IE39231L - Light sensitive materials for the production of printing¹plates. - Google Patents

Light sensitive materials for the production of printing¹plates.

Info

Publication number
IE39231L
IE39231L IE740859A IE85974A IE39231L IE 39231 L IE39231 L IE 39231L IE 740859 A IE740859 A IE 740859A IE 85974 A IE85974 A IE 85974A IE 39231 L IE39231 L IE 39231L
Authority
IE
Ireland
Prior art keywords
acid
group
poly
reaction product
resin
Prior art date
Application number
IE740859A
Other versions
IE39231B1 (en
Original Assignee
Vickers Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vickers Ltd filed Critical Vickers Ltd
Publication of IE39231L publication Critical patent/IE39231L/en
Publication of IE39231B1 publication Critical patent/IE39231B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4223—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1483—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G85/00—General processes for preparing compounds provided for in this subclass
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
    • G03F7/0388—Macromolecular compounds which are rendered insoluble or differentially wettable with ethylenic or acetylenic bands in the side chains of the photopolymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Materials For Photolithography (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Polymerisation Methods In General (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)

Abstract

1466252 Light-sensitive polymeric material VICKERS Ltd 25 April 1974 [26 April 1973] 19994/73 Headings C3R C3P and C3B [Also in Divisions G2 and C2] A light sensitive material comprises the reaction product of a polymer containing a plurality of epoxide groups, hydroxyl groups or primary and/or secondary amino groups with a halosulphonyl group containing compound of the formula wherein R represents an aromatic radical; a is 0 or 1, R 1 , R 2 and R 3 each represents a hydrogen atom, a halogen atom or a cyano, alkyl, aryl, alkoxy, aryloxy, aralkyl or aralkoxy group; and R 4 is an alkoxy carbonyl group, a carboxyl group, a phenyl group substituted with a deactivating group or a halosulphonyl substituted phenyl group when a is 0 or 1 and additionally when a is 1 a hydrogen atom or an alkyl or cyano group, and X represents a halosulphonyl group except when R 4 is a halosulphonyl phenyl group in which case X is a deactivating syrup, e.g. a halogen atom. Suitable polymers are epoxy and novolak/epoxy resins, phenol/aldehyde resins, phenoxy resins, poly(vinylalcohol), cellulose or a cellulose derivative, a partially hydrolysed poly(vinyl ester), poly(hydroxyethylacrylate), poly(hydroxyethyl methacrylate), a partially hydrolysed acetal, a phenoxy alkanol/aldehyde condensate, poly- (vinyl amine), an aniline/formaldehyde resin, poly(ethyleneimine) or the condensation product of a styrene/maleic anhydride copolymer or an alkyl vinylether/maleic anhydride copolymer with an excess of an aliphatic or aromatic diamine. The polymer may be additionally reacted before, during or after the reaction with the halosulphonyl group containing compound, with a halide of an aromatic sulphonic acid, an aliphatic or aromatic carboxylic acid, the halide containing no free carboxylic acid groups. Suitable halides are those of p-toluene sulphonic acid, acetic acid, propionic acid, benzoic acid, p-azido-benzoic acid or cinnamic acid. In the examples the following light-sensitive materials are prepared: (1) the reaction product of chlorosulphonylcinnamylidene malonic acid and either (i) a resorcinol/HCHO resin, or (ii) an epoxide resin prepared by condensing 2,2- bis - (p - hydroxyphenyl)propane with excess epichlorohydrin, or (iii) 2-phenoxyethanol- HCHO resin, or (iv) the reaction product of a phenol/HCHO resin and p-azidobenzoyl chloride, or (v) a styrene-maleic anhydride copolymer that has been reacted with excess ethylene diamine; or (vi) a polyethylene imine; (2) the reaction product of α-(chlorosulphonylphenyl)- chlorocinnamic acid, chlorosulphonylcinnamylidene malonic acid and a resorcinol/HCHO resin; (3) the reaction product of chlorosulphonylcinnamylidenecyanoacetic acid and a resorcinol/HCHO resin; (4) the reaction product of chlorosulphonyl-delta-chlorocinnamylidene malonic acid and a resorcinol-HCHO resin. The light sensitive materials are used to produce printing plates by applying a solution thereof in DMF and 2-ethoxyethanol to an aluminium sheet, drying the plate and then image-wise exposing the plate. A developer, e.g. trisodium phosphate or sodium metasilicate solution is then applied to remove the non- light-struck areas of the layer. [GB1466252A]
IE859/74A 1973-04-26 1974-04-22 Improvements in or relating to light sensistive material IE39231B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1999473A GB1466252A (en) 1973-04-26 1973-04-26 Light-sensitive material

Publications (2)

Publication Number Publication Date
IE39231L true IE39231L (en) 1974-10-26
IE39231B1 IE39231B1 (en) 1978-08-30

Family

ID=10138567

Family Applications (1)

Application Number Title Priority Date Filing Date
IE859/74A IE39231B1 (en) 1973-04-26 1974-04-22 Improvements in or relating to light sensistive material

Country Status (16)

Country Link
JP (1) JPS5842460B2 (en)
AT (1) AT344998B (en)
BE (1) BE814282A (en)
CA (1) CA1023491A (en)
CH (2) CH607100A5 (en)
DE (1) DE2420372A1 (en)
FI (1) FI62911C (en)
FR (1) FR2227556B1 (en)
GB (1) GB1466252A (en)
IE (1) IE39231B1 (en)
IT (1) IT1010118B (en)
LU (1) LU69940A1 (en)
NL (1) NL175631C (en)
NO (1) NO148794C (en)
SE (1) SE418191B (en)
ZA (1) ZA742559B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6841335B2 (en) * 2002-07-29 2005-01-11 Kodak Polychrome Graphics Llc Imaging members with ionic multifunctional epoxy compounds

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE758116A (en) * 1969-10-30 1971-04-01 Fuji Photo Film Co Ltd COMPOUND A HIGH MOLECULAR WEIGHT AND ITS PREPARATION PROCESS
JPS4944601B1 (en) * 1970-05-15 1974-11-29
BE790383A (en) * 1971-10-22 1973-02-15 Howson Algraphy Ltd Light sensitive material

Also Published As

Publication number Publication date
BE814282A (en) 1974-08-16
NL175631C (en) 1984-12-03
ATA349474A (en) 1977-12-15
CA1023491A (en) 1977-12-27
JPS5031819A (en) 1975-03-28
ZA742559B (en) 1975-04-30
CH598621A5 (en) 1978-05-12
NO741505L (en) 1974-10-29
SE418191B (en) 1981-05-11
FI62911C (en) 1983-03-10
FR2227556B1 (en) 1980-08-29
FI62911B (en) 1982-11-30
IE39231B1 (en) 1978-08-30
JPS5842460B2 (en) 1983-09-20
NL175631B (en) 1984-07-02
NO148794C (en) 1983-12-14
LU69940A1 (en) 1974-08-06
GB1466252A (en) 1977-03-02
CH607100A5 (en) 1978-11-30
NL7405575A (en) 1974-10-29
AT344998B (en) 1978-08-25
AU6823074A (en) 1975-10-30
FR2227556A1 (en) 1974-11-22
DE2420372A1 (en) 1974-11-07
IT1010118B (en) 1977-01-10
NO148794B (en) 1983-09-05

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