IE35681B1 - An improved catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides - Google Patents

An improved catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides

Info

Publication number
IE35681B1
IE35681B1 IE1219/71A IE121971A IE35681B1 IE 35681 B1 IE35681 B1 IE 35681B1 IE 1219/71 A IE1219/71 A IE 1219/71A IE 121971 A IE121971 A IE 121971A IE 35681 B1 IE35681 B1 IE 35681B1
Authority
IE
Ireland
Prior art keywords
hydroperoxides
oxirane compounds
improved catalyst
olefins
epoxidizing olefins
Prior art date
Application number
IE1219/71A
Other versions
IE35681L (en
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of IE35681L publication Critical patent/IE35681L/en
Publication of IE35681B1 publication Critical patent/IE35681B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Tubes (AREA)

Abstract

1339309 Oxiranes SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 29 Sept 1971 [1 Oct 1970] 45352/71 Heading C2C [Also in Division B1] One or more olefins are reacted with one or more organic hydroperoxides to produce one or more oxirane compounds in the presence of a catalyst (see Division B1) containing silica and a metal or boron oxide, which has been treated with an organo-silane, -silamine, or -silazane. Examples are given of the epoxidation of octene- 1 with ethylbenzene hydroperoxide, and propylene with ethylbenzene hydroperoxide. [GB1339309A]
IE1219/71A 1970-10-01 1971-09-29 An improved catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides IE35681B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7738570A 1970-10-01 1970-10-01

Publications (2)

Publication Number Publication Date
IE35681L IE35681L (en) 1972-04-01
IE35681B1 true IE35681B1 (en) 1976-04-28

Family

ID=22137754

Family Applications (1)

Application Number Title Priority Date Filing Date
IE1219/71A IE35681B1 (en) 1970-10-01 1971-09-29 An improved catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides

Country Status (16)

Country Link
JP (1) JPS5440526B1 (en)
AT (1) AT315135B (en)
BE (1) BE773363A (en)
CA (1) CA1002056A (en)
CH (1) CH568792A5 (en)
DE (1) DE2148637C3 (en)
DK (1) DK150592C (en)
ES (1) ES395527A1 (en)
FR (1) FR2109867A5 (en)
GB (1) GB1339309A (en)
IE (1) IE35681B1 (en)
IT (1) IT938878B (en)
NL (1) NL153872C (en)
NO (2) NO129888B (en)
SE (1) SE377525B (en)
ZA (1) ZA716592B (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK151016C (en) * 1972-03-13 1988-06-27 Shell Int Research PROCEDURE FOR THE PREPARATION OF OXIRAN COMPOUNDS BY CONVERSING AN OLEFINIC UNLAMATED COMPOUND WITH AN ORGANIC HYDROPEROXIDE IN THE PRESENT OF A CATALYST
DE3734138A1 (en) * 1987-10-09 1989-04-20 Scharmer Klaus Dr Ing ACID CATALYST AND METHOD FOR PRODUCING THE CATALYST
CA2002341A1 (en) * 1988-11-09 1990-05-09 Takehisa Nakanishi Method for preparing epichlorohydrins
US5081267A (en) * 1989-10-05 1992-01-14 Arco Chemical Technology, Inc. Epoxidation process
US5319114A (en) * 1993-09-23 1994-06-07 Arco Chemical Technology, L. P. Olefin epoxidation using a carbon molecular sieve impregnated with a transition metal
ES2139197T3 (en) * 1994-03-31 2000-02-01 Infineum Usa Lp POLYMERIZATION REACTIONS WITH SUPPORTED LEWIS ACID CATALYSTS.
DE19545042A1 (en) * 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphous microporous mixed oxide catalysts with controlled surface polarity for selective heterogeneous catalysis adsorption and material separation
DE19743165A1 (en) * 1997-09-30 1999-04-01 Studiengesellschaft Kohle Mbh Selective alkylation of aromatics with surface-modified microporous mixed oxides
EP1005907A4 (en) * 1998-02-24 2000-12-27 Agency Ind Science Techn UNSATURATED HYDROCARBON PARTIAL OXIDATION CATALYST
SG73663A1 (en) * 1998-08-04 2000-06-20 Sumitomo Chemical Co A process for producing propylene oxide
SG82626A1 (en) * 1998-08-04 2001-08-21 Sumitomo Chemical Co Titanium-containing silicon oxide catalyst
JP2000279809A (en) * 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd Epoxide production catalyst and epoxide production method
DE19925926A1 (en) * 1999-06-08 2000-12-14 Bayer Ag Catalysts based on titanium-containing, organic-inorganic hybrid materials for the selective oxidation of hydrocarbons
JP4694712B2 (en) * 2001-01-15 2011-06-08 丸善石油化学株式会社 Titanium-containing solid catalyst and method for producing epoxy compound using the same
EP3831818A4 (en) * 2018-07-30 2022-05-04 Kao Corporation Method for producing epoxy alkane, and solid oxidation catalyst
WO2021142635A1 (en) * 2020-01-14 2021-07-22 万华化学集团股份有限公司 Method for preparing catalyst for epoxidation of propylene and use thereof
CN113181961B (en) * 2020-01-14 2022-09-20 万华化学集团股份有限公司 Preparation method and application of propylene epoxidation catalyst

Also Published As

Publication number Publication date
NO138883C (en) 1978-11-29
DK150592C (en) 1987-10-05
NL153872C (en) 1981-07-16
IT938878B (en) 1973-02-10
DE2148637B2 (en) 1981-02-26
JPS5440526B1 (en) 1979-12-04
BE773363A (en) 1972-03-30
SE377525B (en) 1975-07-14
NO129888B (en) 1974-06-10
NO138883B (en) 1978-08-21
CH568792A5 (en) 1975-11-14
ES395527A1 (en) 1973-12-16
GB1339309A (en) 1973-12-05
NL153872B (en) 1977-07-15
ZA716592B (en) 1972-06-28
IE35681L (en) 1972-04-01
DK150592B (en) 1987-04-06
AT315135B (en) 1974-05-10
DE2148637A1 (en) 1972-04-06
FR2109867A5 (en) 1972-05-26
DE2148637C3 (en) 1982-04-22
AU3399671A (en) 1973-04-19
CA1002056A (en) 1976-12-21
NL7113338A (en) 1972-04-05

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