IE39886L - Catalyst. - Google Patents

Catalyst.

Info

Publication number
IE39886L
IE39886L IE741832A IE183274A IE39886L IE 39886 L IE39886 L IE 39886L IE 741832 A IE741832 A IE 741832A IE 183274 A IE183274 A IE 183274A IE 39886 L IE39886 L IE 39886L
Authority
IE
Ireland
Prior art keywords
olefins
catalyst
us3956181a
ammoxidation
bismuth
Prior art date
Application number
IE741832A
Other versions
IE39886B1 (en
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of IE39886L publication Critical patent/IE39886L/en
Publication of IE39886B1 publication Critical patent/IE39886B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins. [US3956181A]
IE1832/74A 1973-09-04 1974-09-04 Chromium-containing catalysts useful for oxidation reactios IE39886B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/393,732 US3956181A (en) 1973-09-04 1973-09-04 Oxidation catalyst

Publications (2)

Publication Number Publication Date
IE39886L true IE39886L (en) 1975-03-04
IE39886B1 IE39886B1 (en) 1979-01-17

Family

ID=23556013

Family Applications (1)

Application Number Title Priority Date Filing Date
IE1832/74A IE39886B1 (en) 1973-09-04 1974-09-04 Chromium-containing catalysts useful for oxidation reactios

Country Status (32)

Country Link
US (1) US3956181A (en)
JP (1) JPS5064191A (en)
AR (1) AR205351A1 (en)
BE (1) BE819533A (en)
BG (1) BG36494A3 (en)
BR (1) BR7407285D0 (en)
CA (1) CA1048481A (en)
CH (3) CH600946A5 (en)
CS (1) CS220305B2 (en)
DD (1) DD112906A5 (en)
DE (1) DE2440329C2 (en)
DK (1) DK146583C (en)
EG (1) EG11372A (en)
ES (1) ES429744A1 (en)
FI (1) FI62959C (en)
FR (1) FR2242146B1 (en)
GB (1) GB1473530A (en)
HU (2) HU181732B (en)
IE (1) IE39886B1 (en)
IL (1) IL45503A (en)
IN (1) IN143036B (en)
IT (1) IT1020135B (en)
MY (1) MY7800190A (en)
NL (1) NL186138C (en)
NO (1) NO141830C (en)
PH (1) PH12128A (en)
PL (1) PL108045B1 (en)
RO (1) RO66352A (en)
SE (1) SE403104B (en)
SU (1) SU588906A3 (en)
TR (1) TR18345A (en)
ZA (1) ZA745492B (en)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
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US4190556A (en) * 1973-07-19 1980-02-26 Standard Oil Company Production of unsaturated nitriles using catalysts promoted with various metals
US4162234A (en) * 1974-07-22 1979-07-24 The Standard Oil Company Oxidation catalysts
IT1025612B (en) * 1974-11-12 1978-08-30 Montedison Spa PROCEDURE FOR THE PREPARATION OF UNSATURATED ALDEHYLIC ACIDS AND CARBOXYLIC ACIDS BY OXIDATION OF CATALYTES CA IN THE GASEOUS PHASE OF THE CORRESPONDING OLEPHINS
US4397771A (en) * 1975-01-13 1983-08-09 The Standard Oil Co. Oxidation catalysts
CA1071659A (en) * 1975-09-18 1980-02-12 Goodyear Tire And Rubber Company (The) Oxidative dehydrogenation of olefins to diolefins
US4052332A (en) * 1976-04-20 1977-10-04 E. I. Du Pont De Nemours And Company Catalyst regeneration with impregnation of bismuth and molybdenum
US4101448A (en) * 1976-05-14 1978-07-18 The Standard Oil Company Catalyst compositions especially useful for preparation of unsaturated acids
US4083805A (en) * 1976-06-30 1978-04-11 The Standard Oil Company Preparation of methacrylic acid from methacrolein
US4202826A (en) * 1977-02-10 1980-05-13 Denka Chemical Corporation Process for preparing anhydride from alkanes
US4167516A (en) * 1977-02-10 1979-09-11 Denka Chemical Corporation Preparation of dicarboxylic anhydrides
US4105586A (en) * 1977-02-10 1978-08-08 Denka Chemical Corporation Oxidation catalysts and process for preparing anhydride from alkanes
US4556731A (en) * 1977-07-28 1985-12-03 The Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
US4322368A (en) * 1979-12-28 1982-03-30 The Standard Oil Co. Copper-promoted antimony phosphate oxide complex catalysts
JPS56140931A (en) * 1980-04-04 1981-11-04 Nippon Zeon Co Ltd Preparation of conjugated diolefin
JPS56150023A (en) * 1980-04-22 1981-11-20 Nippon Zeon Co Ltd Preparation of conjugated diolefin
US4444906A (en) * 1981-06-08 1984-04-24 The Standard Oil Company Method for the preparation of high activity phosphomolybdic acid based catalysts
CA1199905A (en) * 1982-06-07 1986-01-28 William J. Kennelly Catalyst compositions and their use for the preparation of unsaturated carboxylic acids
JPS59115750A (en) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for synthesis of methacrylic acid
US4777313A (en) * 1983-08-12 1988-10-11 Atlantic Richfield Company Boron-promoted reducible metal oxides and methods of their use
US4855275A (en) * 1988-02-18 1989-08-08 The Standard Oil Company Catalyst performance improvement via separate boron addition
US5134105A (en) * 1990-03-19 1992-07-28 The Standard Oil Company Catalyst for propylene ammoxidation to acrylonitrile
US5158923A (en) * 1990-05-21 1992-10-27 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
US5262548A (en) * 1990-05-21 1993-11-16 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
TR27951A (en) * 1992-06-23 1995-11-08 Standard Oil Co Ohio A process and catalyst developed for propylene amoxidation with acrylonitrile.
JP3114587B2 (en) * 1995-10-23 2000-12-04 ヤマハ株式会社 Karaoke amplifier
ES2283260T3 (en) * 1999-11-24 2007-11-01 Saudi Basic Industries Corporation OXIDIZING DEHYDROGENATION OF PARFINS.
US7649112B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
KR100888133B1 (en) * 2007-10-02 2009-03-13 에스케이에너지 주식회사 Method for preparing multicomponent bismuth molybdate catalyst composed of four metal components and method for preparing 1,3-butadiene using the catalyst
JP2013505997A (en) * 2010-07-09 2013-02-21 住友化学株式会社 Process for producing olefin oxide
JP2013506000A (en) * 2010-07-09 2013-02-21 住友化学株式会社 Process for producing olefin oxide
WO2012009056A1 (en) * 2010-07-10 2012-01-19 Sumitomo Chemical Company, Limited Process for producing olefin oxide
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
EA024249B1 (en) 2012-01-30 2016-08-31 Басф Се PROCESS FOR PREPARING BUTADIENE AND/OR BUTENES FROM n-BUTANE
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
WO2014044693A1 (en) 2012-09-20 2014-03-27 Basf Se Method for producing butadiene with removal of oxygen from c4 hydrocarbon streams
US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
CN104837558A (en) 2012-12-06 2015-08-12 巴斯夫欧洲公司 Method for oxidative dehydrogenation of N-butenes to butadiene
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
EA201591316A1 (en) 2013-01-15 2016-01-29 Басф Се Method of producing 1,3-butadiene from n-butylene by means of oxidative dehydration
WO2014111331A1 (en) 2013-01-16 2014-07-24 Basf Se Method for producing butadiene by oxidative dehydrogenation of n-butenes by monitoring the peroxide-content during product processing
EP3019458B1 (en) 2013-07-10 2017-04-05 Basf Se Method for the oxidative dehydrogenation of n-butenes to butadiene
WO2015063019A1 (en) 2013-10-30 2015-05-07 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
US20160347686A1 (en) 2014-01-13 2016-12-01 Basf Se Method of starting up a reactor for the oxidative dehydrogenation of n-butenes
DE102014203725A1 (en) 2014-02-28 2015-09-03 Basf Se Oxidation catalyst with saddle-shaped carrier shaped body
EP3180298B1 (en) 2014-08-12 2018-11-07 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation
CN106795066A (en) 2014-09-26 2017-05-31 巴斯夫欧洲公司 The method for preparing 1,3 butadiene by oxidative dehydrogenation by n-butene
WO2016071268A1 (en) 2014-11-03 2016-05-12 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
JP6685299B2 (en) 2014-11-14 2020-04-22 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Process for producing 1,3-butadiene by dehydrogenation of n-butenes while providing a material stream containing butane and 2-butene
CN107428636A (en) 2015-03-26 2017-12-01 巴斯夫欧洲公司 1,3 butadiene are manufactured by oxidative dehydrogenation by n-butene
EA201792113A1 (en) 2015-03-26 2018-04-30 Басф Се METHOD OF OBTAINING 1,3-BUTADIENE FROM H-BUTENES THROUGH OXIDATIVE DEGYDERATION
WO2016150940A1 (en) 2015-03-26 2016-09-29 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
WO2016151074A1 (en) 2015-03-26 2016-09-29 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
US20180354872A1 (en) 2015-12-03 2018-12-13 Basf Se Method for producing butadiene by oxidatively dehydrogenating n-butenes
US10370310B2 (en) 2016-01-13 2019-08-06 Basf Se (Isenbruck Bösl Hörschler Llp) Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
WO2017133997A1 (en) 2016-02-04 2017-08-10 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
KR20190046848A (en) 2016-08-09 2019-05-07 바스프 에스이 Starting method of reactor for oxidative dehydrogenation of n-butene
WO2018095840A1 (en) 2016-11-22 2018-05-31 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation, comprising furan removal in the processing
WO2018095776A1 (en) 2016-11-22 2018-05-31 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation, comprising aqueous scrubbing of the c4 product gas flow
EP3323797A1 (en) 2016-11-22 2018-05-23 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation comprising an acidic washing of a c4 product gas flow
WO2018095856A1 (en) 2016-11-22 2018-05-31 Basf Se Method for preparing 1,3-butadiene from n-butenes through oxidative dehydrogenation comprising methacrolein removal during processing
WO2018219996A1 (en) 2017-06-02 2018-12-06 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation in recycle gas mode with co2-enriched recycle gas
WO2018234158A1 (en) 2017-06-19 2018-12-27 Basf Se PROCESS FOR THE PREPARATION OF 1,3-BUTADIENE FROM N-BUTENES BY OXIDATION DEHYDROGENATION COMPRISING A C4 FLUID WASTE PRODUCED IN C4

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US3678124A (en) * 1968-10-24 1972-07-18 Gennady Arkadievich Stepanov Process for the production of mono- and diolefin hydrocarbons
US3642930A (en) * 1968-12-30 1972-02-15 Standard Oil Co Ohio Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor
BE749305A (en) * 1969-05-02 1970-10-01 Nippon Kayaku Kk OXIDIZATION CATALYST AND ITS USE (
BE757476A (en) * 1969-10-17 1971-03-16 Nippon Kayaku Kk OXIDESHYDROGENATION PROCESS
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GB1434581A (en) * 1972-05-26 1976-05-05 Ube Industries Catalyst and process for catalytic ammoxidation of propylene or isobutylene
GB1426303A (en) * 1972-08-25 1976-02-25 Ube Industries Catalyst and process for oxidation of ammoxidation of olefin mixtures

Also Published As

Publication number Publication date
NL186138B (en) 1990-05-01
NO743150L (en) 1975-04-01
TR18345A (en) 1977-01-12
CH600946A5 (en) 1978-06-30
AR205351A1 (en) 1976-04-30
PL108045B1 (en) 1980-03-31
IL45503A0 (en) 1974-11-29
SE7410289L (en) 1975-03-05
AU7283974A (en) 1976-03-04
JPS5064191A (en) 1975-05-31
DK146583B (en) 1983-11-14
SE403104B (en) 1978-07-31
DE2440329A1 (en) 1975-03-13
BG36494A3 (en) 1984-11-15
HU181951B (en) 1983-11-28
ES429744A1 (en) 1977-06-16
US3956181A (en) 1976-05-11
NO141830B (en) 1980-02-11
FR2242146B1 (en) 1980-10-24
FR2242146A1 (en) 1975-03-28
CA1048481A (en) 1979-02-13
NL7411580A (en) 1975-03-06
DD112906A5 (en) 1975-05-12
GB1473530A (en) 1977-05-11
EG11372A (en) 1977-08-15
CS220305B2 (en) 1983-03-25
FI257074A7 (en) 1975-03-05
NL186138C (en) 1990-10-01
BE819533A (en) 1975-03-04
PH12128A (en) 1978-11-07
DE2440329C2 (en) 1982-10-21
SU588906A3 (en) 1978-01-15
IT1020135B (en) 1977-12-20
FI62959B (en) 1982-12-31
FI62959C (en) 1983-04-11
ZA745492B (en) 1975-09-24
IE39886B1 (en) 1979-01-17
DK146583C (en) 1984-04-30
BR7407285D0 (en) 1975-07-01
NO141830C (en) 1980-05-21
IN143036B (en) 1977-09-24
DK465074A (en) 1975-05-05
HU181732B (en) 1983-11-28
RO66352A (en) 1979-07-15
CH603514A5 (en) 1978-08-15
CH605477A5 (en) 1978-09-29
IL45503A (en) 1977-06-30
MY7800190A (en) 1978-12-31

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