IE38870L - Organometal complexes. - Google Patents

Organometal complexes.

Info

Publication number
IE38870L
IE38870L IE732126A IE212673A IE38870L IE 38870 L IE38870 L IE 38870L IE 732126 A IE732126 A IE 732126A IE 212673 A IE212673 A IE 212673A IE 38870 L IE38870 L IE 38870L
Authority
IE
Ireland
Prior art keywords
complexes
olefins
formula
carbon atom
atom number
Prior art date
Application number
IE732126A
Other versions
IE38870B1 (en
Original Assignee
Anic Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anic Spa filed Critical Anic Spa
Publication of IE38870L publication Critical patent/IE38870L/en
Publication of IE38870B1 publication Critical patent/IE38870B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
    • C07C5/52—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0033—Iridium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/74—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The preparation of organic delta - and pi -complexes of transition metals of the formula Me(A)n(L-C)(L)m is described. Me is a transition metal, L is selected from alkyl or aryl-phosphines, -arsines, and -stibines, L-C is selected from the same, in which one C-H bond has reacted with the central metal Me, and A is an olefin selected from linear olefins having a carbon atom number from 2 to 5 or cyclic olefins having a carbon atom number from 6 to 8. The reaction is carried out starting with the hydride complex of the formula MeHxLn1, in which x varies from 5 to 7 and n can be 2 or 3. The complexes thus obtained show an increased reactivity towards the olefins, compounds with mobile hydrogen and towards hydrogen itself. They are used as catalysts in numerous reactions such as hydrogenations, carbonylations and oxidations. [GB1423888A]
IE02126/73A 1972-11-29 1973-11-22 Organometallic complexes their production and their uses IE38870B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT32211/72A IT972270B (en) 1972-11-29 1972-11-29 SIGMA AND PI GREEK COMPLEX ORGANS OF TRANSITION METALS AND THEIR PREPARATION PROCEDURE

Publications (2)

Publication Number Publication Date
IE38870L true IE38870L (en) 1974-05-29
IE38870B1 IE38870B1 (en) 1978-06-21

Family

ID=11235019

Family Applications (1)

Application Number Title Priority Date Filing Date
IE02126/73A IE38870B1 (en) 1972-11-29 1973-11-22 Organometallic complexes their production and their uses

Country Status (11)

Country Link
JP (2) JPS5621039B2 (en)
BE (1) BE807903A (en)
CA (1) CA1013755A (en)
CH (1) CH610904A5 (en)
FR (1) FR2207926B1 (en)
GB (1) GB1423888A (en)
IE (1) IE38870B1 (en)
IT (1) IT972270B (en)
LU (1) LU68881A1 (en)
NL (1) NL7316309A (en)
SE (1) SE409865B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3582055D1 (en) * 1984-12-04 1991-04-11 Fuel Tech Inc ADDITIVES FOR FUELS AND SOLUBLE COMPOUNDS OF A FUEL CONTAINING A METAL FROM THE PLATING GROUP AND USE IN ENGINES WITH INTERNAL COMBUSTION.
US4751344A (en) * 1986-05-05 1988-06-14 Ethyl Corporation Catalytic synthesis of olefins from paraffins
JPH0965U (en) * 1996-04-30 1997-01-28 日之出水道機器株式会社 Underground structure lid

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3652614A (en) * 1966-10-20 1972-03-28 Shell Oil Co Rhodium complexes containing tert-phosphine ligand

Also Published As

Publication number Publication date
DE2359552B2 (en) 1976-02-05
FR2207926B1 (en) 1979-06-29
JPS4982634A (en) 1974-08-08
GB1423888A (en) 1976-02-04
LU68881A1 (en) 1974-01-29
CA1013755A (en) 1977-07-12
CH610904A5 (en) 1979-05-15
JPS5636492A (en) 1981-04-09
BE807903A (en) 1974-03-15
IT972270B (en) 1974-05-20
SE409865B (en) 1979-09-10
DE2359552A1 (en) 1974-06-12
FR2207926A1 (en) 1974-06-21
JPS5621039B2 (en) 1981-05-16
NL7316309A (en) 1974-05-31
IE38870B1 (en) 1978-06-21

Similar Documents

Publication Publication Date Title
Evans The organometallic chemistry of the lanthanide elements in low oxidation states
Aracama et al. Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium (IV) complexes OsH2Cl2 (PR3) 2 (PR3= Pi-Pr3, PMe-t-Bu2)
Kameo et al. Recent developments in the coordination chemistry of multidentate ligands featuring a boron moiety
Koloski et al. Structure and reactivity of Cp2W (. eta. 2-Me2Si: CH2), a tungsten silene complex
ES453524A1 (en) Process for the preparation of a catalyst and catalyst used in olefin polymerization
Su et al. Synthesis and characterization of high-valent oxo olefin and oxo carbonyl complexes. Crystal and molecular structure of W (O) Cl2 (CH2: CH2)(PMePh2) 2
Tsutsui et al. . sigma.-Bonded organic derivatives of f elements
US3900557A (en) Anchored homogeneous-type catalysts for h-d exchange
Kataoka et al. Addition of methanol to nonactivated internal alkynes catalyzed by dichloro (diphosphine) platinum (II) complex/silver salt systems
IE38870L (en) Organometal complexes.
Van Voorhees et al. Formation of metallo hydride, formyl, and alkyl complexes of Rh (TMTAA)
Leigh et al. [Cp2Co][Bi {Co (CO) 4} 4]: A Paramagnetic, Ten‐Electron, Tetrahedral Complex of Bismuth
Novikov et al. Catalytic properties of lamellar compounds of graphite
Hawthorne et al. Iron (II)-and manganese (I)-carborane complexes formed through metal-carbon. sigma. bonds
Adams et al. Unsaturation in a high-nuclearity metal carbonyl cluster complex. Synthesis, structures, and interconversions of Pt2Os4 (CO) 12 (COD) 2 and Pt2Os4 (CO) 11 (COD) 2
GB1325199A (en) Process for the hydroformylation of olefines and catalysts for use therein
Wah et al. Activation of molecular oxygen by iron nitrosyls in the presence of bidentate nitrogen ligands (2, 2′-bipyridine, 4, 4′-dimethyl-2, 2′-bipyridine and 1, 10-phenanthroline)
GB1377569A (en) Organometallic complexes and production of the same
ES406349A1 (en) Catalysts for the oxidation of olefines
US4255601A (en) Process for making indene
IE40506L (en) Producing heterocyclic compounds.
SE330008B (en)
Das et al. Palladium (II) tetrakis (1-pyrazolyl) borate and some related species
Previdi et al. Induced halogen exchange in 1, 2-dichloroethane by bis (NN-diethyldithiocarbamato) nickel (II)
Marshall THE DESIGN OF MOLECULAR CAVITIES: ALLOSTERIC EFFECTS AND REACTION SELECTIVITY (EPOXIDATION, CROWN ETHERS)