283113A/en not_active Expired
-
1971
- 1971-03-08 IE IE283/71A patent/IE34988B1/en unknown
- 1971-03-09 ZA ZA711543A patent/ZA711543B/en unknown
- 1971-03-09 CA CA107,290A patent/CA988243A/en not_active Expired
- 1971-03-10 NL NL7103184A patent/NL7103184A/xx unknown
- 1971-03-12 DE DE19712112061 patent/DE2112061A1/en active Pending
- 1971-03-12 FR FR7108633A patent/FR2081919B1/fr not_active Expired
- 1971-03-12 BE BE764222A patent/BE764222A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB1283113A (en) | 1972-07-26 |
| BE764222A (en) | 1971-09-13 |
| DE2112061A1 (en) | 1971-09-23 |
| FR2081919A1 (en) | 1971-12-10 |
| FR2081919B1 (en) | 1977-08-05 |
| ZA711543B (en) | 1972-08-30 |
| NL7103184A (en) | 1971-09-15 |
| IE34988B1 (en) | 1975-10-15 |
| CA988243A (en) | 1976-04-27 |
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